烯基

Promoted by metal dysprosium, aldehydes and ketones could react smoothly with propargyl bromide to afford the corresponding homopropargylic alcohol s in good to excellent yields, and no allenic alcohols were found.

在金属镝的促进下，醛、酮可与炔丙基溴反应，高选择性高产率地得到相应的高炔丙醇，没有发现连二烯醇的存在。

The new olefination methods of alkyl substituted propargylic dithioacetals are described in this thesis.

中文摘要本篇论文围绕在烷基取代炔丙基硫缩醛的新型态烯化反应，可分为两部分进行探讨。

The pyridinium salts was transformed by the base to 1-hydroxy or 3-hydroxy-quinolizinylides, which undergo 1,3-dipolar cycloadditionreaction with alkenes,and then aromatizated to cycl[3,3,2]azinone in thepresence of oxidant.

实验证明，这是一个连续进行的多步反应：2-羰基吡啶鎓盐在反应中先生成1-羟基或3-羟基喹嗪叶立德，然后与烯烃起1，3—偶极加成反应，最后在氧化剂作用下脱氢芳构化而生成Cycl[3，3，2]azinone。

Comparison of inhibitors for anti-polymerization of isoprene, such as NaNO2, p-tert-butylcatechol, N-methyl pyrrolidone and paradioxybenzene, was carried out using polymer segregation process and the results showed that TBC was the best one.

采用聚合物离析法比较了亚硝酸钠（NaNO2）、对叔丁基邻苯二酚、N-甲基吡咯烷酮、对苯二酚对异戊二烯的阻聚效果，发现TBC阻聚效果最好。

Results Six compounds were isolated and identified as:5α,8α-epidioxy-(22E,24R)-ergosta-6,22-dien-3β-ol,scopoletin,isofraxidin,p-hydroxy benzaldehyde,3,4,5-trimethoxy benzoic acid,protocatechuic acid ethyl ester...

结果得到6个化合物，分别鉴定为：5α，8α表二氧(22E，24R)麦角甾6，22二烯3β醇、东莨菪素、异秦皮啶、对羟基苯甲醛、3，4，5三甲氧基苯甲酸、原儿茶酸乙酯。结论化合物Ⅰ～Ⅵ均为首次从该属植物中分离得到。

In the catalytic tranformation of n-butane, Pd modified silicoaluminate molecular sieves were tested for n-butane's isomerization and dehydroismerization.

考察了硅铝分子筛为基质的双功能催化剂催化丁烷异构化的反应性能及催化丁烷一步异构脱氢反应的可能性，发现丁烷到异丁烯的一步转化无法在这一反应体系十有效实现。

In the catalytic tranformation of n-butane, Pd modified silicoaluminate molecular sieves were tested for n-butane's isomerization and dehydroismerization.

考察了硅铝分子筛为基质的双功能催化剂催化丁烷异构化的反应性能及催化丁烷一步异构脱氢反应的可能性，发现丁烷到异丁烯的一步转化无法在这一反应体系中有效实现。

Sodium allyl hydroxyalkyl sulphonate was used as reactive surfactant to modify the polymerization ofelastic acrylic emulsion. Influence of SAHS on minimum content of surfactants and particle size of emulsion was studied andmechanism of change of particle size discussed.

使用烯丙基羟烷基磺酸钠作为可聚合乳化剂，改性合成了弹性丙烯酸酯乳液，研究了它对乳化剂的最低用量和乳胶粒粒径的影响，探讨了乳胶粒粒径变化的机理。

Main products are Perfluorosulfonated acid resin, PFSA aqueous dispersion, and on the basic of them, HFPO,TFE sultone,PSVE,PPVE,MTPME etc fluorinated fine chemicals,and FEP,FKM,PVDF etc fluorpolymers.

公司主导产品有全氟磺酸离子交换树脂、全氟磺酸离子交换树脂溶液，同时以此为依托，配套生产六氟环氧丙烷、四氟磺内酯、PSVE、PPVE、甲氧基四氟丙酸甲酯等含氟精细化学品，聚全氟乙丙烯树脂（FEP，F46）及分散液、氟橡胶、聚偏氟乙烯等含氟高分子材料。

The side chain of thioacetic acid has been sythesized from the material of acetic acid via four steps, then synthesized the key intermediate of 2-hydroxypenem via displacement, P〓induced cyclization and hydrolyzed reaction from the material of azetidinone.

以羟乙酸为原料，经四步反应合成了侧链化合物硫基取代的羟乙酸，发生取代反应导入到经七步合成的单环氮杂环丁酮中，然后发生酰化，Wittig诱导环化，水解等五步反应合成关键中间体2-羟甲基青霉烯。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。