烯基

In this dissertation, electrophilic reactions of Nitrosonium with imines, aza-Diels-Alder reactions of N-arylimines with a variety of electron rich olefinic compounds induced by NO~+, and photoreactions of N-nitrosodiphenylamine with aromatic amines were studied.

本文研究了：(1)NO~+与亚胺双健发生的亲电反应；(2)NO~+引发的芳香亚胺和富电子碳碳双键作为亲二烯体的氮杂Diels-Alder反应，高选择性地得到了一系列四氢喹啉的衍生物；(3)N—亚硝基二苯胺与芳香胺发生光化学反应得到了一系列偶氮苯类化合物。

The process comprises polymerizing olefins in the presence of a supported indenoindolyl catalyst system and an organoboron or organoaluminum-treated solid.

该方法包括在茚并吲哚基载体催化剂体系和无机硼或无机铝处理的固体存在下聚合烯烃。

The reaction of cyclic b-keto esters with CF3CO2ZnCH2I provides the corresponding ring-expanded products with the advantage of mild condition in moderate to good yields. A simple and efficient procedure has been developed for a variety of 1,3-diketones converted into the corresponding 1,4-diketones and trans-1,2-disubstituted cyclopropanols in high yields. In conclusion, this new type of organozinc reagents has been developed for many useful reaction in organic synthesis.

利用有机锌试剂所具有的双重特性，在新型的Baylis-Hillman反应中，可以直接与炔基酮和醛反应一锅制得多官能团的三取代的顺式烯；在b-酮酯化合物的扩环反应中，取得了重要进展，得到了增加一个碳的扩环产物，&一步法&合成，反应条件温和、环境友好；在1，3-二酮分子中成功地插入1个碳，合成出1，4-二酮和环丙醇，为现代有机合成提供了新的合成方法，具有良好的应用前景。

These salts can beprepared on treatment of phosphinimines with trifluoroaceticanhydride. After addition-elimination, triflromethylated β-enaminoesters and β-iminoesters were synthesized by thereaction of the above salts with organozinc reagents.

通过膦亚胺和三氟乙酸酐反应制备了N-三氟乙酰基氨基膦盐，该膦盐和锌试剂发生加成-消除反应后，合成了含有三氟甲基的β-烯胺酯和β-亚胺酯。

The main compounds of essential oils were Pentadecane（20.88%,46.56%）,Ethyl-cinnamate(25.60%,10.94%), Ethyl-p-methoxycinnamate(28.69%,2.41%),3-Carene(3.31%,11.36%).

主要成分均为十五烷（20.88%，46.56%），桂皮酸乙酯(25.60%，10.94%)，对甲氧基桂皮酸乙酯(28.69%，2.41%)，3-蒈烯(3.31%，11.36%)。

Ethyl alcohol, 3-methyl-4-oxo- pentanoic acid, acetic acid butyl ester, 2-methyl-butanoic acid ethyl ester, diethyl phthalate,-2,4-Decadienal were the same volatiles d from the 10 cultivars.

其中共有组6种，为乙醇、3-甲基-4-羰基戊酸、乙酸丁酯、2-甲基丁酸乙酯、邻苯二甲酸二乙酯、-2，4-癸二烯醛。

The effects of spatial hindrance , solvent, free volume were investigated. The result showed that the structure of graft copolymers exhibit a marked influence on photoisomerization.

另外，邻位被丙烯酰氧基取代的偶氮聚合物还表现出光致变色性禁阻，这说明空间位阻起了一个非常重要的作用。

Seven of them have not been reported.Their structures were confirmed by IR,~1HNMR,MS,and element analysis. 4.Meanwhile,the green methylation procedure of imides was developed by using dimethyl carbonate as methylation reagent.A series of imides,for example,phthalimide,3,4-dibromo-maleimide and succincide were used for substrates.The effects of DABCO(1,4-diazabicyclo [2.2.2]octane)and DBU(1,8-diazabicyclo[5.4.0]undec-7-ene)as a catalyst in this kind of reactions were investigated.2-Bromo-3-(1-methylindolyl-3-yl)-1-methyl-1H-pyrrole-2,5-dione was prepared by using dimethyl carbonate,which further expanded the use of dimethyl carbonate,as a green agent in organic synthesis.

在以硫酸二甲酯为甲基化试剂对3，4-二溴马来酰亚胺进行N-甲基化反应合成3，4-二溴-N-甲基马来酰亚胺的同时，以碳酸二甲酯为甲基化试剂，对3，4-二溴马来酰亚胺、邻苯二甲酰亚胺、琥珀酰亚胺等酰亚胺类化合物的N-甲基化反应进行了研究；考察了1，4-二氮杂双环[2.2.2]辛烷，1，8-二氮杂双环[5.4.0]十一碳-7-烯、碳酸钾和四丁基溴化铵等作为催化剂对碳酸二甲酯N-甲基化反应的反应时间和收率等的影响，并应用碳酸二甲酯为甲基化试剂，合成了N-甲基-3-溴-4-(1-甲基-吲哚-3)-马来酰亚胺。

The result indicated that polychloride and anionic polyacrylamide could improve the retention of TiO_(2)-zeolite singnificantly.

考察了TiO2-沸石复合纸板制备中聚二甲基二烯丙基氯化铵/阴离子聚丙烯酰胺和阳离子淀粉/APAM二元助留体系助留效果。

Eight kinds of 2-benzimidazolylalkylene derivatives in polyphosphoric acidhave been synthesized by multi-power bands microwave irradiation technique,starting from corresponding cinnamic acid compounds and they were characterized by~1H NMR,(~13C NMR and MS respectively.

以8种肉桂酸衍生物和邻苯二胺为原料，在多聚磷酸中，采用分段式微波辐射方法合成了8种2-苯并咪唑基烯烃衍生物，并通过1H NMR、13C NMR和MS进行了表征。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。