烯基

Polyether modified polysiloxane was synthesized by the hydrosilation reaction of hydrogen containing silicone fluidand allyl polyether, using chloroplatinic acid as the catalyst.

以氯铂酸为催化剂，利用含氢硅油与烯丙基聚醚的硅氢加成反应，合成出聚醚改性硅油；然后用乙醇胺进行胺化反应，制成纸张用氨基改性聚醚硅油柔软剂。

Too high allyl contents are unfavorable in that a high BMI proportion will be required to copolymerize with the allylated Novolak resin.

为了协调好工艺性、耐热性与T〓三者之间的矛盾，获得综合性能优良的改性酚醛树脂体系，应通过控制投料比将Novolak树脂的烯丙基化程度控制在25％左右。

In the present study,a novel microgel was designed by the incorporation of temperature sensititive N-isopropylacrylamide and pH sensitive acrylic acid to copolymerize with glucosamine derivative,acrylamido-2-deoxy-glucose. The novel microgel has favorable biocompatibility,tissue-targeting and stimuli-responsibility to pH and temperature.

本文利用具有生物相容性的氨基葡萄糖单糖衍生物、具有温敏性的异丙基丙烯酰胺及具有pH敏感性的丙烯酸共聚得到了全新的微凝胶，新型微凝胶具有良好的生物相容性、组织靶向性和对温度、pH的刺激响应性。

Condensation of cinnamaldehyde with methyl crotonate in the presence of alcohol-flee potassium methoxide gives,after hydrolysis,p-phenyl-benzoic acid in low yield.Its structure has been ascertained by direct comparison with an au- thentic sample.

桂皮醛与α-丁烯酸甲酯在催化剂去醇的甲氧基钾影响下进行反应，得到低产率的对-苯基-苯甲酸，共结构经用已知方法所得同样的酸直接加以比较而确定。

Butadiene was polymerized to some extent in the presence of binary catalyst system NdCl33iPrOHAlEt3 in toluene and the allylchloride was then added to the solution in order to cyclize the formed polybutadiene and cyclopolymerize the unreacted butadiene monomers.

采用NdCl3·3i－PrOH－AlEt3稀土催化剂进行丁二烯的顺式聚合，在聚合过程中引入烯丙基氯，进行分子内环化反应以及单体的环聚反应。

Butadiene was polymerized to some extent in the presence of binary catalyst system NdCl33iPrOHAlEt3 in toluene and the allylchloride was then added to the solution in order to cyclize the formed polybutadiene and cyclopolymerize the unreacted butadiene monomers.

采用NdCl3·3i－PrOH－AlEt3稀土催化剂进行丁二烯的顺式聚合，在聚合过程中引入烯丙基氯，进行分子内环化反应以及单体的环聚反应。考察了稀土催化剂用量、n／n（AlEt3）、环化时间、反应温度、单体浓度等对环化反应的影响，并对产物进行了红外光谱、核磁共振光谱的表

The results indicated, catalytic activity was very high, the average rate of O 2 uptake was 4.25×10 -2 mmol/min after 10 min, the yield of cyclopentanone was up to 83%.

实验结果表明，该催化体系对环戊烯的羰基化显示出较高的催化活性，反应 1 0 min，反应的平均吸氧速率为 4.2 5× 1 0 -2 mmol/min，环戊酮的收率可达 83%。

Under the optimum conditions of a cyclopentene amount of 1.0 mol, a molar ratio of cyclopentene to water of 0.25, a reaction temperature of 120 ℃, a reaction time of 4.0 h, a main catalyst dosage of 4.0 g and a cocatalyst dosage of 0.8 g, the yield of cyclopentanol reached 68.6%.

确定适宜的反应条件为：环戊烯1.0 mol，n﹕n=1﹕4，反应温度120 ℃，反应时间4.0 h，硅胶负载铌酸主催化剂用量4.0 g，三（3，6-二氧杂庚基）胺助催化剂0.8 g。在此反应条件下，环戊醇收率68.6%。

Cyclopentanol was synthesized from cyclopentene and water through hydration reaction using HNb3O8·H2O/SiO2 as main catalyst and tris(dioxa-3,6-heptyl)amine (TDA-1) as cocatalyst.

在以硅胶负载铌酸为主催化剂、三（3，6-二氧杂庚基）胺为助催化剂的作用下，以环戊烯和水为原料，通过水合加成反应合成了环戊醇。

In the second part of this thesis, a formal [2+2] cycloaddition ketenes and dialkyl azodicarboxylates was studied. We found that by adjusting the substituents in the diazenes, the reaction mode can be completely switched, and furnish four-membered-ring products, aza-b-lactams, the enantioselectivity was up to 91%.

经研究发现，通过对偶氮化合物取代基团的改变，我们可以实现[4+2]环加成反应到[2+2]环加成反应的转变，在手性氮杂环卡宾的作用下，对具有各种取代基的烯酮都可以很好的产率得到氮杂b-内酰胺，其对映选择性最高可以达到91%。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。