烯基

The preparation of potassium malonyloxyborohydride in situ and its seletive hydroborating alkene are described.

介绍了丙二酰氧基硼氢化钾的制备及其原位与烯烃的选择性硼氢化。

The second part is the folding of apo cyt c induced by the alternating copolymers of maleic acid and alkene.

论文工作的第二部分研究了马来酸—烯烃交替共聚物对脱辅基细胞色素c结构转换的影响。

In this study enamine was used as the reactive intermediate for alkylation of cyclohexanone alkylate,to provide a new route to synthesize the perfume-α-tert-butylcyclohexanone after overcoming many disadvantages of the traditional technical route,such as the complicated of reaction steps,the expensive reagents adopted,the high demand for the equipment used,and the low yield of product.

利用烯胺作为环己酮烷基化的活性中间体，为香料α-叔丁基环己酮的合成提供了一条新的途径，克服了传统工艺反应步骤烦琐，试剂昂贵，设备要求较高，产率不高等缺点，易于工业化生产。

These ligands were found to be very effective in construction of quaternary carbon centers by using asymmetric allylic alkylation.

这类配体在前手性亲核试剂的不对称烯丙基化构筑手性季碳中心的反应中，显示了较好的反应活性及对映选择性。

The ligands were found to be effective in palladium-catalyzed asymmetric allylic alkylation to construct chiral quaternary carbon center.

这类配体在前手性亲核试剂的不对称烯丙基化构筑手性季碳中心的反应中，显示了较好的反应活性及对映选择性。

A process for preparing alkylene glycols including reacting an alkylene oxide with water in the presence of a combination of additives and an anion exchange resin, wherein the combination of additives comprises carbon dioxide and an organic or inorganic base provided in an amount sufficient to maintain a pH of the reaction mixture between about 5.0 and 9.0, with the proviso that, when the base is bicarbonate or carbonate, then the anion exchange resin is a trimethyl benzyl ammonium anion exchange resin.

制备亚烷基二醇的方法，包括让烯化氧与水在添加剂组合和阴离子交换树脂存在下进行反应，其中添加剂组合包括二氧化碳和以足以保持反应混合物的pH值在约5.0和9.0之间的量提供的有机或无机碱，前提条件是当碱是碳酸氢盐或碳酸盐时，阴离子交换树脂是三甲基苄基铵阴离子交换树脂。

In the paper, the research evolvement of electrocarboxylation from carbon dioxide with olefin, alkyne, and ketones in near decades was summarized, these reactions were convenient ways to synthesize some valuable pharmaceutical precursor and intermediates in organic synthesis.

文章综述了近几十年来二氧化碳与烯烃化合物、炔烃化合物以及酮类化合物的电羰基化反应的研究进展，这些反应是合成一些有价值的药物前驱体或是有机合成中间体的简便方法。

It was found that the stereoselectivity of this reaction to produce S-CHBE could be remarkably improved by pretreatment with heating and allyl alcohol.

而烯丙基溴预处理可以使反应立体选择性从通常的生成S-型产物过量转变为R-型产物过量，优化处理条件后能使R-CHBE的e.e。

Chemistry of or pertaining to the allyl radical.

烯丙基的或与之相关的。

It is possible to achieve the conversion of allyl chloride and selectivity for epichiorohydrin as high as 99% on Ti-MWW.

在Ti-MWW催化剂上烯丙基氯的转化率和环氧氯丙烷的选择性都能达到99%以上。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。