烯基
- 与 烯基 相关的网络例句 [注:此内容来源于网络,仅供参考]
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N-propyl-4-(N-methylacryloxy-ethyl)amino-1,8-naphthalimide was synthesized and used for determination of picric acid.
合成了N-丙基-4-(N-甲基丙烯酰基氧乙基)氨基-1,8-萘酰亚胺,研制出了苦味酸荧光光纤传感器,可间接测定药片中磷酸氯喹和水样中苦味酸的含量。
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We screened a set of Lewis base organocatalysts derived from chiral pipecolinic acid and tert-butanesulfinamide for the reduction of-N-Cbz-1- phenylpropenamine, including newly designed ones and some of those previously developed in our lab. However, only moderate stereoselectivities, albeit high yields were obtained.
在本课题组前期研究的基础上,我们筛选并设计了一系列以手性哌啶酸和叔丁基亚磺酰胺为母体的有机小分子路易斯碱催化剂,它们能催化三氯氢硅对-N-苄氧羰基-1-苯基丙烯胺的不对称还原,获得很高的收率和中等的对映选择性,并且具有很好的底物普适性。
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Promoted by metal dysprosium, aldehydes and ketones could react smoothly with propargyl bromide to afford the corresponding homopropargylic alcohols in good to excellent yields, and no allenic alcohol s were found.
当用苯基炔丙基溴代替炔丙基溴与醛、酮反应时,主要得到了相应的连二烯醇,而没有发现高快丙醇的存在,由此提出了六元环过渡态的反应机理
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Fourthly, The preparation of 1 -triazolyl-2-isoxazolinyl substituted-ethenes was developed through an one-pot 1, 3-dipolar cycloaddition of NaN_3 and RI,α-alkylation reaction of substituted allyl bromides and 1, 3-dipolar cycloaddition of nitrile oxidesbased on polystyrene-supported propargyl selenide.
四、从聚苯乙烯负载的炔丙基硒醚出发,通过与叠氮化钠和碘化物的一锅法1,3-偶极环加成反应、取代烯丙基溴的α-烷基化反应和腈氧化物的1,3-偶极环加成反应固相合成了1—三唑—2—异噁唑啉取代的-乙烯。
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A new fullerene derivative containing energy-producing groups was prepared, and the reaction conditions affecting the yield were studied by the kroenecker method. The optimal reaction conditions with a 53.5% yield (based on consumed C60) are: 1:3:6 of molar ratio of C60 , o–nitrobenzaldehyde and sarcosine , 55℃ of reaction temperature, 12 h of reaction time, 40mL of toluene solvent.
利用N-甲基甘氨酸、邻-硝基苯甲醛和C60反应,合成分离出了含有硝基的新型富勒烯吡咯烷衍生物,通过正交试验对其工艺条件进行了研究,探讨了反应物剂量比、温度、时间和溶剂体积对产物产率的影响,得到了合成产物的最佳工艺条件:反应物剂量比为1:3:6、温度为55℃、反应时间为12h、溶剂甲苯体积为40mL,此时产物产率可达到53.5%(以消耗的C60计)。
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Some useful fluorine-containing intermedi-ates were synthesized by the reaction of activated methylenecompounds or silyl enol ether with 2,2-dihydropolyfluoro-alkanoates or 2-hydropolyfluoroalk-2-enoates in the presenceof different bases.
进一步研究表明,在氢化钠的作用下,苯乙腈,苄基苯基甲酮也可以与2-氢多氟-2-烯酸乙酯发生亲核加成反应,苄基苯基甲酮的加成中间体经多聚磷酸环化,得到了间位氟烷基取代的α-萘酚衍生物。
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The cis-decalin 79 was obtained from 2-methoxy-4-methylphenol (77) via a sequence of reactions involving intermolecular Diels-Alder reaction of masked o-benzoquinone derived from 77 and ethyl vinyl ketone, silyl enol ether formation and Cope rearrangement.
第一部份:以2-甲氧基-4-甲基酚(77)为起始物,经由二乙醯基亚碘苯氧化、分子间Diels-Alder反应、烯醇矽醚的形成及Cope重排反应得到具有十氢萘骨架化合物79。
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Chiral 3 methy 1,4 butanediol and its derivatives are the important intermediate of synthesis of chiral smectic liquid crystal polyesters and chiral natrual products with biological activity. In the paper, a new efficient route of 3 methyl 1,4 butanediol and its two derivatives, 2 methyl 4 tetrapyranyloxy 1 butanol and 2 methyl 4 tetrapyranylbutanal, was described, and the target products were synthesized by employing asymmetric hydroboration oxidation improved.
手性2-甲基-1,4-丁二醇及其衍生物是合成各种手性近晶型液晶材料以及手性天然生物活性物质的重要中间体,以3-甲基-3-丁烯-1-醇为原料利用改进的不对称硼氢化-氧化反应,成功地合成了-2-甲基-1,4-丁二醇以及其2种手性衍生物:-2-甲基-4-四氢吡喃氧基-1-醇和-2-甲基-4-四氢吡喃氧基丁醛。
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Poly silica hybrids were prepared through polymerization, condensation and sol gel processes of the mixture of methyl methacrylate, poly and a small amount of coupling agent methacryloxylpropyl trimethoxy siliane in tetrahydrofuran.
采用溶胶-凝胶技术,以硅酸钠为原料制备聚硅酸/四氢呋喃溶胶,再与甲基丙烯酸甲酯及少许偶联剂甲基丙烯酰氧丙基三甲氧基硅烷(MPTMS 混合,经聚合、缩合和溶胶-凝胶过程制备了有机/无机两相间有— C—Si—O—键的杂化材料——聚甲基丙烯酸甲酯/二氧化硅(PMMA/Si O2 )。
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Using tetrabutyl titanate and methyl methacrylateor 2-Hydroxyethylmethacrylate (HEMA as materials, methacryloxylpropyl trimethoxy siliane as coupling agent, HCl as catalyst, Poly-titania(PMMA-TiO2) nanocomposites and Poly-titania(PMMA-TiO2) nanocomposites were synthesized by sol-gel process.
以盐酸作为催化剂,将钛酸四丁酯水解制备二氧化钛(TiO2)溶胶;随后将所制备溶胶与甲基丙烯酸甲酯、硅烷偶联剂(γ-甲基丙烯酰氧丙基三甲氧基硅烷)相混合,以过氧化苯甲酰作为引发剂,经过聚合、缩合和溶胶-凝胶过程,制备了均匀透明的PMMA-TiO2纳米复合材料和PHEMA-TiO2纳米复合材料。
- 推荐网络例句
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With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.
随着死亡的吉他手Schuldiner接受主唱的职务,乐队在现实中树立了重要的影响。
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But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.
不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐,因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。
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Closes the eye, the deep breathing, all no longer are the dreams as if......
关闭眼睛,深呼吸,一切不再是梦想,犹如。。。。。。