烯基

The mechanism was supposed as follows: polyfluoroalkyl iodides were initiated by sodium dithionite to give R〓 which was added to one double bond of diallylacetic acid, after the sequential radical cyclization and nucleophilic substitution to form bicyclo-lactones.

这是因为：多氟烷基碘化物在连二亚硫酸钠的引发下，得到自由基R〓，后者加成到二烯丙基乙酸中的一个—C=C—双键上，然后在碱性介质中进行分子内亲核反应得到双环内酯类产物。

In another direction, the radical cyclization of thioimide with acylsilane produced simple cyclization product in low yield without expected enol silyl ether compound.

对於硫醯亚胺与矽基酮的自由基反应，则是得到低产率的简单环化产物，而不是预期的烯醇矽醚化合物。

A gas chromatographic-mass spectrometric method for the simultaneous determination of environmental estrogens (including 4-nonylphenol, bisphenol A,diethylstilbestrol and 17α-ethinylestradiol) and endogenous estrogens (including 17α-estradiol, 17β-estradiol, estriol and estrone) in urine and bed mud is reported.

报道了尿及河底泥中环境雌激素(壬基酚、双酚A、己烯雌酚、17α-乙炔基雌二醇)和内源性雌激素(17α-雌二醇、17β-雌二醇、雌三醇、雌酮)的气相色谱-质谱测定法。

Rice seed storage glutelin could be separated into three acidic and three basic subunit components by SDS-PAGE using 15%~25% gradient acrylamide gel.

利用15%～25%丙烯酰胺梯度凝胶的SDS-PAGE分析法可将水稻种子贮藏谷蛋白分离为3个酸性亚基和3个碱性亚基。

A novel carbonyl transposition led by anilines'nucleophilic addition to methyl 2-keto α-D-glucopyranoside was discovered. And the mechanism of the reaction concerned to an enol rearrangment was provided through tracing the change of 〓H-NMR and 〓C-NMR of a hemiacetal intermediate which was obtained in the reaction of o-phenylene diamine with 2-keto glycoside. Both the intermediate and the converting product were identified by 〓H-NMR,〓C-NMR,〓H-〓H COSY and HMQC.

一、发现了2-位氧化α-甲基D-葡萄糖苷的芳胺亲核加成引起羰基转位的新方法，利用核磁共振氢谱及碳谱对邻苯二胺与2-位氧化α-甲基D-葡萄糖苷加成生成的稳定中间体半缩酮化合物在氘代丙酮中的变化进行跟踪，结合对转化产物的氢氢相关谱和HMQC结构确证，提出了该反应中2-位羰基通过烯醇化互变而转至3-位的机理并得到了验证。

The solubility and the dissolution rate of cellulose in two ionic liquids with different structure AMIMCl and BMIMCl were investigated.

测定了纤维素在不同结构的离子液体——1-烯丙基-3-甲基咪唑氯化物和1-丁基-3-甲基咪唑氯化物中的溶解度和溶解速率。

The calculated adiabatic ionization potential is 8.18 eV, which is in excellent agreement with the experimental value. The result is helpful for identifying the allyl radical formed from other flames and for understanding the mechanism of soot formation.

计算的电离能与实验得到的电离能符合得很好，这一结果有助于今后鉴别和分析其它火焰中的烯丙基自由基，且对研究火焰燃烧机理有十分重要的价值。

The results showed that the thermo-sensitivity of hairy PNIPA changed obviously in the presence of hairy PAA as polyelectrolyte.4-cyanopentanoic acid dithiobenzoate as soluble reversible addition-fragmentation chain transfer agent was directly added into the above PS particles with photo-initiator on the surface and NVP or NIPA as monomer.

其次，将水溶性RAFT试剂直接引入上述光引发聚合体系，探讨连续相中RAFT试剂的存在对微球表面N-乙烯基吡咯烷酮或N-异丙基丙烯酰胺聚合的影响，考察了RAFT试剂对聚合过程中微球壳层高分子毛发厚度和单体转化率变化趋势。

The results show that the atmosphere has a big influence on the thermal stability of C_(60).C_(60) begins to decompose at 423.5℃in the air,the deomposed peak temperature is 668.5℃,but very stable in the helium atmosphere,only sublimate,the crystal shape of C_(60) has a certain influence to its thermal stability.The synthesized nine kinds of nitro-fullerene derivatives all have good thermal stability and their decomposed peak temperatures all exceed 350℃.The thermal explosion temperature for 5 seconds delay of product 4 is 253℃.The category,number and position of nitryl group in nitro-fullerene derivatives all have influence on their thermal stability.

利用差热分析仪和DSC-TG综合热分析仪对C_(60)及其硝基衍生物的热稳定性进行了研究，结果表明，环境气氛对C_(60)热稳定性影响很大，C_(60)在空气中423.5℃开始分解，放热峰值温度为668.5℃，在氦气中很稳定，仅表现为升华，C_(60)的晶型对其热稳定性也有一定的影响；合成得到的九种硝基富勒烯衍生物都具有较好的热稳定性，分解峰值温度均高于350℃；产物4的5秒爆发点测试结果为253℃。

In order to prepare bismaleimide/montmorillonite nanocomposites with high performance, Na-montmorillonite was modified with allyl-tri-phenyl phosphonium bromide via ion-exchange method.

通过离子交换法将烯丙基三苯基溴化交换到钠基蒙脱土的层间制备改性蒙脱土。

The labia have now been sutured together almost completely.The drains and the Foley catheter come out at the top.

此刻阴唇已经几乎完全的缝在一起了，排除多余淤血体液的管子和Foley导管从顶端冒出来。

To get the business done, I suggest we split the difference in price.

为了做成这笔生意，我建议我们在价格上大家各让一半。