烯基

Selected novel olefinic orthoesters, may be copolymerized with other olefins using certain late metal transition catalysts, to form novel polyolefins containing orthoester pendant groups.

利用某些后过渡金属催化剂，可以使选择的新颖烯烃原酸酯与其它的烯烃共聚合，以形成含原酸酯侧基的新颖聚烯烃。

The Suzuki reaction, the coupling of organoborate compounds with organic electrophiles catalyzed by Palladium complexes, is a valuable Csp2-Csp bond forming reaction. The reaction has been drawing increased attention in that the reaction permit the use of organoboron compounds that are thermally stable and inert to water and oxygen.In this section microwave promoted Suzuki reaction of phenylboronic acid with benzyl halides catalyzed by Pd(PPh3)2Cl2 DMF/H2O(v/v=10 : 2) was first reported.

第四章：微波辐射下Pd配合物催化端烯与芳卤偶联反应研究本章中我们在微波辐射条件下，研究了PdclZ(P Ph3)：催化端烯与芳卤的偶联反应，合成出了七种乙烯基化合物；并分别考察了微波辐射功率、辐射时间、原料配比、和PTc等因素对反应的影响，优选出了较佳的反应条件，并根据文献及实验结果，讨论了可能的反应机理。

Starting from 4-androstenedione, three novel 3-oxo-4-aza-5-androstene-17-oxime derivatives 7, 8 and 9 were synthesized through oxidation ring cleavage, amination ring closure, oximation,and substitution .

以4雄烯二酮为起始原料，经过氧化开环、氨解闭环、肟化、取代等4-步反应，合成了3个新的3-羰基-4-氮杂-5-雄甾烯-17肟衍生物7、8和9，并用质谱、1HNMR、13CNMR等测试手段对目标化合物的结构进行了表征

The reaction with propargyl sulfide gave a mixture of allenic sulfide and furan.The former is the [2,3]-sigmatropic rearrangement product,while the latter is derived from the furt...

同样条件下与炔丙基硫醚的反应则生成[2，3]-σ重排产物联烯和呋喃衍生物，后者是联烯进一步在Ru作用下重排的产物。

The reactions of benzaldehydes bearing an ortho substituent group on the phenyl ring with propargyl bromide may yield a mixture of regioisomers (homopropargyl and homoallenyl alcohols) or a single homoallenic alcohol due to the steric effect.

邻位上的取代基由于位阻原因往往使反应得到含有高丙二烯醇和高炔丙醇的混合物或者单一的高丙二烯醇。

A series of modified polyurethane elastomer materials with different amino siloxane content were synthesized,which were based on polyoxypropylene glycol,aminoethyl aminopropyl poly,toluene diisocyanate and the curing agent dimethylsulfide toluylenediamine.

以聚氧化丙烯二醇或聚氧化丙烯三醇、氨乙基氨丙基聚二甲基硅氧烷、甲苯二异氰酸酯为原料在无溶剂条件下制备预聚体，利用二甲基硫甲苯二胺为固化剂合成一系列氨基硅油改性聚氨酯弹性体材料，并对材料的力学性能、耐热性、表面水接触角等性能进行了测试。

The change for substitute group on chlorin ring of chlorophyll-a derivative and the effect on their visible spectra is discussed and summarized according to relation of electron effect and substituted position of different groups with conjugated region.

根据不同取代基的电子效应、取代位置与分子共轭区域的联系，提出二氮杂轮烯和四氮杂轮烯组成的非等原子芳香体系结构，总结了卟吩大环上的化学结构变化对其可见光谱的影响。

As superplasticizer , a series of comb-shaped copolymers of polycarboxylic acid were synthesized by polyoxyethylene allyl methyl diether, maleic anhydride, and styrene with different initiators,and esterified with PEO-n.

以聚氧乙烯甲基烯丙基二醚、顺丁烯二酸酐、苯乙烯等为共聚单体，采用不同引发剂，合成了一系列聚羧酸型梳状共聚物超分散剂，并以PEO n单酯化得酯化产物，研究了共聚物的结构、组成、添加量等对水泥粒子分散性能的影响。

The catalytic performance of PhTMG was evaluated in the reaction for synthesis of diethylene glycol bis via carbon dioxide route and the highest yield of ADC was 95.3%.

考察了PhTMG对以二甘醇、氯丙烯和CO2为原料合成二甘醇双烯丙基碳酸酯反应的催化性能，ADC的最高收率为95.3%。

The results suggested that the reaction temperature, the ratio of oil to water, the amount of ethyl cellulose as dispersant, initial monomers composition, the drop manner and the amount of initiator, the stirring speed, the pH of the buffer and the elution process have great influence on the morphology such as diameter of the hydrogel beads.

研究结果表明，采用反相悬浮聚合法，以丙烯酰胺和N-乙烯基吡咯烷酮为共聚单体，N，N'-亚甲基双丙烯酰胺为交联剂，牛血清白蛋白为模板，可以制备BSA印迹共聚物微球；反应温度、水油比、乙基纤维素分散剂用量、初始共聚单体配比、引发剂用量和加入方式、搅拌速度、水相pH值以及后续洗脱条件等均对粒径等微球结构和形态产生明显影响。

The labia have now been sutured together almost completely.The drains and the Foley catheter come out at the top.

此刻阴唇已经几乎完全的缝在一起了，排除多余淤血体液的管子和Foley导管从顶端冒出来。

To get the business done, I suggest we split the difference in price.

为了做成这笔生意，我建议我们在价格上大家各让一半。