烯基

Mol/L and calcinations temperature at 500?℃. The solid superacid can be used as catalyst two times in the alkylation of naphthalene, and the total composition of MIPN,DIPN, and TIPN in product is over 98%. When the consumpt...

在催化剂用量为 10 %、反应温度为 160℃、反应时间为 2 5h的条件下连续两次使用SO2 - 4 TiO2 超酸催化萘对丙烯的烷基化反应，产品中一异丙基萘、二异丙基萘、三异丙基萘的总含量大于 98%。

Further more, to make the hybrid microspheres with good dispersibility in aqueous media, 3-propyl triethoxysilane was added to copolymerize with St and DVB, and after hydrolization the microspheres with silanol groups on the surface were obtained, which can be well dispersed in water and used for cell imaging.

进而将3-甲基丙烯酰氧基丙基三甲氧基硅烷作为共聚单体，得到了表面硅羟基功能化的聚苯乙烯荧光微球，改善了微球在水相中的分散性，并将此类荧光功能微球成功用于细胞成像。

The related reaction conditions and factors such as catalysis of some catalysts etc were discussed. In the procedures, 2-pentylidene cyclopentanone intermediate, which could be isomerizated into a 2-pentyl cyclopentenone under acidic conditions, was effectively prepared in the presence of a phase transfer promotor.

讨论了正戊醛和环戊酮在碱性条件下缩合生成2-亚戊基环戊酮的反应温度、碱浓度、相转移催化剂等因素对反应的影响。2-亚戊基环戊酮中间体化合物能在酸催化剂作用下，异构成2-戊基环戊烯酮，其中酸浓度和溶剂等参数对反应影响明显。

The formation of charge transfer complex was studied in the first part. The second part includes the synthesis and characterization of the acrylated unsaturated polyester and the kinetic studies on the Ar-UPE/ triethylene divinyl ether (DVE-3) photocuring system, the rheology and properties of film after photocuring. The third part includes the synthesis and characterization of the urethane modified unsaturated polyester and the kinetic studies on the PU-UPE/DVE-3 photocuring system, the rheology and properties of film after photocuring. The fourth part includes the synthesis and characterization of the vinyl ether end capped polyurethane and the kinetic studies on the VE-PU/DVE3 photocuring system, the rheology and properties of film after photocuring.

整个研究工作分为四个部分：一是电荷转移复合物的研究；二是丙烯酰氧基化不饱和聚酯的合成，表征，Ar-UPE/二缩乙二醇二乙烯基醚（DVE-3）体系光固化动力学研究以及Ar-UPE/DVE-3体系流变性能和光固化后涂膜综合性能的研究；三是氨酯改性的不饱和聚酯的合成，表征，PU-UPE/DVE-3体系光固化动力学研究以及该体系光固化后涂膜综合性能的研究；四是乙烯基醚封端的聚氨酯的合成，表征，VE-PU/马来酸二甲酯体系光固化动力学研究以及VE-PU/DMA体系流变性能和光固化后涂膜综合性能的研究。

In Granards' reactionof fluorinated β-ketophosphonium salts we found differentGranard reagents give different reaction mechanisms andPhMgBr realized the enolate reaction of fluorinatedβ-keto-phosphonium salts.

在研究含氟β-酮基鏻盐的β位亲核加成反应中，我们利用含氟α-烷氧基-β-酮基鏻盐与有机锂试剂的亲核加成反应一锅法高度立体选择性地合成了E式或Z式三氟甲基的烯醚类化合物。

The silica/Polystyrene monocore-shell nanocomposite particles(95nm in diameter) were synthesized through miniemulsion polymerization by using sodium dodecyl sulfate surfactant,hexadecane costabilizer in the presence of silica particles(50nm in diameter) coated with methacryloxytrimethoxysilane.

采用细乳液聚合法，以3-甲基丙烯酰氧基丙基三甲氧基硅烷(KH570)表面改性的直径50nm的氧化硅粒子为核，在乳化剂、助乳化剂、引发剂存在的情况下制备了小粒径、单核核壳结构氧化硅/聚苯乙烯纳米复合微球。

The beta-thioalkoxyalcohols could be obtained in good yields by the reaction of dialkyl-substituted propargylic dithioacetals with a series of carbonyl compounds.

我们发现在铁触媒和格林那试剂的存在下，利用双烷基取代炔丙基硫缩酮和羰基化合物反应生成的beta-硫烷氧基醇，可以进行不常见的beta-氧消去反应，而得到烯炔衍生物。

In chapter four, molecular imprinting polymers against amino acid derivatives utilizing 2-VP+AM as combined functional monomer and trimethylolpropane trimethacrylate as tribasic cross-linker were prepared and result was compared with those with the same amino acid derivative as the imprinted molecules utilizing ethyleneglycol dimethacrylate as dibasic cross-linker. It was found that cross-link intensity of the molecular imprinting polymer is higher when TRIM was utilized and baseline separation for the imprinted molecule could be achieved. When TRIM was utilized as cross-linker more molecule is imprinted during the polymerization.

第四章采用2-乙烯基吡啶+丙烯酰胺复合功能单体，考察了三元交联剂三甲氧基丙烷三甲基丙烯酸酯烙印氨基酸衍生物的情况，并与二元交联剂乙二醇二甲基丙烯酸酯烙印相同氨基酸衍生物的情况进行了对比，发现三甲氧基丙烷三甲基丙烯酸酯交联剂在较小的用量下就可使分子烙印聚合物达到足够的交联度，实现烙印分子的基线分离。

Further studies on the sulfinatodehalogenation of I〓 with olefinsindicated that either symmetrically and unsymmetrically disubstituted adducts could beobtained depending on the amount of 〓 and temperature. Non-fluorinated compounds (such as dichloro-, chloroacetates, chloroform) andCFCs e.g.

由于此反应能被对二硝基苯和对苯二酚（HQ阻止，光照反应加速，且与二烯丙基醚反应时得到的产物为四氢呋喃衍生物，所以我们推断反应历程是一个自由基反应过程。

Comb-shaped copolymer of polycarboxylate containing carboxyl,sulfonic groups(-SO3M),polyethylene glycol(-OC2H4-) was synthesized by monomers of sodium 2-acrylamido-2-methylpropane sulphonate,acrylic acid,polyethylene glycol monoester acrylate under certain conditions.

本文通过2-丙烯酰胺-2甲基丙基磺酸钠与丙烯酸、聚乙二醇单丙烯酸酯在一定条件下发生聚合反应合成含有羧基、磺酸基(—SO3M)、聚氧乙烯链(—OC2H4—)等侧链的高性能减水剂PC。

The labia have now been sutured together almost completely.The drains and the Foley catheter come out at the top.

此刻阴唇已经几乎完全的缝在一起了，排除多余淤血体液的管子和Foley导管从顶端冒出来。

To get the business done, I suggest we split the difference in price.

为了做成这笔生意，我建议我们在价格上大家各让一半。