烯基

The originalprocedure has subsequently been replaced by milder and more environmentallyfriendly conditions. We tried to alkylate 3,4,5-trimethoxytoluene by2-allylphenylbenzyl ether in the presence of N-bromosuccinimide.

本实验是在溴代琥珀酰亚胺的作用下使2-烯丙基苯基苄基醚产生苄正离子，苄正离子亲电进攻3，4，5-三甲氧基甲苯从而进行傅氏烷基化反应的。

Of these end groups those having an allylic chlorine might be expected to show the highest activity.

在这些端基中，带有烯丙基氯原子的端基活性最高。

Then Doripenem came into the market in the July ,2005. We studied the synthesis of Doripemen.Firstly, we synthesized the chemical 2 from the starting material------o-hydroxylphenylacylamine through Reformastky reaction, alkylation, Diekmann reaction, enolization, esterification and etc. Secondly, we synthesized the chemical 3 from L — hydroxylproline through the protection of carboxyl, amidogen and hydroxyl group, reduction by NaBr, SN_2 substitution and Mitsumobu reaction.

我们以水杨酰胺为起始原料，经Reformatsky反应、烷基化、Diekmann环合、烯醇化、酯化等反应合成双环母核2；再从L-羟基脯氨酸出发，经酯化保护羧基、保护氨基、保护羟基、硼氢化还原酯得醇、Sn2取代和Mitsumobu反应等合成巯基侧链3；最后由化合物3经脱保护、水解得硫醇，和化合物2在二异丙基乙基胺的作用下缩合，最后Pd／C催化脱保护，历经16步反应最终得到产物多尼培南。

Moreover, the polymeric arsine palladium(0) complex is an efficient catalyst for the carbonyl allylation of aldehydes and the coupling reaction of aryl halides with terminal alkynes or Grignard reagent.

该聚合物负载的胂钯(0)配合物还是醛的羰基烯丙基化及芳基卤化物与端炔、Grignard试剂的交叉偶联反应的有效催化剂。

The present invention relates to a thermoplastic interpolymer product comprising an alpha -olefin interpolymerized with at least one vinyl or vinylidene aromatic monomer and/or at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene aromatic monomer and, in at least one aspect, is characterized as having substantially synergistic thermal properties.

本发明涉及一种包含与至少一种乙烯基或亚乙烯基的芳族单体和/或至少一种受阻的脂族或环脂族的乙烯基或亚乙烯基芳族单体共聚的α－烯烃热塑性共聚体产物，及至少一方面，其特征为具有实质协同热性质。

Using N, N-dimethyl-ethylenediamine as cationic substitute and 2-hydroxyethyl methacrylate or allylamine as co-substitute, a kind of pH-sensitive polyorganophosphazenes bearing unsaturated side group was prepared.

以N，N-二甲基乙二胺为阳离子型取代基，甲基丙烯酸羟乙酯或烯丙胺为共取代基，制备了同时带有pH响应性侧基和不饱和双键侧基的聚膦腈。

The preparation of avermyctin emulsions in water was achieved by mixing the surfactants polyoxyethylene (10) octylphenyl ether (OP10), polyoxyethylene styrenated phenol ether (602), and polyoxyethylene (40) castor oil ether (EL-40) with polyoxyethylene (20) castor oil ether (EL-20), separatively. Emulsion stability was investigated by analyzing the hydrophile-lipophile balance, critical micelle concentration, and surface tension. Then, the surfactants of polyoxyethylene polyoxypropylene styrenated phenol ether (1601), block copolymer (L64), and octyl phenyl polyoxyethylene phosphonate were added to the emulsion made by blending EL-40 and EL-20, separatively. The stability of the emulsions was investigated further and discussed in terms of droplet size, surface tension, and zeta potential.

首先将辛基酚聚氧乙烯醚(OP10)、苯乙烯基酚聚氧乙烯醚(602)和蓖麻油聚氧乙烯(40)醚(EL-40)分别与蓖麻油聚氧乙烯(20)醚(EL-20)复配制备阿维菌素水乳剂，从亲水亲油平衡值、临界胶束浓度、表面张力等方面分析了二元表面活性剂复配对乳液稳定性的影响；其次，在EL-40与EL-20复配基础上，将苯乙烯基酚聚氧乙烯聚氧丙烯醚(1601)，嵌段共聚物(L64)和辛基酚聚氧乙烯醚磷酸酯分别添加到乳液中，从粒径、表面张力和zeta电势等方面考察三元表面活性剂复配对乳液稳定性的影响。

Thestercoselectivity of the reaction of propargylide was different completely from that of the reactionof telluronium 3-trimethylsilylalltide with α,β-unsaturaled ketones and trans-trimethysilylacetylenyl-l-benzoyleyelopropane derivatives were obtained.

发现这一反应的立体化学与同样条件下含硅烯丙基碲叶立德和α，β-不饱和酮反应的立体化学完全不同，得到的是又式-2-三甲基硅基乙炔基-1-酮基环丙烷衍生物。

A series of tri-block copolymers of styrene/tetradecyl methyl acrylate/3-methacryloxyl-propyl thimethoxyl silane was synthesized by atom transfer radical polymerization. The structures of those copolymers were characterized by means of gel permeation chromatography, infrared spectrum, and nuclear magnetic resonance (1H-NMR). Effect of tri-block copolymers on the mechanical properties of glass fiber/polypropylene composites was also investigated.

采用原子转移自由基聚合法合成了一系列新的三嵌段共聚物大分子偶联剂聚苯乙烯－b-聚甲基丙烯酸十四酯－b-聚3-甲基丙烯酰氧基丙基三甲氧基硅烷，通过凝胶渗透色谱、红外光谱和核磁共振(1H-NMR)证实了其结构，并研究了其对玻璃纤维／聚丙烯复合材料力学性能的影响。

MS results revealed that 3- propionaldehyde was transferred into 3- propanol, 3- propanoic acid, 3 ethanol, 3- timonacic.

质谱鉴定其转化产物有甲硫基丙醇、甲硫基丙酸、甲硫基乙醇、甲硫基丙烯。

The labia have now been sutured together almost completely.The drains and the Foley catheter come out at the top.

此刻阴唇已经几乎完全的缝在一起了，排除多余淤血体液的管子和Foley导管从顶端冒出来。

To get the business done, I suggest we split the difference in price.

为了做成这笔生意，我建议我们在价格上大家各让一半。