烯基

P-Isopropylphenol was synthesized by catalytic transfer dehydrogenation with 5% Pd/C using 4-isopropylcyclohexenone as the material and the hydrogen offer, industrial dipentene as the hydrogen acceptor and the solvent.

采用5%Pd/C作为转移氢催化剂，4-异丙基环己烯酮为氢给予剂，工业双戊烯为氢接受剂和溶剂进行反应，合成了对异丙基苯酚。

In addition, ioding was found to be an efficient catalyst for the imino Diels-Alder reaction of N-arylimine and enol ethers and the reaction provided tertrahydroqinolines in good yields. One pot synthesis of tetrahydroqinolines from aldehyde, aniline and enol ethers was also achieved using iodine as the catalyst. The chemical yield of the"one pot"reaction was comparable with that obtained using preformed N-arylimine.

此外我们也发现碘能够有效地催化N-芳基亚胺与烯醇醚的Diels-Alder反应，以很高的化学收率得到了四氢喹啉衍生物，并且发现碘也能够直接催化芳香醛、苯胺、烯醇醚的三组分&一锅&反应，获得的化学产率与使用预制的N-芳基亚胺相当。

The results indicated isoprene was soon consumed under the condition of excess ozone. During the reaction, the major carbonyl products formed were methyl vinyl ketone, methacrolein, methylglyoxal, and formaldehyde. Formic acid, CO and CO2 were also among the products.

在反应温度(294±2)K，压力为1.01×10^5Pa空气，O3过量的条件下，异戊二烯很快反应完全，反应中生成的羰基产物主要包括甲基丙烯醛、甲基乙烯基酮、丙酮醛和甲醛；产物中还包括甲酸、一氧化碳和二氧化碳。

Brominated butyl rubber was prepared by solution method,and its microstructures were characterized by 1H-NMR. It has three main microstructures,that is the unbrominated isoprene structure,the exomethylene allylic bromide structure (structure Ⅱ) and the bromomethyl olefinic structure (structure Ⅲ).

通过溶液法制备溴化丁基橡胶，并用核磁共振对溴化丁基橡胶的微观结构进行了分析，其中存在3种主要微观结构，即未溴化的丁基橡胶结构，溴代仲位烯丙基结构及溴代伯位烯丙基结构。

In addition, the invention further relates to a catalyzer combination used for polymerizing a conjugated dialkene monomer and the anions of an optional mono-vinyl aromatic hydrocarbon into a polydiene polymer having high and medium vinyl content. The catalyzer combination comprises an organolithium compound used as an anionic polymerization initiator, at least an alkali metal alkoxide compound expressed by the formula as a structure regulator.

此外，本发明还涉及一种用于将共轭二烯烃单体和任选的单乙烯基芳烃阴离子聚合成具有中高乙烯基含量的聚二烯聚合物的催化剂组合物，其包含作为阴离子聚合引发剂的有机锂化合物，和作为结构调节剂的至少一种式所示的碱金属醇盐化合物。

With industrial monomer solution of dimethyldiallylammonium chloride as raw material, ammonium persulphate as initiator and Na_4EDTA as chelating agent,using the methods of adding initiator all at once,graduated increasing of temperature and stepwise initiation and polymerization,the polymerization process of preparing poly-dimethyldiallylammonium chloride was researched.

以一步法工业单体二甲基二烯丙基氯化铵为原料，以过硫酸铵为引发剂，采用一次性加入引发剂，梯度升温，分步引发水溶液聚合反应的方法，对制备聚二甲基二烯丙基氯化铵的聚合反应的工艺进行了优化研究。

The copolymer of N isopropylacrylamide and acrylamido azobenzene was synthesized for the study of the effect of the photoisomerization of a water soluble copolymer containing azobenzene groups on the photocontrolled release behavior of liposomes.

为了研究侧链含有偶氮苯基的水溶性共聚物的光异构化对脂质体内包容物的光控释放的影响，设计合成了N－异丙基丙烯酰胺和丙烯酰胺基偶氮苯的共聚物。

Twenty-seven compounds were isolated from the methanol extract of the stems of Pinus massoniana by means of chromatographic methods, and their structures were elucidated as 8(14),15-Pimaradien-19-oic acid (1), Pimaric (2), Podocarpic acid (3), 12-Hydroxydehydroabietic acid (4), Dehydroabietic acid (5), 15-Hydroxydehydroabietic (6), 3β-Methoxyserrat-14-en-21-one (7), 3β-Hydroxy- serrat- 14-en-21-one (8), 3β-Methoxyserrat-14-en-21-one-30-al (9),(24R)-Stigmst- 4-ene-3-one (10),β-sitosterol (11),-3-Hydroxy-5-methoxy-stilbene(12), 4-Hydroxy-3- methoxycinnamaldehyde (13),-Ferulic acidtetracosyl ester (14), Alkylferulates (15), Pinocembin (16), Coniferaldehyde (17), Matairesinol (18),-Nortrachelogenin (19), Balanophonin (20), Cedrusin (21),-Pinoresinol (22), Tanegoside (23), 1,2-Bis-(4-hydroxy-3- methoxyphenyl)-propane-1,3-diol (24),(1S*, 2S*)-1-(4- Hydroxyphenyl) glyceri...

同时对马尾松枝条的甲醇提取物利用各种色谱技术进行了分离纯化，并利用现波谱技术鉴定了27个化合物的结构，分别为：8(14)，15-Pimaradien-19-oic acid (1)、海松酸(2)、罗汉松酸(3)、12-羟基脱氢松香酸(4)、脱氢松香酸(5)、15-羟基-脱氢松香酯(6)、3β-甲氧基-锯齿石松-14-烯-21-酮(7)、3β-Hydroxyserrat-14-en-21-one (8)、3β-Methoxyserrat-14-en-21– one-30-al (9)、(24R)-豆甾-4-烯-3-酮(10)、-3-羟基-5-甲氧基-二苯乙烯(12)、4-Hydroxy-3-methoxycinnamaldehyde (13)、-Ferulic acidtetracosyl ester (14)、Alkylferulates (15)、Pinocembin (16)、Coniferaldehyde (17)、罗汉松树脂酚(18)、 Balanophonin (20)、tanegoside (23)、1，2-Bis-(4-hydroxy- 3-methoxyphenyl)-propane- 1，3-diol (24)、(1S*，2S*)- 1-(4-hydroxyphenyl)glycerins (25)、(1R*，2R*)-1-(4-hydroxy- phenyl)gly-cerins (26)和赤松素(27)。

Because the limonene does not have a carbonyl group, the small amount of it which remainsin the carvone fraction will not form a semicarbazone derivative.

由于柠檬烯没有羧基，留在香芹酮馏份中少量的柠檬烯将不会产生缩胺基脲的衍生物。

The synthesis of hyperbranched poly based upon 1,2-bis diallyl (methyl silyl ethane (B4) as a core molecule and diallyl silane (AB2) monomer via hydrosilylation addition have been investigated: And the hyperbranched poly were prepared using onestep without core, one-step with core and pseudo-one-step methods.

以四烯丙基硅烷(B4)为核、甲基氢二烯丙基硅烷(AB2)为单体，通过硅氢加成反应，采用无核一步法、核一步法、核多步法合成了超支化聚有机硅破烷。

The labia have now been sutured together almost completely.The drains and the Foley catheter come out at the top.

此刻阴唇已经几乎完全的缝在一起了，排除多余淤血体液的管子和Foley导管从顶端冒出来。

To get the business done, I suggest we split the difference in price.

为了做成这笔生意，我建议我们在价格上大家各让一半。