烯基

The photocycloaddn. of 1-naphthonitrile (1-NpCN) and 2,3-dimethyl-2-butene in cyclohexane or benzene gave cyclobutane I primarily, but that of 2-NpCN gave azetine II as the major and cyclobutane III as the minor product in low conversion photolysis. The photocycloaddn. of 1-NpCN with DMB is retarded by increasing amts. of trifluoroacetic acid which is shown to form non-photoreactive complexes with ground state as well as with singlet excited state 1-NpCN. It also quenches the *(1-NpCN-DMB) exciplex.

在低转光解情况下，1-萘甲腈(1-NpCN)和2，3-二甲基丁烯-2在环已烷或苯中的光环加成反应主要得到环丁烷3，但2-NpCN主要得到氨杂环丁烯6和少量的环丁烷5，三氟醋酸量增加抑制1-NpCN和DMB的光环加成反应，表明TFA与基态及单激发态1-NpCN生成非光反应的复合物，它也淬灭^*(1-NpCN-DMB)激基复合物。

OH radicals produced by ultrasound in aqueous solution attack phenolic cycle at adjacent or para position of the hydroxyl on phenol so that phenol is changed into small organic molecules such as muconic acid, maleic acid and ethane diacid. These small organic molecules will be oxidized to form carbon dioxide and water by.

苯酚超声降解的作用机理是，超声空化在水溶液中产生的·OH自由基进攻苯酚苯环上羟基的邻位或对位而使苯环断裂生成己二烯酸、顺式丁烯二酸和乙二酸小分子有机物而使苯酚得以降解，这些小分子有机物在·OH自由基的进一步作用下最终被氧化成CO〓和H〓O。

CONCLUSION摘要: Diallyl trisulfide coated stent could significantly enhance the iNOS expression and NO production, which may play an important role in inhibiting neointimal hyperplasia.

结论摘要：二烯丙基三硫化物涂层支架可显著增加iNOS表达，并提升NO产量，提示二烯丙基三硫化物涂层支架可能是抑制内膜增生的一个重要机制。

Objective To study the effects of diallyl trisulfide on proliferation, apoptosis and cell cycle in acute myeloid leukemia cells HL-60 and the probable mechanism involved, aiming at offering credible academic and experimental bases for clinical use.

目的：研究二烯丙基三硫对急性髓细胞系白血病细胞株HL-60细胞增殖、凋亡及细胞周期的影响并探讨其作用机制，为二烯丙基三硫用于临床防治癌症提供可靠的理论基础和实验依据。

Part 1 Effects of DATS on proliferation of human bladder carcinoma T24 cells Objective To investigate the effects of diallyl trisulfideon growth inhibition, cell cycle and corresponding molecular mechanism of T24 cells.

中文摘要：第一部分二烯丙基三硫化物对人膀胱癌T24细胞增殖的影响目的研究大蒜提取物二烯丙基三硫化物于体外对人膀胱癌细胞系T24细胞增殖和细胞周期的影响及其可能机制。

Diallyl trisulfide coated stent could significantly enhance the iNOS expression and NO production, which may play an important role in inhibiting neointimal hyperplasia.

二烯丙基三硫化物涂层支架可显著增加iNOS表达，并提升NO产量，提示二烯丙基三硫化物涂层支架可能是抑制内膜增生的一个重要机制。

Diallyl trisulfide coated stent could significantly enhance the iNOS expression and NO production, may play an important role in inhibiting neointimal hyperplasia.

二烯丙基三硫化物涂层支架可显著增加iNOS表达，并提升NO产量，提示二烯丙基三硫化物涂层支架可能是抑制内膜增生的一个重要机制。

In chapter four, the preperation of ytterbium diiodide was examined. The reductive cleavage of Se-Se bond and S-S bond induced by ytterbium diiodide was investigated. The reaction of diselenides and disulfides with allylic bromide promoted by ytterbium diiodide was also examined. The intermolecular Barbier-type reaction induced by ytterbium diiodide was studied. In the last section of this chapter, the intermolecular reductive coupling of nitriles with azides induced by samarium diiodide was investigated.

第四章，研究了二碘化镱的制备方法，以及二碘化镱作为一种优良的单电子转移试剂在有机合成中的应用：二硒醚的Se--Se键和二硫醚S-S键的还原断裂，及其在合成烯丙基硒醚，硒代酯和烯丙基硫醚，硫代酯中的应用，实验结果表明二碘化镱也能促进分子间的Barbier反应，而文献认为二碘化镱不能促进分子间的Barbier反应；最后研究了二碘化钐促进的叠氮化合物与腈的交叉还原偶联反应，一步高收率地制备脒的方法。

Trifluoromethyl-3-heptadfluoroisopropyl-2-perfluoropentene-4-(N',N'-dimethylamino propyl) imino was prepared by the reaction of hexafluoropropene timer with N,N-dimethyl propanediamine in the molar ratio 1:1.0 at room temperature for 8h, and the structures of VIII were identified by IR and NMR spectra.

以六氟丙烯三聚体与N，N-二甲基丙二胺为原料合成叔胺2-三氟甲基-3-七氟异丙基-2-全氟戊烯-4-(N'，N'-二甲胺丙基)亚胺，利用红外光谱和核磁共振确定其结构，并通过对合成条件的考察得其最佳合成条件：乙醚为溶剂，碳酸钠为缚酸剂，摩尔投料比为1：1.0，在室温下反应8小时。

With the aim of enhancing the nonlinear optical property of poly, poly[(thiophene-2,5-diyl)p-(N,N-dimethylamino) azobenzylidene] is prepared from 4-aldehyde-4'-dimethylamino azobenzene and thiophene through condensation polymerization reaction.

为了提高聚噻吩甲烯的非线性光学性能，通过4-醛基-4'-二甲胺基偶氮苯和噻吩的缩聚反应，合成了聚噻吩对二甲氨基偶氮苯甲烷，再用PTDMAAB与四氯苯醌发生脱氢反应合成了侧链含偶氮的聚噻吩甲烯。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。