烯基

The thermolysis of the isomerized products derived from norbornadiene-coordinated carbonyl iron complexes gave two sorts of the thermolytic products based on different substituents on the olefin ligands. One is the corresponding diiron dimer complex, and the other is the complex in which the C-C bond of the cycloolefin ligand is broken.

以降冰片二烯三羰基铁络合物衍生出来铁卡宾络合物的异构化产物的热解，随着烯烃配体上取代基的不同，而分别得到了络合物发生二聚和烯烃配体发生碳碳键断裂的两类热解产物。

On the base of molecular structure design, the mechanism and technique of the synthesis of 2-(acryloyloxy ethyl trimethyl-ammonium chloride/2-acrylamido-2methylpropane sulfonic acid/acrylamide (AETMAC/AMPS/AM) amphoteric terpolymers by radical co-polymerization in aqueous solution was studied systematically.

依据分子结构设计理论，将2—丙烯酰氧乙基—三甲基氯化铵/2—丙烯酰胺基—2—甲基丙烷磺酸/丙烯酰胺(AETMAC/AMPS/AM)三种单体进行水溶液自由基共聚，合成了AP系列两性离子聚合物。

Among the variousα-oxo ketene dithioacetals,α-alkenoyl ketene dithioacetals are easier to prepare and bear much more functionalities.

在众多的α-羰基二硫缩烯酮类化合物中，α-烯酰基二硫缩烯酮具有易于制备，官能团多等特点。

Two classes of specific binding sites in the polymer matrix were investigated by Scatchard analysis, which indicated that two kinds of complexes between functional monomers and templates were formed before the polymerization process. Comparing with the structure of TNT and acrylamide, one kind of complex between TNT and acrylamide was strongly charge-transfer complexing interaction by p-πcomplex between electron-rich amino group of acrylamide and electron-deficiecy-benzene ring of TNT, the other was hydrogen bonding interaction between amino group (-NH_2) of acrylamide molecule nitro group (-NO_2) of TNT.

Scatchard分析结果表明，在TNT印记聚合物微球中存在两类结合位点，这表明在聚合反应之前，TNT与功能单体丙烯酰胺分子之间存在两种不同类型的作用力而自组装成两类的模板分子-功能单体复合物，一类可能是由于富电子的丙烯酰胺和缺电子的TNT的苯环通过p-π配键而形成的电荷转移复合物，另一类可能是由于丙烯酰胺的胺基与TNT的硝基之间的氢键作用而形成的复合物。

The synthesis of divinyl liquid crystalline monomer 4-undecenyloyloxybenzoyl-4'-allyloxybenzoyl-p-benzenediol bisate and network polymers was described. The chemical structures of the synthesized monomer and network polymers were confirmed by FT-IR spectrum.

以双烯类液晶单体4-十一烯酰氧基苯甲酸-4'-烯丙氧基苯甲酸对苯二酚双酯为交联剂，通过与聚矽氧烷接枝反应，合成了系列网络聚合物P1~P5。

Synthesis of organic sulfuric compounds in aqueous media is carried out by: using thio-olefin compounds with carbonyl compounds, acetal/keltone, hydrazone, oxime, osazone and enamine to synthesize mercaptal/keltone compounds in aqueous media; using thio-olefin compounds with alpha-hydroxyaldehyde/keltone or alpha-halogenated aldehyde/keltone to synthesize thia-olefin derivatives in a queous media; using thio-olefin compounds with alpha, beta-unsaturated hydroxy compounds, C-C treble bond, C-N treble bond, C-C double bond, N-N double bond, C-N double bond, C-S double bond, epoxy and its derivatives, aziridine and its derivatives, cyclopropane and its derivatives and halogenated carboxy to synthesize sulfoether compounds in a queous media.

含水介质中有机硫化合物的合成方法，本发明属于有机合成方法，用硫缩烯酮类化合物与羰基化合物、缩醛/酮、腙、肟、脎、烯胺在含水介质中合成缩硫醛/酮化合物，与α-羟基醛/酮或α-卤代醛/酮在含水介质中合成噻烯类衍生物，与α，β-不饱和羰基化合物、碳碳叁键、碳氮叁键、碳碳双键、氮氮双键、碳氮双键、碳硫双键、环氧乙烷及其衍生物、氮杂环丙烷及其衍生物、环丙烷及其衍生物、卤代烃等在含水介质，中合成硫醚化合物。

Was applied to the AD reaction of eight olefins in PEG/NMO system according to the protocol of ligand 8. The yields and ees of the diols were 70～90% and 77～96%(except for trans-5-decene and ally naphthyl ether) respectively.

在与8相同的催化反应条件下，手性配体9催化八种烯烃的AD反应得到的化学产率和ee值分别为70～90％和77-96％（反式-5-癸烯和萘基烯丙基醚除外）。

The yields were 67～89% and 61～90% respectively, and the ees were 66～99. 9% and 68～99. 9% respectively (except for trans-5-decene and ally naphthyl ether). With trans-stilbene as the substrate, chiral ligands and OsO〓 could be recovered and reused five times in the AD reaction with high catalytic activity and stereoselectivity.

4在PF〓/NMO体系中，将配体8和10分别用于八种烯烃的AD反应，配体、OsO〓和底物的摩尔比为0.02/0.015/1时，化学产率分别为67～91％和61～90％，ee值分别为66～99.9％和68～99.9％（反式-5-癸烯和萘基烯丙基醚除外）。

Has been isolated and identified, by MS-GC, 27 compounds of which main consti tuents are 1,8-cineol, comphor, pinene, terpinol, cabinene, terpinene, tert-buty- penZene, phellandrene, coaryphyllene, sabinene.

河南辛夷的挥发油，通过气相色谱—质谱分离鉴定出27个成份1.8按叶素、樟脑、蒎烯、松油醇、杜松烯、松油烯、特丁基苯、菲兰烯、丁香烯、桧烯为其主要成份。

In order to decrease copolymerization loss of isoprene during thermal dimerization of cyclopentadiene in C5-fraction,the effect of three inhibitors,diethylhydroxylamine,p-tert-butylcatechol and o-nitrophenol,on dienes' polymerization in the process was investigated by experiment with sealed glasstube.

为减少C5馏分环戊二烯热二聚过程中异戊二烯的聚合损失，采用封管实验方法考察了添加阻聚剂二乙基羟胺、对叔丁基邻苯二酚、邻硝基苯酚对热二聚过程中各二烯烃组分聚合程度的影响。

By using competitive adsorption of activated carbom to remove unfavorable influence of carbon in carbonaceous gold concentrate on leaching process, the leaching rate of gold concentrate can be improved to 88% as compared with 10%by direct cyanidation.

本文论述了利用活性炭竞争吸附作用，消除含炭金精矿中炭在浸出过程中的影响，使金精矿的浸出率可由直接氰化的10％提高到88％。

The only thing you're ever gonna be king of is King of the Stupids!

你只配做傻瓜的国王！