烯基

In chapter three, the activating agents of ytterbium have been examined. Barbier-type reaction promoted by ytterbium metal was examined. The experimental results shown that the yield of Barbier reaction of imines with allylic bromide promoted by ytterbium is higher than that of aldehydes and ketones with allylic bromide under the same reaction conditions. In this chapter, the reductive cleavage of Se-Se and S-S bond induced by ytterbium metal was also studied.

首先研究了金属镱的活化剂以及活化方法，接着考察了金属镱促进的Barbier反应及其在合成高烯丙基胺和高烯丙基醇中的应用，以及影响该反应的主要因素；究了金属镱促进的二硫醚和二硒醚的S—S键和Se—Se键的还原断裂，继而与氯代烃，胺基甲酰氯反应生成相应的硫醚，硒醚，胺基甲酸硫代酯和硒代酯。

Compareing with essential oil of the steam distillation method and the bensine solvent extraction method through GC-MS analysis .The result showed that:the essential oil principal constituent extracted by benzine is camphene,a-pinene,bornyl acetate, limonene, 1-methyl-4-(1-methylethyl)-1,4-cyclohexadiene, myrcene, caryophyllene, borneol.

对巴山冷杉针叶水蒸气蒸馏和石油醚萃取所得精油的GC-MS 分析对比研究结果表明：石油醚萃取精油主要成分为：莰烯，a-蒎烯，乙酸龙脑酯，柠檬烯，1-甲基-4-异丙基-1，4-环己二烯，月桂烯，石竹烯，龙脑。

Various inorganic acid, such as ammonium chloride, copper sulfate, aluminum sulfate, mercury chloride, cerium sulfate and cerium chloride, have been evaluated for copper powder, zinc powder, or tin powder-mediated allylation reactions of carbonyl compounds with allyl bromide in aqueous medium.

结果表明：在同样的反应条件下，与铜粉或锌粉作用的此类反应相比，锡粉能更好的作用羰基烯丙基化反应，并且该反应的产率都比较高；在同样的金属促进剂存在下，硫酸亚铈的促进性能是所有无机酸中最好的。 2、研究了二氧化碳促进羰基化合物烯丙基化反应。

The catalyst, palladium supported with chitosan condensated with salicylaldehyde, was studied in hydrogenation ofα-octene, nitrobenzene, 4-nitrophenol and m-dinitrobenzene, it was active and good selectivity forα-octene and nitrobenzene, when the activation time is 90 min, the catalyst showed the best hydrogenation active.

壳聚糖缩水杨醛负载不同比例PdCl_2的催化剂对α-辛烯、硝基苯、4-硝基酚和间二硝基苯的催化性能进行了研究，结果表明该催化剂活化90 min时加氢催化活性最好，对α-辛烯，硝基苯的催化选择性在催化5 h时达到了100%。

Water,c12-20 acid peg-8 ester,octyldodecanol,cetearyl isononanoate,butylene glycol,biosaccaride gum-1,peg-40 hydrogenated caster oil,ethylhexyl menthoxycinnamate,phenoxyethanol,potassium cetyl phosphate,macadamia ternifolia seed oil,dimethicone,carbomer,propylene glycol,glyceryl stearate,cocoglycerides,butyrospermum parkii,c12-13 alkyl lactate,methylparaben,benzophenone-3,pentadecalactone,sorbic acid,citrus aurantium dulcis oil,sodium hydroxyde,tocopheryl acetate,disodium edta,iris germanica root extract,retinyl palmitate,equisetum arvense extract,butylparaben,peg-8,propylparaben,ethylparaben,sodium hyaluronate,chlorhexidine digluconate,citrus aurantium amaraoil,tocopherol,ascorbyl palmitate,citric acid,ascorbic acid,limonene,linalool

水，c12-20 acid peg-8 ester，辛基十二烷醇，鲸蜡硬脂醇异壬酸酯，丁烯二醇，多醣物质，PEG-40氢化蓖麻油，4-甲氧基肉桂酸-2-乙基己基酯，苯氧乙醇，十六烷基磷酸钾，澳洲胡桃子油，地美司康，卡波姆，丙烯乙二醇，甘油硬脂酸，椰油脂酸甘油酯类，牛油果，c12-13烷醇乳酸酯，对羟基苯甲酸甲酯，二苯甲酮-3 ，环十五内酯，山梨酸，甜橙油，氢氧化钠，维生素E醋酸酯，乙二胺四乙酸二钠，鸢尾花萃取，维他命A酯，问荆萃取，对羟基苯甲酸丁酯，聚乙二醇- 8，羟苯丙酯，羟苯乙酯，透明质酸钠，洗必泰葡萄糖酸盐，苦橙油，维生素E ，维生素C棕榈酸酯，柠檬酸，抗坏血酸，柠檬精油，沉香醇水：几乎所有护肤品成分第一位都是水。辛基十二烷醇：界面活性剂、乳化剂、稠化剂，有一定刺激性

Other methyl nucleophiles includingMeMgBr, MeCeCl2, MeTiCl3, Me3Al, Me3ZnMgCl, MeMnClwere tried, but in all these cases no detectable amount of exo-C8-methylated product was obtained. Although protecting C3-carbonyl as 1,3-dioxolanes could be achieved, the serious enolization of C8-carbonyl was still problematic. Converting C9-furan ring to α,β-butenolide did depress the enolization, but desired C8-methylation was completely replaced by migration of the double bond of the butenolide.

在本论文的早期阶段，主要着眼于解决二环[3.2.1]-C8-羰基加成甲基所遇到的C9-呋喃环差向异构化和C3与C8两个羰基之间化学选择性的问题：通过引入不同金属降低甲基试剂的碱性并没有取得甲基化的成功；通过不同的方法将C3-羰基掩蔽，但是C8-羰基的烯醇化依然无法抑制；虽然通过将呋喃环转化为α，β-不饱和-γ-丁内酯可以抑制烯醇化，但内酯环上的双键迁移又成了新的竞争反应。

In searching for novel and high active fungicides with pyridyl moiety, with Dimethomorph as a model compound and isonicotinic acid as the main starting material, twenty-seven title compounds were designed and synthesized through chlorination, Friedel-Crafts acylation, Wittig-Horner reaction and other steps. All the target structures were confirmed via 1H NMR and elementary analysis.

为了寻找具有高活性的含吡啶杂环杀菌剂，以烯酸吗啉为模板化合物，以异烟酸为起始原料，通过卤代反应、Friedel-Crafts酰基化反应、Wittig-Homer反应等，将吡啶－4-基或2-氯吡啶－4-基引入到模板结构中，设计合成了27个4-［3-（吡啶－4-基）－3-取代苯基丙烯酰］吗啉类化合物，其结构通过1H NMR和元素分析确证。

To avoid the low yield in direct hydrosilylation addition of allyamine, 1, 1, 1, 3, 3, 3-hexamethyldisilazane is used to protect the amino groups, and the protective groups are removed easily after hydrosilylation addition, then the high yield of ladderlike copolymethyl-aminpropylsilsesquioxane was obtained.

为了克服将烯丙基胺直接与聚氢基甲基倍半硅氧烷进行硅氢加成反应接枝效率低的缺点，探索用六甲基二硅氮烷对烯丙基胺预保护，硅氢加成反应后再脱保护，从而以较高产率制备了含胺丙基、甲基的反应性梯形共聚倍半硅氧烷。

From the experiment discovered for the first time the dimethyl ether may substitute CO to take the chain-carrying agent of the peroxy free radical chemistry amplifier system, and optimized the CH_3OCH_3-NO-HO_2 chemistry amplifying system determination condition, the CH_3OCH_3 best density is 1.876 ppmv, the NO best density is 1.3ppmv, and obtained this method chain length CL=124, 5 parallel determinations densities of HO_2 are the 44.0pptv, the relatively standard deviation is smaller than 4%; Although chemistry box model computed result indicated the dimethyl ether, the ethene, the propene and the ethanol all can take the chain-carrying agent of the peroxy free radical chemistry amplifier system, and their simulation chain length all grows up compared to the CO-NO-HO_2 chemistry amplifying systems, but experiments proved the ethene, the propene and the ethanol have not suit the chain-carrying agents.

首次从实验上发现二甲醚可以替代CO作为过氧自由基化学放大系统的链传递试剂，并优化了CH_3OCH_3-NO-HO_2化学放大系统的测定条件，CH_3OCH_3的最佳浓度是1876ppmv，NO的最佳浓度为1.3ppmv，并得到了这一方法的链反应长度(CL=124)，5次平行测定浓度为44.0pptv的HO_2自由基，相对标准偏差＜4％；虽然化学盒子模式计算结果表明二甲醚、乙烯、丙烯和乙醇都能作为过氧自由基化学放大系统的链传递试剂，并且它们的模拟链长都比CO-NO-HO_2化学放大体系的链长大，但是实验证明乙烯、丙烯和乙醇不适合作为过氧自由基化学放大系统的链传递试剂。

A new corrosion inhibitor and Universal antibacterial reagent, namely, the copolymer of N-isopro-pylacrylamide and N-allyl-1-benzoyl-3-phenyl-4,5-dihydro-4-formamido pyrazole was prepared.

合成了一种新的腐蚀抑制及广谱抑菌剂：N-异丙基丙烯酰胺与N-烯丙基-1-苯甲酰基-3-苯基-4，5-2H-4甲酰胺基吡唑的共聚物PNIPAM-Co-PBPCP。

By using competitive adsorption of activated carbom to remove unfavorable influence of carbon in carbonaceous gold concentrate on leaching process, the leaching rate of gold concentrate can be improved to 88% as compared with 10%by direct cyanidation.

本文论述了利用活性炭竞争吸附作用，消除含炭金精矿中炭在浸出过程中的影响，使金精矿的浸出率可由直接氰化的10％提高到88％。

The only thing you're ever gonna be king of is King of the Stupids!

你只配做傻瓜的国王！