烯基

While the adsorptions of 1-propanol and 1-Br-propane at 100℃ give rise to 1-propoxy species, which mainly converted to propanal at higher temperature. IR spectrum arising from the interaction of propene with the catalyst at 100 ℃ shows the IR bands of allyl alcoholate and isopropoxy species. As the temperature was increased to 150℃, the bands ascribable to the adsorbed acetone and acrolein were observed. Based on these results, it is suggested that isopropoxy species is one of the intermediates for SOP to acrolein over MoPO/SiO〓 catalyst.

2原位IR光谱实验结果表明：200℃时丙烷/O〓混合气在催化剂表面吸附后的IR谱与同温度下异丙醇吸附的IR谱相似，均检测到吸附态丙酮物种和丙烯醛物种的IR谱峰；溴代异丙烷和异丙醇在催化剂表面吸附后均转化为异丙氧基，异丙氧基主要转化为丙烯和丙酮，丙烯进一步转化为丙烯醛；溴代正丙烷和正丙醇在催化剂表面吸附后均转化为正丙氧基，正丙氧基主要转化为丙醛；丙烯在催化剂表面吸附后转化为σ-氧烯丙基和异丙氧基，升温后σ-氧烯丙基转化为丙烯醛而异丙氧基转化为丙酮。

While the adsorptions of l-propanol and 1-Br-propane at 100 癈 give rise to 1-propoxy species, which mainly converted to propanal at higher temperature. IR spectrum arising from the interaction of propene with the catalyst at 100 癈 shows the IR bands of allyl alcoholate and isopropoxy species. As the temperature was increased to 150 癈, the bands ascribable to the adsorbed acetone and acrolein were observed. Based on these results, it is suggested that isopropoxy species is one of the intermediates for SOP to acrolein over MoPO/SiO2 catalyst.

原位IR光谱实验结果表明：200℃时丙烷／O_2混合气在催化剂表面吸附后的IR谱与同温度下异丙醇吸附的IR谱相似，均检测到吸附态丙酮物种和丙烯醛物种的IR谱峰；溴代异丙烷和异丙醇在催化剂表面吸附后均转化为异丙氧基，异丙氧基主要转化为丙烯和丙酮，丙烯进一步转化为丙烯醛；溴代正丙烷和正丙醇在催化剂表面吸附后均转化为正丙氧基，正丙氧基主要转化为丙醛；丙烯在催化剂表面吸附后转化为σ-氧烯丙基和异丙氧基，升温后σ-氧烯丙基转化为丙烯醛而异丙氧基转化为丙酮。

Water,Hydrogenated Polyisobutene,Cyclohexasiloxane,Glycerin,Alcohol Denat,Cetearyl Alcohol,PEG-20,Petrolatum,C13-14 Isoparaffin,Zea Mays Oil,Tocopheryl Acetate,Hydroxypropyl Tetrahydropyrantriol,Hydrolyzed Soy Protein,CI 14700/Red 4,Phenoxyethanol,Adenosine,PEG-100 Stearate,Ethylparaben,Triethanolamine,Polyacrylamide,Malus Domestica Stem Cell Culture,CI 19140/Yellow 5,Dimethyl Isosorbide,Dimethicone,Dimethiconol,Limonene,Xanthan Gum,Pentaerythrityl Tetra-Di-T-Butyl Hydroxyhydrocinnamate,Linalool,2-Oleamido-1,3-Octadecanediol,Capryloyl Salicylic Acid,Acrylates/C10-30 Alkyl Acrylate Crosspolymer,Passiflora Edulis Seed Oil,Disodium EDTA,Castanea Sativa Seed Extract,Butyrospermum Parkii· Cetyl Alcohol,Butylene Glycol,Octyldodecanol,Cetearyl Glucoside,Methylparaben,Citronellol,Prunus Armeniaca Kernel Oil,Laureth-7,Coumarin,Oryza Sativa Bran Oil,Glyceryl Stearate,Fragrance

水，甘油，氢化聚异丁烯，液体石蜡/矿油，丁二醇，环己硅氧烷，鲸蜡醇，甘油硬脂酸酯，棕榈油，玉米胚芽油，PEG-100硬脂酸酯，白蜂蜡/蜂蜡，肉豆蔻醇肉豆蔻酸酯，石蜡，香精，腺苷，苧烯，山梨醇，CI 14700，CI 19140，稻糠油，杏仁油，EDTA二钠，羟丙基四氢吡喃三醇，苯氧乙醇，聚乙二醇-14M，异十六烷，氢氧化钠，辛基十二醇，季戊四醇四（双-t-丁基羟基氢化肉桂酸）酯，山梨坦三硬脂酸酯，水解大豆蛋白，卡波姆，鸡蛋果籽油，苹果果实提取物，欧洲栗籽提取物，异山梨醇酐二甲醚，聚山梨醇酯-80，辛酰水杨酸，2-油酰胺基-1，3-十八烷二醇，氯苯甘醚，麦芽糖醇，香豆素，黄原胶，微晶蜡，丙烯酰胺/丙烯酰基二甲基牛磺酸钠共聚物，丙二醇，芳樟醇，香茅醇，玉米油，羟苯丙酯，羟苯甲酯

Sodium 2-Acrylarnido-Acetate has been synthesized through the reaction of Aminoacetic acid with acryloyl chlorine, then Copolymer of sodium 2-acrylamido-acetate and dimethyl diallyl ammonium chloride with acrylamide had been prepared by free radical polymerization using (NH4)2S2O8 and NaHSO3 as the free radical initiator in water solution.

本论文首先以氨基乙酸和丙烯酰氯为原料制备丙烯酰胺基乙酸钠单体，然后以丙烯院胺丙烯酰胺基乙酸钠和二甲基二烯丙基氯化铵为单体，(NH4)2S2O8和NaHSO3为自由基引发剂，采用水溶液聚合法合成丙烯酰胺／丙烯既胺基乙酸钠／二甲基二烯丙基氯化铵共聚物。

Grasp the electron delocolization theory; be capable of judging the relative stability of allylic and benzylic free radicals and carbocations, know the relative stability of dienes and other multiple unsaturated hydrocarbons; grasp the characteristics for the nucleophilic substitution reactions of allyl halides and benzyl halides, and the addition reactions of conjugate dienes.

掌握电子非定域化理论；能够分析判断烯丙基、苄基自由基和正离子的稳定性和二烯及多重不饱和碳氢化合物的稳定性；掌握烯丙基、苄基卤代物的亲核取代反应特性和共轭二烯的加成反应。

The major products were methane, ethylene, propylene, butylene, butadiene, cyclopentadiene, benzene, toluene, styrene, vinyl-substituted cyclopentene derivatives and C5/C6 isomers (pentadiene, methyl-substituted cyclopentene derivatives, cyclohexene, hexadiene and methyl-substituted cyclopentadiene derivatives), and the main primary products were determined to be C1～C4 compounds, cyclopentadiene, benzene, toluene and vinyl-substituted cyclopentene derivatives.

热裂解主要产物为甲烷、乙烯、丙烯、丁烯、丁二烯、环戊二烯、苯、甲苯、苯乙烯、环戊烯的乙烯基取代物及C5， C6异构体(戊二烯、环戊烯的甲基取代物、环己烯、己二烯和环戊二烯甲基取代物)，其中， C1～C4、环戊二烯、苯、甲苯、乙烯基取代环戊烯为初始产物。

The major products were methane, ethylene, propylene, butylene, butadiene, cyclopentadiene, benzene, toluene, styrene, vinyl-substituted cyclopentene derivatives and C5/C6 isomers pentadiene, met...

热裂解主要产物为甲烷、乙烯、丙烯、丁烯、丁二烯、环戊二烯、苯、甲苯、苯乙烯、环戊烯的乙烯基取代物及C5，C6异构体(戊二烯、环戊烯的甲基取代物、环己烯、己二烯和环戊二烯甲基取代物)，其中，C1～C4、环戊二烯、苯、甲苯、乙烯基取代环戊烯为初始产物。

This work, concentrated on the asymmetric allylation of aldehydes controlled by different chiral auxiliaries prepared from rotational pure tartaric acid, can be divided into three parts.The first part aims to review the developments of chiral drugs and asymmetric synthesis, from which derived the present research topic backgrounds and works.Synthesis and applications of allylation from aldehydes are the second part of the thesis. By optimizing the reaction conditions, such as solvents, temperature, time and chiral auxiliaries like N,N\'-dibenzyl tartamide, N,N\'-p-dimethylphenyl tartamide, N,N\'-o-dimethylphenyl tartamide, N,N\'-o-dichlorophenyl tartamide, N,N\'-a-dinaphyl tartamide, N,N\'-dicyclohexyl tartamide and N,N\'-diphenyl tartamide, ideal experimenttal conditions are obtained according to HPLC monitoring, as well as the auxiliaries\' recoveries experiments. Starting from benzaldehyde and 3-bromopropaldehyde, N,N\'-dibenzyl tartamide is considered the best auxiliary in this reaction.

本文介绍了醛的不对称烯丙基化反应，以光学纯酒石酸为原料，研究了不同构型手性配体在醛的烯丙基化反应中的立体选择性，全文共分三部分十个章节：第一部分对当前手性药物和手性技术进行了概述，并由此展开了本文的研究背景和任务；第二部分为有机合成部分，对醛的不对称烯丙基化反应进行了深入探讨，以苯甲醛为原料对反应条件进行优化，在优化的反应条件下对制备的七种可回收手性酰胺配体(N-苄基酒石酸二酰胺、N-对甲苯基酒石酸二酰胺、N-邻甲苯基酒石酸二酰胺、N-邻氯苯基酒石酸二酰胺、N-a-萘基酒石酸二酰胺、N-环己基酒石酸二酰胺和N-苯基酒石酸二酰胺)进行筛选，优化配体回收实验条件，最终确定出N-苄基酒石酸二酰胺在苯甲醛的不对称烯丙基化反应中具有较大优越性，结晶回收的手性配体光学纯度保持不变。

In this Ph. D. dissertation, reverse microemulsion method was fully used infabricating and modifying polyacrylamide with functional and high-relative moleculeweight. The copolymerization of 2-acrylamide-2-methylpxopanesulfonic acid, fluorescent monomer 4-methoxy-N-(2-N\', N\'-dimethylamino ethyl)naphthalimide alkyl chloride quaternary ammonium salt, fluorescentmonomer 4-(N\'-methyl-1-piperazinylallyl)-N-butyl-naphthalimide chloride quaternaryammonium salt, Cationic monomer dimethylethylammonium bromide and hydrophobical monomer octadecylacrylate with acrylamide and properties of the copolymers werestudied. The interaction between five polymers and Al_2O_3(012) crystal surface have beensimulated by Materials Studio 3.0 program package, binding energies and non-bondinteraction energies and deformation energies have also been acquired.

本文以制备具有较高相对分子质量和功能型PAM为研究目的，将反相微乳液法运用到其制备及改性的有关环节，通过反相微乳液聚合工艺，将几种改性功能单体2-丙烯酰胺基-2-甲基-丙磺酸、荧光单体2-(4-甲氧基-1，8-萘二甲酰亚胺基)-乙基二甲基烯丙基氯化铵、荧光单体4-(N'-甲基-1-哌嗪基)-N-丁基-1，8-萘烯丙氯季铵盐、阳离子单体丙烯酰氧乙基-二甲基-乙基溴化铵和疏水单体丙烯酸十八酯与AM共聚，制备AMPS改性PAM、荧光示踪型PAM、阳离子单体DMB改性PAM和OA改性PAM等四类不同功能单体改性PAM，并研究其应用性能。

The results of in situ DRIFTS on propylene oxidation show that the allyl species originated from α-H abstraction of propylene were located at the wavenumbers of 1454 cm~(-1) and 1427 cm~(-1). The rate-determining step is the abstraction of an α-H abstraction from a lattice oxygen linked to a bismuth ion to form a π-allyl intermediate coordinated to a molybdenum ion. The metal-oxo group then attacks the allyl intermediate forming a σ-bonded oxygen-allyl species, which is in a rapid equilibrium with the π- bonded species. The σ-bonded species then transforms to acrolein by further abstraction of α-H. Such species as formate, carboxylate, carbonate transform to deep oxidation products. The acetone was derived from propylene by an enolic species at lower temperatures.

丙烯氧化反应体系的原位漫反射红外光谱研究结果表明，由丙烯脱氢生成的烯丙基中间物种吸收峰在1454cm~(-1)和1427cm~(-1)处；基于此提出了较完整的丙烯氧化反应网络：丙烯选择氧化生成丙烯醛主要经历丙烯脱除甲基上的一个H，生成烯丙基物种，该物种嵌氧生成σ-O络合物，脱氢得到丙烯醛前驱体，脱附生成丙烯醛；完全氧化产物是由催化剂表面上生成甲酸盐、羧酸盐、碳酸盐等形式的中间物种转化而成；较低反应温度下丙烯氧化生成丙酮，通过烯醇式中间物种氧化生成丙酮前驱体得到。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。