烯基

A Theoretical Study on the Reaction Mechanism of Epoxidation Reaction of the 4- Bicyclo

CEPS 思博网--文章书目；-1页数：7 需求点数：28 电子全文：请登入。篇名（4-溴甲基双环[4.4.1]-1，3，5，7，9-十一碳五烯基－3-）甲醇环氧化反应机理的理论研究

Methyl-2,3,5,6-tetrafluoro-benzene methanol was synthesized by chlorination, acylation, fluorination, esterifica- tion, reduction, bromization, reduction from terephthalic acid. Tefluthrin was obtained from-(1RS,3RS)-3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cycolpropa-necarboxylate acid by reacting with 4-methyl-2,3,5,6-tetrafluoro-benzene methanol.

以对苯二甲酸为原料，经氯化、酰氯化、氟化、酯化、还原、溴化、还原七步反应合成了4-甲基-2，3，5，6-四氟苄醇，甲基苄醇与-(1RS，3RS)-3-(2-氯-3，3，3-三氟丙-1-丙烯基)-2，2-二甲基环丙甲酸一步酯化合成了七氟菊酯。

The protic- or Lewis acid catalyzed ring-closure of divinyl ketones (and their acid-labile precursors) pentadienylic cations is known as the via Nazarov cyclization.

质子酸或路易斯酸通过戊二烯基阳离子催化二乙烯酮的环闭合（以及它们的酸不稳定前体）这个反应被称为Nazarov环化。

Results The five purified ginkgolic acid monomers were GA13:0.,GA15:0.,GA15:1 ,GA17:1 and GA17:2 ,with a side chain of 13,15,17 alkyl or ethylenic radicals respectively on their benzene loop.

结果纯化的银杏酸5个同系物单体为GA13：0、GA15：1、GA15：0、GA17：1和GA17：2，其母核苯环上分别有1个13、15及17烷基或烯基的侧链。

6 Ppm and 116.8 ppm, attributable to the two tertiary ethylenic carbon atoms

118.6 ppm和116.8 ppm：两个烯基叔碳原子－这样翻译对吗？

For example,the addition reaction with small molecular,the metathetical reaction with alkynes and Wittig reaction to prepare high-valent transtion-metal allenylidene complexes.

对于化合物11，详细研究了其与小分子加成反应、炔烃复分解反应以及通过Wittig反应制备高价态过渡金属丙二烯基卡宾化合物。

In this thesis, the process of side-chain alkenylation and cyclization reaction have been studied. NaK eutectic mixture is seldom used as acatalyst, not to mention the sonochemical treatment of it in a catalytic system.

本研究通过烯基化反应合成OTP并对其进行环化反应合成1，5-DMT，同时对反应催化剂进行表征并对反应机理进行探讨。

Meantime, we further studied this reaction under microwave irradiation conditions and first introduced the concept of the solvent-free and no-catalyst in this reaction, expanded the olefination of organozinc halides reagents with aldehydes, enlarged the application scopes of this reaction.

同时在微波辐射条件下进一步研究了该类反应，并在该类反应中初步引进无溶剂、非催化的概念，扩展和完善了有机卤化锌试剂与醛的烯基化反应，扩大了其应用范围。

In the presence of Pt catalyst, polyhydrodimethylsiloxane reacted with allyl polyoxyethylenepolyoxypropylene ether (F-6) by hydrosilylation to form an intermediate polyether silicone, which further undergo phosphation reaction with phosphorous pentoxide, a kind of phosphate modified polyethersiloxane surfactant was prepared.

采用铂作催化剂，通过含氢硅油和端烯基聚醚（F-6）的硅氢化加成反应先制得聚醚硅油中间体，再将其和五氧化二磷进行酯化反应，制得了一种磷酸酯型有机硅表面活性剂。

Two compounds have been isolated from hard coral Porites Compressa Dana,their structures were determined by IR,MS, HNMR, 13CNMR analysis.The two compounds are: batyl alcohol,(2) N-[l--2-hydroxyl--3,7-heptadecadienal]- h exadecanamide.

从采自西沙群岛的扁缩滨珊瑚中的石油醚部分分离出两个化合物，经IR、MS、~1HNMR、~(13)CNMR等波谱方法鉴定，其结构分别为(1)鲨肝醇，(2)N-1-羟基甲基-2-羟基--3，7-十七碳二烯基十六酸酰胺。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。