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The deactivation of catalyst in benzene alkylation with propene over Hβ zeolites under different conditions was investigated.

对不同条件下苯与丙烯烷基化反应Hβ催化剂的寿命、失活催化剂的积炭量和积炭性质进行了研究。

The pyridinium salts was transformed by the base to 1-hydroxy or 3-hydroxy-quinolizinylides, which undergo 1,3-dipolar cycloadditionreaction with alkenes,and then aromatizated to cycl[3,3,2]azinone in thepresence of oxidant.

实验证明,这是一个连续进行的多步反应:2-羰基吡啶鎓盐在反应中先生成1-羟基或3-羟基喹嗪叶立德,然后与烯烃起1,3—偶极加成反应,最后在氧化剂作用下脱氢芳构化而生成Cycl[3,3,2]azinone。

Quinonyl compounds were reducted to phenolic compounds in high yields promoted by aluminum triiodide ,and after the reaction with dienophiles in Diels Alder reactions concave adductions were combined.

在现场制备的三碘化铝促进下,醌类化合物发生还原反应以良好产率生成酚类物,并且在原位与亲双烯体发生Diels Alder反应从而生成凹状加合

The catalytic performance of the synthesized molecular sieves, modified by Pd or Pt, for isomerization and dehydroisomerization of n butane was investigated. Pd/SAPO 11 catalyst showed the highest selectivity in...

结果表明,载 0 3%Pd的SAPO 11分子筛催化剂具有最高的丁烷异构化选择性,而在丁烷一步异构脱氢反应中,含金属杂原子的催化剂具有更高的异丁烯选择性。

A series of mono-, sesqui-, di- and tri-terpenoids with various structural types, which produced by bio- oxidation, hydrogenation, hydrolyzation, esterification and cyclic cleavage toward-limenone, were analyed by GC-MS.

经GC-MS分析发现该两细菌对-柠檬烯有显著的生物催化转化作用,能对底物进行不同程度的氧化、还原、水解、酯化、开环等反应,并产生丰富的系列结构不同的其它萜类化合物:包括单萜、倍半萜、二萜、以及三萜等。

In the catalytic tranformation of n-butane, Pd modified silicoaluminate molecular sieves were tested for n-butane's isomerization and dehydroismerization.

考察了硅铝分子筛为基质的双功能催化剂催化丁烷异构化的反应性能及催化丁烷一步异构脱氢反应的可能性,发现丁烷到异丁烯的一步转化无法在这一反应体系十有效实现。

In the catalytic tranformation of n-butane, Pd modified silicoaluminate molecular sieves were tested for n-butane's isomerization and dehydroismerization.

考察了硅铝分子筛为基质的双功能催化剂催化丁烷异构化的反应性能及催化丁烷一步异构脱氢反应的可能性,发现丁烷到异丁烯的一步转化无法在这一反应体系中有效实现。

Chiral 3 methy 1,4 butanediol and its derivatives are the important intermediate of synthesis of chiral smectic liquid crystal polyesters and chiral natrual products with biological activity. In the paper, a new efficient route of 3 methyl 1,4 butanediol and its two derivatives, 2 methyl 4 tetrapyranyloxy 1 butanol and 2 methyl 4 tetrapyranylbutanal, was described, and the target products were synthesized by employing asymmetric hydroboration oxidation improved.

手性2-甲基-1,4-丁二醇及其衍生物是合成各种手性近晶型液晶材料以及手性天然生物活性物质的重要中间体,以3-甲基-3-丁烯-1-醇为原料利用改进的不对称硼氢化-氧化反应,成功地合成了-2-甲基-1,4-丁二醇以及其2种手性衍生物:-2-甲基-4-四氢吡喃氧基-1-醇和-2-甲基-4-四氢吡喃氧基丁醛。

A high molecular weight polyisobutenyl succinimide dispersant with high nitrogen content and good thermal and oxidative stabilities was developed.

采用氯化烃化工艺和后偶联反应技术开发了一种氮含量高、热稳定性和氧化稳定性好的高相对分子质量的聚异丁烯基丁二酰亚胺分散剂。

The results show: in a specific concentration range, the solubility in neutral solution of SOL, as well as the surfactivity, the ability to reduce ITF and the wettability on the condition of non- alkali are better than the lignosulfonate in market.While using as sacrifice agent, the modified lignosulfonate can reduce 60% of the mahogany sulfonate and 50% of the α-alkene sulphonate which both are adsorbed on the oil sand surface.

结果表明在一定浓度范围内,SOL在中性溶液条件下的溶解性、在无碱条件下的表面活性、降界面张力能力、对岩石的润湿性效果优于市场木质素磺酸盐产品;作为牺牲剂使用时,改性磺化木质素能减少石油磺酸盐在油砂表面吸附的60%,减少α-烯烃磺酸盐在油砂表面上吸附的50%。

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