烯化

The thermolysis of the isomerized products derived from terpadiene-coordinated carbonyl iron complexes afforded the same kind of the thermolytic products.

以萜二烯三羰基铁络合物衍生出来的铁卡宾络合物及其异构化产物，热解以后都得到了同一类型的络合物。

It was shown from the results that emulsifier TP-Ⅴ which was prepared by PEG 4000 reacted with TME, in the molar ratio of TME to PEG 2:1, at about 110℃ for 1 h, catalyzed by boron trifluoride diethyl etherate, has a very good emulsifying impact for TME. Particle size distribution of the emulsion was homo-geneous and viscosity of the emulsion was small.

实验结果表明，以M相对适中的PEG4000与TME按物质的量比2： 1、在催化剂三氟化硼乙醚作用下、110℃左右反应1h合成的乳化剂TP-Ⅴ，对萜烯基环氧树脂具有很好的乳化效果，制备的乳液粒子粒径均一度较高，乳液表观黏度较小。

The reaction takes place as soon as 3a is dissolved in solution. With the presence of a tethering terminal vinyl group bound to the vinylidene ligand, the [2+2] cycloaddition of two C=C double bonds readily occurred.

当有一乙烯基键结在丙二烯基上，分子内的两个碳碳双键会马上发生[2+2]的环化加成反应。

It was found that ARA was composed of esterification products of (2-HEA)-ester with pimaric acid, dehydroabietic acid, abietic acid and two isomers of acrylpimaric acid. ARA is a good crosslinking agent which can copolymerize with most vinyl monomers. The properties of solvent-resistance and heat resistance of the copolymer were improved considerably by the use of ARA.

实验结果表明：ARA主要由海松酸、脱氢枞酸、枞酸和丙烯海松酸的二种异构体的丙烯酸－2-羟基乙基酯的酯化产物组成，ARA是一种良好的交联剂，可与大多数乙烯基单体共聚合，其与MMA的共聚物的耐溶剂性和耐热性均得到了较大幅度的提高。

This mechanism is different from that for the acetalization reaction of polyvinyl alcohol with saturated aldehydes,which has only 1,2-addition.Crosslinking in polyvinyl butenal was mainly resulted from the 1,4-addition.

此机理不同于只有1，2-加成方式的聚乙烯醇缩饱和醛化反应。1，4-加成主要导致聚乙烯醇缩丁烯醛的交联。

Chemical experiments and carbon nuclear magnetic resonance studies showed that there were two addition manners,l,2-and l,4-additions when α-butenal,as an unsaturated aldehyde,conducted an acetalization reaction with polyvinyl alcohol.

化学分析法及碳核磁共振研究表明，作为不饱和醛的α-丁烯醛与聚乙烯醇在水溶液中进行缩醛化时存在着 1，2-加成与1，4-加成两种反应方式。

In this paper, the synthesis ways and applications of 4,5-dimethyl-l,3-dioxolen -2-one were introduced. An appropriate way synthesizing DMDO from acetoin via acylation, cyclization and dehydrochlorination was selected. The influences of various process conditions on the reaction were studied in detail, and the optimum process conditions were obtained by single factor experiments.

本文介绍了医药中间体4，5-二甲基-1，3-二氧杂环戊烯-2-酮的应用情况和合成路线，选择了适于工业化生产的工艺路线，即采用羟基丁酮为原料，经酰化、环合和脱氯化氢等步骤合成DMDO，并采用单因素试验法详细研究了各项工艺条件对反应结果的影响规律，确定了优化工艺条件。

4R,5S,6R-5,6-Bis-allyl-6-aldehyde-γ-hexanelactone I-145 was prepared from D-arabinose by six steps. Compound I-145 underwent Mukaiyama-type intramolecular aldolization to produce bicyclooctane I-147 stereospecifically.

我们以D-阿拉伯糖为起始原料，经六步反应，得到(4R，5S，6R)-5， 6-二烯丙氧基-6-醛基-γ-己酸内酯I-145，然后I-145发生分子内的Mukaiyama式aldol缩合反应，完全立体专一性地得到环化中间体I-147。

The attempt to hydrogenation of the alkenyl phthalides has been proved promising, and 55% ee value was the best selectivity by far. But the reault was not very repeatable.

对于烯基苯酞的不对称氢化进行了一定尝试，目前对映选择性最高可以获得55%，但是目前结果还不是很稳定。

In addition to the multi-ring alkenyl ethers and alpha-fluorinated acrylates, additional monomers comprising one or more cyclic aliphatic and heterocyclic compounds, both unsubstituted and substituted, in particular dihydropyrans, may be incorporated into the photosensitive polymers.

除了多环烯基醚和α-氟化丙烯酸酯之外，可向所述光敏聚合物引入另外的单体，所述单体包括一种或多种未取代的和取代的环状脂肪族化合物和杂环化合物，特别是二氢吡喃。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。