烯化

Nanometer composite S2O(superscript 2- subscript 8)/SnO2-TiO2 was used as a catalyst in α-pinene isomerization.

首次将纳米复合S2O(上标 2-下标 8)/SnO2-TiO2用于催化α-蒎烯异构化反应。

Molecular dynamics simulations of NPT (constant pressure and constant temperature) dynamics are carried out to obtain specific volume as a function of temperature for polyethylene , polypropylene , poly-isobutylene , polyoxymethylene , and polydimethylsiloxane .

用NPT分子动力学模拟来获得聚乙烯、聚丙烯、聚异丁烯、聚甲醛和聚二甲基硅氧烷在不同温度下的特征体积。体积玻璃化转变温度通过对模拟得到的V-T作图的曲线的拐点决定。

As a precursive work of polymerization directly from vesicles, a polymerizable surfactant, allyl dodecyl dimethylammonium bromide was synthesized, and spontaneous stable vesicles were formed from aqueous solutions of ADDB and sodium dodecyl sulfonate in equimolar composition.

作为可聚合囊泡制备的前期基础工作，研究了一种可聚合的囊泡体系：1-丙烯基－2，2，二甲基－十二烷基溴化胺和ADDB与十二烷基磺酸钠的等摩尔比混合体系。

In this dissertation, Ir-catalyzed asymmetric hydrogenation of quinoline derivatives, pyridine derivatives and exocyclic enamines have been studied.

本论文研究了铱催化的喹啉和吡啶衍生物以及环外烯胺的不对称氢化。

The effects of reaction temperature, phase transfer agent and the concentration of rhodium catalyst were examined.

研究了采用水溶性铑膦络合催化体系对双环戊二烯的氢甲酰化反应，考查了反应温度、相转移剂CTAB、铑催化剂浓度等对反应的影响。

In this paper, the carbonylation has been studied of olefins in different solvent systems.

本文研究了烯烃在不同溶剂体系中进行羰基化反应的规律。

Liquid-phase epoxidation of allyl chloride with hydrogen peroxide was carried out over Ti-MWW, a novel titanosilicate with the MWW structure, to synthesize epichiorohydrin selectively and effectively. Ti-MWW proved to be superior to the conventional TS-1 catalyst in both catalytic activity and product selectivity. Ti-MWW prefers aprotic solvents of acetone and acetonitrile, both of which can restrain the solvolysis of epichiorohydrin, whereas TS-1 favors a protic solvent of methanol.

研究了具有MWW结构的新一代钛硅分子筛Ti-MWW催化剂对烯丙基氯液相环氧化高效合成环氧氯丙烷的催化性能结果表明，Ti-MWW的催化活性以及产物选择性均优于传统的钛硅分子筛TS-1，对于Ti-MWW，合适的溶剂为非质子性溶剂丙酮和乙腈，在该溶剂中环氧化物不易发生溶剂化开环反应；而对于TS-1，合适的溶剂是质子性溶剂甲醇，但甲醇可导致醇醚副产物的生成。

Synthesis, spectral and structural studies of isomerized products of isopreneiron complexes and crystal structure of tetracarbonyl ethoxypentachloroph

异戊二烯二羰基铁配合物的异构化产物的合成，波谱和结构研究及四羰基铁的晶体结构

Treated by transesterification with methanol to 60% of the theoretical extent and esterified with maleic anhydride,then oxidized by air with supported metal stearate catalyst at 80 ℃ for 4-6 h and sulphited by sulphite,a novel combined sulphited fatliquoring agent is obtained from rape oil.

对菜油进行甲醇酯交换反应，反应程度控制在理论值的 6 0 %，然后用顺丁烯二酸酐酯化酯交换产物。这种酯化物在负载型金属皂的催化下，用空气进行氧化，温度 80℃，时间 4～ 6h。

15K. It is shown that two main factors, pressure and the polarity of the mixture, influence the EAA tautomerism.

结果表明，EAA的酮式-烯醇式异构化平衡常数随共溶剂极性的增加而减小。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。