烯化

DAY 1: Distillation and Gas Chromatography: WORK in PAIRS. Split evently the limonene and carvone fractions for the derivatization step.

第一天：蒸馏和气相色层分析：以对为单位工作，一组分一个柠檬烯一组分一个香芹酮馏份作为衍生化步骤

Water,glycerin,rosa centifolia flower water,butylene glycol,centaurea cyanus flower water,peg-40 hydrogenated castor oil,propylene glycol,ppg-26-buteth-26,phenoxyethanol,methylparaben,sorbic acid,benzophenone-4,pentadecalactone,citrus aurantium dulcisoil,panthenol,menthyl lactate,sodium hydroxide,glycyrrhiza glabraroot extract,aesculus hippocastanumseed extract,citrus aurantium amaraoil,allantoin,limonnene,linalool,blue 1(ci 42090),yellow 5ci 19140

水，甘油，千叶蔷薇花水，丁烯二醇，矢车菊花水，PEG-40氢化蓖麻油，丙二醇，PPG-26-丁醇聚醚-26，苯氧乙醇，对羟基苯甲酸甲酯，山梨酸，二苯甲酮-4，环十五内酯，甜橙油，泛醇，乳酸孟酯，氢氧化钠，甘草根萃取，七叶树籽萃取，苦橙油，尿囊素，柠檬精油，芳樟醇，蓝，黄水：几乎所有护肤品成分第一位都是水。

Novel sulfonic acid and carbon chains of mixed-mode packing materials were synthesized through sulfonating polymer-encapsulated zirconia covered by a porous copolymer of olefinic hydrocarbon and divinylbenzene on its surface.

通过共聚交联方法将长链碳烯-苯乙烯包覆到锆胶表面上，得到聚合物包覆固定相，再对该填料进行磺化引入离子官能团到聚合物表面，得到混合型固定相。

Zibo sea of FA factory, covering 20,000 square meters, business owners 10 million yuan in fixed assets 2, 5 10 million yuan of liquidity, is set the strength of the economy, advanced production technology, quality inspection, self-analysis, human resource-rich The integration of chemical manufacturing companies, is China's Anti-corrosion Technology Association member units, Zibo City with the contract and trustworthy enterprises, enterprises have passed ISO9001-2000 international quality management system certification, with import and export right, and its products FA, Acrylamide Crystal has been the international market, exported to Russia, South Korea, Japan, India, New Zealand, more than 10 countries and won wide acclaim and appreciation.

淄博海化糠醇厂，占地面积2万平方米，企业拥有固定资产2千万元，流动资金5千万元，是集经济实力雄厚、生产工艺技术先进、质量检验、分析设备齐全、人力资源丰富于一体化的化工制造企业，是中国防腐蚀技术协会会员单位，淄博市重合同守信用企业，企业已通过ISO9001-2000国际质量管理体系认证，已具备自营进出口权，其产品糠醇、丙烯酰胺晶体已走向国际市场，远销俄罗斯、韩国、日本、印度、新西兰等十几个国家，并赢得了广泛赞誉。

In this thesis, it was intended to investigate the role of planar chirality, and to design and synthesize novel ligands.

在前项工作基础上合成一类有效的手性二茂铁配体，拓宽烯丙基化反应的底物或反应类型，为解决这些问题做出我们的一些贡献。

AIM: To synthesize 2 novel chiral ligands derived from cinchona alkaloids and study their catalytic performance in asymmetric dihydroxylation of 5 olefins.

目的：合成两种新的金鸡纳生物碱类衍生物配体并将其用于催化五种烯烃的不对称二羟化反应，考察催化效果。

METHODS: Inexpensive quinine and cinchonine were transformed to 9NH2quinine and 9NH2cinchonine, which reacted with 4chlorobenzoyl chloride to afford 2 novel chiral ligands. The AD reactions of olefins were performed in H2OtBuOH (1∶1) using the 2 ligandsK2OSO24 as catalysts.

以价廉易得的奎宁和辛可宁为原料，经过结构转换得到9氨基奎宁和9氨基辛克宁，进而与对氯苯甲酰氯反应制得两种新型手性配体，并将其用于锇催化的烯烃的不对称双羟化反应。

A new chiral quaternary ammonium salt 1a was synthesized by the reaction of cinchonine and(2,4,6-)trimethyl benzyl chloride.Etherification between 1a and benzyl bromide,allyl chloride,or methyl give corresponding etherified quaternary ammonium salts 1b,1c,and 1d.

由辛可宁和2，4，6-三甲基苄氯，合成了一种新的手性季铵盐(1a)，并进一步用苄基溴、碘甲烷和烯丙基氯对分子中的羟基进行醚化，得到相转移催化剂1b、1c和1d。

Macadamia Nut Oil, Joba Oil, Vitamin e, Tamanu Oil, Blackseed Oil, Rose Geranium oil, Frankinsense Oil, Lavender Oil, Lecithin, Co-enzyme Q10, Vitamin A, Citral*, D-lomene*, Citronellol*, Geraniol*, Linalool**from 100% natural essential oils.

澳洲坚果油，氢化霍霍巴油，维生素E，红厚壳油， blackseed油，玫瑰老鹳草油，乳香油，薰衣草油，卵磷脂，抗氧化Q10的酵素，维生素A ，柠檬醛*，右旋柠烯*，香茅醇*，香叶醇*，芳樟醇

Using DFT combined with the orbital localized approach and Xu's covalence new concepts on a molecular fragment, it is concluded that the covalence of copper atom is 7 in 〓-type clusters and in inorganic fullerene-like molecule 〓, and there are Cu-Cu single bonds in 〓-type clusters.

应用DFT结合轨道定域化的方法和分子片共价的新概念，提出了在〓类簇合物和无机类富勒烯分子〓〓中Cu原子的共价为7，以及化合物中Cu-Cu单键的存在；解释了通常认为这类化合物中Cu-Cu之间没有成键作用而又不能回答较短的Cu-Cu键长的问题。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。