烯化

It was found that H3PO4 is an effective catalyst for the acylation of 2,3-dimethyl-2-butene by acetic anhydride at room temperature.

结果表明，H3PO4是室温下催化2，3-二甲基-2-丁烯与乙酐酰化反应的有效催化剂。

FeCl_3 was used to catalyse the acylation reaction of triisobutylene by acetic anhydride at room temperature.

室温下FeCl3用于催化三聚异丁烯与乙酸酐的酰化反应。

It was found that SnCl_2·2H_2O is an effective catalyst for the acylation of 2,3-dimethyl-2-butene by acetic anhydride at room temperature.

发现SnCl2·2H2O是室温下2，3-二甲基-2-丁烯与乙酐进行酰化反应的有效催化剂。

We investigated constituent of triterpenoid saponins ofAlbizzia, two new compounds together with two known compounds were isolated from Albizzia julibrissin Durazz. by using column chromatography (macroreticular resin, silica gel, Sephadex gel, reverse phase silica gel),preparative HPLC methods et al.On the basis of spectroscopic analysis, including IR,ESI-MS,~1H-NMR,~(13)C-NMR,HMBC,HMQC,~1H-~1HCOSY and chemical methods, the structure of two new compounds were identified as 3 - O -[β-D-xylopyranosyl(1→2)-β-D-fucopyranosyl (1→6)-β- D -2- deoxy - 2 - acetoamidoglucopyranosyl] -21-O-[(6S)-2- trans- 2,6-dimethyl - 6 - O-β- D - quinovopyranosyl -2,7- octadienoyl] - acacic acid- 28 - O-β-D-glucopyranosyl(1→3)[α-L-arabinofuranosyl(1→4)]-α-L-rhamnopyranosyl(1→2)-β-D-glucopyranoside acacic acid 3- O -β- D- glucopyranosy(1→3)-β- D- fucopyranosl(1→6) [β-D- xylopyranosyl (1→2)]-β-D-glucopyranoside ;two known compounds were acacic acid lactone 3- O -β-D- xylopyranosyl-(1→2)-β-D-fucopyranosl (1→6)- 2-deoxy -2 -acetoamido -β-D- glucopyranoside ; acacic acid lactone 3- O-β-D-xylopyranosyl(1→2)-α-L- arabinopyranosl (1→6)- 2- deoxy - 2- acetoamido -β-D-glucopyranoside . The study lays chemical foundation and chemical reference substance for enhancing quality standard of Albizzia julibrissin Durazz.

本研究论文在综述国内外对合欢属Albizzia三萜皂苷化学成分和药理作用研究进展的基础上，利用传统植化分离手段和现代分离技术，包括大孔树脂、硅胶、葡聚糖凝胶、反相硅胶等柱色谱，制备高效液相色谱法等技术从中药合欢皮中分离得到了4个化合物，其中，2个新化合物和2个己知化合物，并进一步通过现代分析技术IR，ESI-MS，~1H-NMR，~(13C-NMR，HMBC，HMQC，~1H-~1HCOSY等和化学方法鉴定了2个新化合物的结构分别是：3-O-[β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖基]-21-O-[(6S)-2-反式-2，6-二甲基-6-O-β-D-吡喃鸡纳糖基-2，7-辛二烯酸基]-金合欢酸-28-O-α-L-呋喃阿拉伯糖基(1→4)[β-D-吡喃葡萄糖基(1→3)]-α-L-吡喃鼠李糖基(1→2)-β-D-吡喃葡萄糖苷，金合欢酸3-O-β-D-吡喃葡萄糖基(1→3)-β-D-吡喃夫糖基(1→6)[β-D-吡喃木糖基(1→2)]-β-D-吡喃葡萄糖苷；2个已知化合物结构分别是：金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷，金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-α-L-吡喃阿拉伯糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷。

They were principally used to catalyze aldol, allylation, Diels-Alder, ene and Friedel-Crafts reactions.

它们主要被用来催化Aldol，烯丙基化，Diels-Alder，Ene和Friedel-Crafts等反应。

The alkene chain and H2Se were detected respectively by a series of experiments to support the new mechanism.

通过一系列实验，我们分别检测了烯烃和硒化氢气体，证实了我们所提出的生成机理。

In addition, preliminary results demonstrating that the halogenation of alkene and benzylic sp3 C-H bonds can also be achieved using this method.

此外，初步结果表明，苄卤化烯烃类sp3C-H键也可以用这种方法取得。

Results showed that using aluminum trichloride combined catalyst under the conditions of a catalyst dosage of 5%, a benzene/olefin molar ratio of 8, a reaction temperature of 60℃ and a reaction time of 6 h, the yield of alky-benzene reached 19.6% and the quality of the obtained alkylate was significantly improved as compared with coker gas oil.

结果表明，采用三氯化铝复合催化剂，在催化剂质量分数为5%、反应温度60℃、苯烯摩尔比为8、反应时间6 h的条件下，烷基苯收率达到19.6％，烷基化油的质量明显优于焦化柴油。

Changes to FCC gasoline cutpoints and the possibility of blending by dilution (adding components such as ethers or alkylate) can be used to meet a sulfur or olefin specification for individual gasoline grades if a preliminary blend is already close to the specification and the refinery desires to increase total gasoline production.

对FCC 汽油cutpoints 的变动和混和的可能性由稀释(增加组分譬如以太或烷基化)可能使用符合各自的汽油等级的硫磺或烯烃规格如果初步混合已经是紧挨规格和精炼厂渴望增加总汽油生产。

In this study enamine was used as the reactive intermediate for alkylation of cyclohexanone alkylate,to provide a new route to synthesize the perfume-α-tert-butylcyclohexanone after overcoming many disadvantages of the traditional technical route,such as the complicated of reaction steps,the expensive reagents adopted,the high demand for the equipment used,and the low yield of product.

利用烯胺作为环己酮烷基化的活性中间体，为香料α-叔丁基环己酮的合成提供了一条新的途径，克服了传统工艺反应步骤烦琐，试剂昂贵，设备要求较高，产率不高等缺点，易于工业化生产。

By using competitive adsorption of activated carbom to remove unfavorable influence of carbon in carbonaceous gold concentrate on leaching process, the leaching rate of gold concentrate can be improved to 88% as compared with 10%by direct cyanidation.

本文论述了利用活性炭竞争吸附作用，消除含炭金精矿中炭在浸出过程中的影响，使金精矿的浸出率可由直接氰化的10％提高到88％。

The only thing you're ever gonna be king of is King of the Stupids!

你只配做傻瓜的国王！