烯化

When the mol quantity of Cu2+ dissolved was 5% of those of AlCl3 in ionic liquids, alkylation results from ionic liquids is comparable with those obtained with concentrated sulfur acid: the yield of alkylate reaching 178% of the volume of butene inputted, the selectivity of C8 reaching 75% and the octane number of alkylate reaching 92.2.

溶入Cu2+和Cu+后，离子液体的催化性能有显著的改善，当Cu2+的摩尔加入量为三氯化铝的5%时，烷基化油收率达到丁烯体积的178%，对C8的选择性为75%，烷基化油辛烷值为92.2，并且离子液体可以重复使用。

The alkylation of benzene with long-chain olefins has been performed in the presence of ionic liquid, the reaction conditions are optimized.

研究了离子液体催化苯与烯烃的烷基化，考察了反应条件对烷基化反应的影响。

Deactivation and regeneration of QZ-2000 catalyst for alkylation of benzene and propylene to synthesize cumene were studied.

对苯和丙烯烷基化反应合成异丙苯的QZ-2000烷基化失活催化剂进行了失活原因及再生条件的研究。

The isomerization reaction of propylene oxide to produce allyl alcohol catalyzed by basic lithium phosphate was studied.

研究了环氧丙烷在碱性磷酸锂催化作用下异构化生成烯丙醇反应过程，考察催化剂的制备条件，异构化温度对催化性能的影响，以及催化反应机理和动力学特性。

We studied effects of additives in the allylic amination reaction. We found that4NF could improve the reactivity and enantioselectivity.

对于烯丙基胺化反应，我们研究了外加添加剂对对映选择性的影响，我们发现四丁基氟化铵的加入可以大大提高反应速度及对映选择性。

THE FIRST TOTAL SYNTHESIS OF TAXAMAIRIN B Taxamairin B, representive of rare naturally-occuring rearrang-ed 9(10→20)-abeo-8, 11, 13-triene diterpenoids, has been firstsynthesized by a eleven-step route in an overall yield of 8.19%,starting from commercially available catechol and 1,3-cyclohexan-dione. The improved Friedel-Crafts annulation, thermodynamicallycontrolled-geminal pairing methylation, the selective oxidation ofallyl group and the selective reduction of the less-hindrancecarbon-carbon double bond are the key steps.

二。美丽红豆杉素B的全合成研究 1，美丽红豆杉素B的首次全合成以价廉，易得的邻苯二酚和1，3-环己二酮为原料，经过改良的Friedel-Crafts烷基化反应，热力学控制的α，β-不饱和酮结构的α一位双烷基化，烯丙位的选择性氧化，以及选择性还原位阻较小的碳碳双键等十一步反应，以8.19％的总收率首次完成了美丽红豆杉素B的全合成。

Water, Beta-glucan, Ascorbic acid, Tri Sodium Ascorbyl Palmitate Phosphate, Magnesium L-ascorbyl -2-phosphate, PEG-60 hydrogenated castor oil, Lecithin, Coceth-7 / PPG-1-PEG 9 lauryl glycol ether/PEG 40 hydrogenated castor oil, DL-panthenol, Retinyl, palmitate, Anthemis Nobilis Flower extracts, Pinebark extract, Phellinus linteus extract, Phellinus linteus / Rice Ferment Extract, Onion extract, Aralia Elata Root Extract, Grape extract, Sandalwood oil, Myrtle oil, Orange oil, 1,3-Butylene glycol, Glycerin, Xanthan gum, Tocopheryl acetate, Ethanol, Methyl paraben

水， β-葡聚糖，抗坏血酸、三磷酸抗坏血酸棕榈酸酯钠、维他命 C 磷酸镁盐、聚乙二醇- 60氢化蓖麻油、卵磷脂、椰油醇聚醚-7 / PPG-1-PEG-9 月桂二醇醚/聚乙二醇40氢化蓖麻油，消旋泛酰醇，视黄醇，棕榈酸盐，白花春黄菊花提取物， Pinebark提取物，桑黄提取物，桑黄/水稻发酵提取物，洋葱提取物，辽东楤木根提取物，葡萄提取物，檀香油，桃金娘油，橙油， 1，3 -丁烯乙二醇，甘油，黄原胶，生育酚，乙醇，羟苯甲酯

The change of adiabatic temperature was small during coupling isomerization with aromatization of hexene-1,because both re.

提出了催化裂化汽油中己烯-1为代表的异构化和芳构化偶合反应的化学平衡模型。

The alkylation of isobutane with butene is very important for the production of reformulated gasoline;however,the severe equipment corrosion and environmental hazards are involved in the current alkylation technology.Therefore,some novel alternative technologies are desired.

异丁烷和烯烃烷基化反应对新配方清洁汽油的生产具有重要意义，而目前的烷基化工艺存在严重的设备腐蚀和污染问题，因此亟需新的替代工艺。

The results indicated that the high level density functional theory calculations can be used to predict the 13C chemical shifts of the modified nanotubes. The calculated results also provided the characteristic chemical shifts values of nitrene (superscript -), carbene (superscript -) and 1,2- and 1, 4-fluorinated nanotubes, which would be helpful for experimental spectrogram assignments. Combined with NMR experiments, these predicted characteristic chemical shifts can be further used to monitor the addition mechanism and the extent of surface modifications on nanotubes.

研究表明高精度的密度泛函理论计算能够用来预测纳米管的13C化学位移，理论研究的结果揭示了氮烯、卡宾以及1，2和1，4氟化的单壁纳米管的若干13C信号特征化学位移值，为实验NMR谱图的归属提供了一定的依据，并且可通过与实验相结合来监测表面官能化碳纳米管加成反应是否发生以及确认其加成方式。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。