烯化

The preparation of potassium malonyloxyborohydride in situ and its seletive hydroborating alkene are described.

介绍了丙二酰氧基硼氢化钾的制备及其原位与烯烃的选择性硼氢化。

A conjugate addition of alkadienyl carbonyl compound with vinyl palladium intermediates which can be formed from oxypalladation of alkynes or allenes was studied, and 1, 6-addition products were obtained.

发现不饱和烃的分子内氧钯化得到的烯基钯中间体能够与不饱和共轭双烯的醛酮反应，选择性的得到1，6-加成产物。

A new monomer,4-hexanoxyl-4′-undecylene-[10]-acyloxyazobenzene was synthesized using the main materials:phenol,underlenic acid,1-bromo- n -hexane, p -nitrophenol,thionyl chloride,by the substitution,reduction,couping and diazotization methods.A new polymer was prepared by hydrosilation reaction of poly (methylhy-drosiloxane) with the monomer.

以苯酚、十一烯酸、正溴己烷、对硝基苯酚和二氯亚砜为主要原料，通过取代、还原、重氮化和偶合等反应，合成了一种新的液晶单体 4-己氧基-4′-十一烯-[10]-酰氧基偶氮苯，并与聚通过硅氢加成生成一种新的高分子液晶。

Allyl starch was prepared by etherification pretreatment of introducing allyl groups onto starch, and then AS-g-PMA was synthesized through graft copolymerization between allyl starch and methyl acrylate. The adhesion to fibers, sizing film and sizing performance of the blended size composed of AS-g-PMA and PVA-1799 were investigated. And the possibility by using AS-g-PMA to substitute PVA component was studied by contrast experiments.

摘〓要：通过烯丙基化变性对淀粉进行预处理制取烯丙基淀粉，再与丙烯酸甲酯进行接枝共聚合成接枝淀粉，文章探索了这种接枝淀粉与PVA1799混合浆的黏附、浆膜及浆纱性能，与目标配方进行比较，揭示出AS-g-PMA取代PVA的可能性。

We studied the nonlinear optical properties of fullerene and its arylatedderivative.They both exhibit weak self-defocusing and strong RSA.

研究了芳化富勒烯及富勒烯的非线性光学性质，它们都具有弱的非线性自散焦和较强的反饱和吸收。

Our group first reported a novel dialkylation reaction of alkyl zinc iodides with aromatic aldehydes and an olefination reaction of benzyl zinc bromides with aromatic aldehydes respectively.

我们实验室分别首次报道了在过渡金属络合物催化下带官能团有机卤化锌试剂与芳香醛的双烷化反应和烯基化反应。

We found that the iodohydroxylation of 1-2-allenyl selenides with I〓 and water can smoothly proceed in aqueous MeCN at 0℃.

我们发现在乙腈水溶液中，1，2-联烯基硒醚可以和碘发生羟碘化作用，碘和羟基高度区域和立体选择性加成到1，2-联烯基硒醚的β，γ-位。

The results indicate the mutual effect exists between the single coals, which could increase the maximum of thermal weight loss obviously and has a small effect on the temperature extent of the weight loss. The main pyrolysis production of coal is coke, but the main production of waste plastics is tar; the yield of water became decrease and the gas became increase by adding the waste plastics. And the CRI and CSR decreased with the ratio of waste plastics in coal. The main ingredients of tar from blend coal are aromatic hydrocarbon and alkane, while those of waste plastics are alkane and alkene. The result of co-coking with coal and waste plastics make the light tar and the aromatic hydrocarbon increase obviously. The combustible ingredient(CO、H2、CH4) of gas from co-coking with coal increase at different ratio; Co-coking with coal and waste plastics could increase the combustible ingredient and thermal value of gas.

结果表明，废塑料与煤混合物在煤的塑性温度区间内存在明显的相互作用，使最大热解失重峰迁移，热解速率变大，且随着废塑料配比的增加呈现规律性的变化；煤热解产物固体焦炭为主，而废塑料的热解产物以焦油为主，废塑料的添加使得总体焦炭和水产率下降，焦炉煤气和焦油的产率增加，即共焦化呈现出明显的&增油减水&效应；随着塑料添加量的增加，焦炭热强度呈现劣化趋势；废塑料代替瘦煤配煤炼焦可使其比例提高到3%而不影响焦炭的质量；纯煤焦化所得焦油以芳香烃类和烷烃类为主，而废塑料热解焦油以烷烃和烯烃为主；废塑料配煤炼焦，可使得的焦油呈现&环构化&和&轻质化&趋势；废塑料的添加可使煤气中的可燃组分(CO、H2、CH4)的含量均有不同程度的增加；废塑料配煤炼焦可以优化焦炉煤气的组成，增加煤气中的可燃组分，提高焦炉煤气的热值。

Feeding for 24h by third instar larvae of the maize stalk borer induced farnesyl pyrophosphate synthase gene expressing, but had no effect on expression of AOC, BX9, PAL and PR2a genes and DIMBOA content.

3玉米螟3龄幼虫处理24h能诱导玉米根中法呢烯基焦磷酸合成酶基因表达，但不能诱导丙二烯氧化物环化酶、β－1，3葡聚糖酶基因（PR2a）、糖基转移酶（BX9）、苯丙氨酸转氨酶基因表达，同时对第二叶和根中丁布含量无显著影响，使第二叶对羟基苯甲酸及第三叶丁布、对羟基苯甲酸、香草酸含量显著降低。

Malonyloxyborohydride,a hydroboration reagent,is prepared by reaction of malonic acid and sodium borohydride,and is used to react with dihydromyrcene in THF.

用一种硼氢化试剂———丙二酸与硼氢化钠反应生成的丙二酰氧基硼氢化钠在THF中与二氢月桂烯反应制备香茅醇。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。