烯化

OH radicals produced by ultrasound in aqueous solution attack phenolic cycle at adjacent or para position of the hydroxyl on phenol so that phenol is changed into small organic molecules such as muconic acid, maleic acid and ethane diacid. These small organic molecules will be oxidized to form carbon dioxide and water by.

苯酚超声降解的作用机理是，超声空化在水溶液中产生的·OH自由基进攻苯酚苯环上羟基的邻位或对位而使苯环断裂生成己二烯酸、顺式丁烯二酸和乙二酸小分子有机物而使苯酚得以降解，这些小分子有机物在·OH自由基的进一步作用下最终被氧化成CO〓和H〓O。

It was found that the thermodynamically unfavourable isomerization of quadracyclane to norbornadiene could be accomplished in the presence of toluene or durene as a co-sensitizer.

首次发现在甲苯、杜苯等芳烃共敏化下，可以使原来不能进行的、热力学不利的四环烷→降冰片二烯异构化得以进行，并根据CIDNP结果提出这是由于生成了敏化剂/底物/芳烃三元基激络合物使反应的势能面改变造成的并促进单线态的系间窜跃。

Subsequently,enol methylation of P in basic condition completed the synthesis of malyngamide O.Applied this route to the synthesis of malyngamides Q and R,the chiral unsaturated acid was connected with the vinyl chloride part by amidation,then the resulting product was converted into the corresponding aldehyde,followed by aldol condensation of the aldehyde with the chlorotitanium enolate of pyrrolidone to complete the skeleton of malyngamides Q and R,then the synthesis of them was completed via enol methylation in acid condition.

该合成路线拓展应用到malyngamides Q和R的合成时，首先用酰胺键将手性不饱和脂肪酸和烯氯片段连接，再转化成相应的醛，与乙酰基吡咯酮进行TiCl_4催化的aldol反应即得到malyngamides Q和R的骨架结构，再经过酸催化的烯醇甲基化反应完成了Q和R的全合成。

We researched on the prepartion of pivotal intermediate 2 and 3 for 1 P-methyl carbapenem antibiotics from intermediate 1, which is subjected to Reformastky reaction, N-alkylation, Dieckmann-type cyclisation, enolization, ester condensation etc. in sequence. The synthesis route of document is optimized by us.

我们研究了1β-甲基碳青霉烯类重要中间体的合成，从中间体1出发经Reformastky反应、水解反应合成出中间体2；经Reformastky反应、烷基化、Dieckmann环合、烯醇化、酯化合成出中间体3，并对其中各步反应作了优化和探索。

The second synthetic strategy commenced from butane-1,4-diol 50, which underwent monobenzylation, Swern oxidation, enolization followed by acetylation and debenzylation to yield an intermediate 46 in an overall yield of 54% in a 4-step procedure.

第二条路线从1，4-丁二醇50开始，这个化合物经过单苄基化、Swern氧化、烯醇化随后乙酰化和脱苄基化共4步反应得到中间体46，总产率54％。

At 15-35℃, copolymerization of acrylamide and styene was carried out in a microemulsion system, in which AM aqueous solution was the continuous phase and St was the dispersed phase using ST-80 as surfactants, respectively. Hydroxamic functions were prepared with hydroxylamine salt at temperatures from 60℃ to 90℃.

以丙烯酰胺水溶液为连续相，苯乙烯为分散相，ST-80为乳化剂制成微乳液，在15~35℃下合成丙烯酰胺与苯乙烯的共聚物，采用程序控温方式，在60~90℃下使用硫酸羟胺将共聚物羟肟化得到产物。

In the synthesis of canthaxanthin by selective catalylitic oxidating of βcarotene,CO2 was used as acidifying or alkalizing agent,which controlled reacting system acidity and protected polyene.,producing less by-products and increasing catalylitic oxidation selectivity.In the addition reaction of isoprene with hypochloric acid,1-chloro-2-methyl-3-buten-2-ol and l-chloro-2-methyl-3-buten-4-ol were made by controlling of the acidity with carbon dioxide i...

CO2作为酸碱调节剂和惰性气体，在β-胡萝卜素催化氧化合成角黄素反应中，可以控制反应体系酸性，保护原料中的双键，减少副反应发生，提高催化氧化反应的选择性；异戊二烯氯醇化生成1-氯-2-甲基-3-丁烯-2-醇和1-氯-2-甲基-3-丁唏-4-醇反应中，CO2代替有机酸作酸碱调节剂，控制次氯酸的生成速度，达到调控反应的目的，反应条件温和，不副产固体。

The palladium-catalyzed heteroannulations of C_(60) with a variety ofο-iodoanilines afforded the first synthesis of C_(60)-fused indoline derivatives.

通过在Pd的催化下，富勒烯和邻碘苯胺类化合物的杂环化反应，首次合成了一系列富勒烯并吲哚啉环衍生物。

In searching for novel and high active fungicides with pyridyl moiety, with Dimethomorph as a model compound and isonicotinic acid as the main starting material, twenty-seven title compounds were designed and synthesized through chlorination, Friedel-Crafts acylation, Wittig-Horner reaction and other steps. All the target structures were confirmed via 1H NMR and elementary analysis.

为了寻找具有高活性的含吡啶杂环杀菌剂，以烯酸吗啉为模板化合物，以异烟酸为起始原料，通过卤代反应、Friedel-Crafts酰基化反应、Wittig-Homer反应等，将吡啶－4-基或2-氯吡啶－4-基引入到模板结构中，设计合成了27个4-［3-（吡啶－4-基）－3-取代苯基丙烯酰］吗啉类化合物，其结构通过1H NMR和元素分析确证。

At the same time, some of the pyrolysates are the important favors in cigarette smoke, such as isophorone and megastigmatrienone, etc. The amounts of these pyrolystaes alter with the change of pyrolysis temperatures and the concentration of oxygen. the lutein is applied to cigarettes as flavoring.

分析结果表明，叶黄素的裂解产物主要是甲苯和对-二甲苯等苯及其同系物、1，2–二氢-1，1，6-三甲基-萘和2，7-二甲基萘等萘及其同系物，另外还生成氧化异佛尔酮和巨豆三烯酮等酮类物质和烯烃类物质等，这些物质随着裂解温度和裂解氛围的变化，其种类和峰面积归一化百分含量有所不同。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新