烯化

The auxiliary can be recovered in high yield (81%) only by filtering and recrystallization. Besides, some other aldehydes have been chosen to test the enantioselectivity of N,N\'-dibenzyl tartamide, in comparison with two other allylaborates reagents developed previously by Roush and Brown, respectively. The results show that %e.e. of homoallylic alcohol is superior to that of the former, and approaches the Brown reagent.

产物经S_N2反应得瑞格列萘中间体-甲基烯丙基-2-氯苯基-叠氮甲烷(17)；同时，将筛选出的新型手性配体N-苄基酒石酸二酰胺用于其他几种醛(正丁醛，异戊醛和环己醛)的不对称烯丙基化反应，并与广泛应用的Roush配体(22)和Brown配体(27)相比较，发现其立体选择性优于Roush配体，并接近Brown配体，但明显具有可回收利用的优势。

By the mechanism of the electrocyclic reaction, three groups of 4-hydroxy-2-cyclobutenones 4 were designed and synthesized to investigate their behaviors underthe thermolysis conditions Meanwhile, a new procedure for preparation of 2(5H)-furanone 5 Was discovered.

根据电环化反应机理，我们设计了三组不同类型的4-羟基-2-环丁烯酮(4)。通过对4-羟基-2-环丁烯酮(4)进行热解，发现了一种制备2(5H)-呋喃酮类化合物(5)的新方法。

Via comprehensive computations, the possibilities of vinylidene and allene intermediates were excluded, and the reaction mechanism was found to contain the following three steps:(1) gold-catalyzed cyclization to give the cyclic intermediate,(2) the cyclic intermediate undergoing a 1,3-H migration to give a more stable intermediate, with the assistance of water-cluster,(3) finially, the 1,2-H or 1,2-silyl migration occuring for generation of the observed product.

通过对各种可能的反应路径的进行计算和比较，排除了亚甲基卡宾和连二烯中间体的可能性，并确定该异构化反应机理包含以下三个步骤：（1）炔丙基吡啶反应在金催化条件下发生分子内的成环得到环状中间体；（2）环状中间体在水分子簇的协助下优先发生1，3-氢迁移反应，异构化得到更为稳定的中间体；（3）最后再进行1，2-氢迁移或是1，2-硅烷基团迁移即得到实验中所观察到的环异构化产物。

Chiral compounds Ⅰ for the first time was applied to allylation of acylhydrazones with allyltrichlorosilane and the results showed that the compound Ⅰ can contribute to the occurrence of the reaction.

首次将手性化合物Ⅰ应用于烯丙基三氯硅烷和酰腙的烯丙基化加成反应中，结果表明化合物Ⅰ能够促进该反应的发生。

Herein, we describe a novel catalysis of palladium complex, which mediates tandem allylation of o-phenylenediamines with 2-ene-1,4-diols using water as solvent.

在本实验中，我们探讨邻－苯二胺类和2—烯—1，4—二醇类在水中进行连续两次烯丙基化的一个新的钯催化系统。

It was found that the reactions of C_(60) with anthranilic acids and isoamyl nitrite in the presence of triethylamine unexpectedly afforded C_(60)-fusedδ-lactones,which would be difficult to be prepared by other known methods.

通过在三乙胺作用下，富勒烯与邻氨基苯甲酸类化合物和亚硝酸异戊酯的环化反应，首次合成了一系列富勒烯并六元环内酯。

Methyl-2,3,5,6-tetrafluoro-benzene methanol was synthesized by chlorination, acylation, fluorination, esterifica- tion, reduction, bromization, reduction from terephthalic acid. Tefluthrin was obtained from-(1RS,3RS)-3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cycolpropa-necarboxylate acid by reacting with 4-methyl-2,3,5,6-tetrafluoro-benzene methanol.

以对苯二甲酸为原料，经氯化、酰氯化、氟化、酯化、还原、溴化、还原七步反应合成了4-甲基-2，3，5，6-四氟苄醇，甲基苄醇与-(1RS，3RS)-3-(2-氯-3，3，3-三氟丙-1-丙烯基)-2，2-二甲基环丙甲酸一步酯化合成了七氟菊酯。

Copolymerize methacrylic acid 3(4′-N,N-dimethylamino) ketone xanthate and acrylamide were copolymerized with N,N-methylene bisacrylamide,and then combined with silane ethylene group in the form of covalent bond on the quartz glass shee t to be made into a sensor,to determine ethanol.

将甲基丙烯酸3-(4′-N，N-二甲氨基)黄酮酯和丙烯酰胺、N，N′-亚甲基双丙烯酰胺共聚并共价键合在硅烷化的含乙烯基团的石英玻片上，制成了可测定乙醇的传感器。

Butadiene was polymerized to some extent in the presence of binary catalyst system NdCl33iPrOHAlEt3 in toluene and the allylchloride was then added to the solution in order to cyclize the formed polybutadiene and cyclopolymerize the unreacted butadiene monomers.

采用NdCl3·3i－PrOH－AlEt3稀土催化剂进行丁二烯的顺式聚合，在聚合过程中引入烯丙基氯，进行分子内环化反应以及单体的环聚反应。考察了稀土催化剂用量、n／n（AlEt3）、环化时间、反应温度、单体浓度等对环化反应的影响，并对产物进行了红外光谱、核磁共振光谱的表

The catalytic performance of a series of supported KNO3 solid bases for the synthesis of methylcyclopentadiene via cyclopentadiene methylation with methanol was investigated.

考察了负载型KNO3固体碱对环戊二烯和甲醇的甲基化制备甲基环戊二烯反应的催化性能。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新