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Propylene production methods including olefin metathesis and catalytic cracking were introduced.

介绍了烯烃经歧化反应和催化裂解生产丙烯的方法,列举了国内外各大化工企业在该领域的研究及应用状况。

The catalytic performance of complex 41 has been investigated.Complex 41 proves to be an excellent catalyst for cross metathesis reaction of 1-butenewith isomerized octadecene.

研究了配合物41催化的1-丁烯与异构化后十八烯的交叉交互置换反应,证明配合物41是性能优良的催化剂。

The influence of the amount of catalyst, reaction temperature, molar ratio of β-methylnaphthalene and olefins, reaction time and the amount of solvent has also been studied in detail.

详细考察了三氯化铝催化剂用量、反应温度、芳烯物质的量比、反应时间及溶剂用量对β-甲基萘与长链烯烃烷基化的影响。

It also classifies them in accordance with the compound method of triazene reagents as follows: reagents diazotizated with sodium nitrite and muriatic acid, reagents diazotizated with nitrosyl positive ion, reagents diazotizated with n-butyrate nitrite.These reagents with high sensitivity and good choice have been widely applied to the determination of microa mounts of cadmium and...

按三氮烯类试剂合成的方法进行分类,分别为在亚硝酸钠和盐酸作用下重氮化的试剂,在亚硝酰正离子作用下重氮化的试剂,在亚硝酸正丁脂作用下重氮化的试剂,此类试剂灵敏度高,选择性好,广泛应用于被镉、汞等过渡金属离子污染的环境样品的分析中。

In chapter 4 an abnormal reaction that the nitro group of 1-aryl-2-nitroethenescan be easily replaced by the organic moity of FG-RZnI using Ni〓 and tertiaryamine as catalyst was first given. The experimental results show that in the presenceof catalytic amount of Ni〓 and tertiary amines, the reaction of FG-RZnI andl-aryl-2-nitroethenes give the substitution products l-aryl-l-alkene, instead ofMichael addition products.

通过实验发现,在催化量的Ni〓及叔胺催化下, l-硝基-2-芳基乙烯与烷基碘化锌并不进行Michael加成反应,而是发生1-硝基-2-芳基乙烯中硝基被取代的反应,生成了高产率的1-芳基-l-烯烃,由于此反应的原料易得、反应条件温和、产物的产率高,因而是合成l-芳基-1-烯烃的有效方法。

This effect is probably related to the interaction between amorphous PE in PP copolymer and PE phase in mPE and EPDM. T〓 of mPE decreases with increasing the octene content, and maximum damping of the glass transition relaxation increases.

PP/SEBS共混物中SEBS的玻璃化温度随SEBS含量的增加而降低,表明共聚PP中的PE相对SEBS中丁二烯嵌段的玻璃化松弛转变影响很小。mPE中的辛烯含量越高,其低温损耗峰的强度越高,玻璃化温度越低,低温韧性越好。

The described tackifier is applicable to perchloride raw rubber based on fragment form and non-halide or low-halide raw rubber, and can make most of allyl group implement bromation reaction in priority.

所述增粘剂基于碎片形式的高氯化生橡胶和非卤化或低卤化的生橡胶,并优选使大部分的烯丙基进行溴化反应。

It showed that the blend system had much slower Rp than that of hybrid monomer, either of acrylate double bond or propenyl ether double bond, and propenyl ether double bond conversion of hybrid monomer was much higher than that of the blend system at the end.

杂化单体与相同类型的混合体系相比,每种基团的反应动力学性质都得到了促进,丙烯酸酯和丙烯基醚双键的聚合速率都有了很大提高,丙烯基醚双键的转化率较混合体系有很大增加。

We prepared the pyrethric acid II through four reactions: esterification, oxidation, decomposition, diesterification. And the original synthesis route of the pyrethric acidII was improved: the yield of oxidation of allyl rise through increasing the activity of Selenium dioxide; in the document, tert-butyl-trans -2, 2-dimethy1-3-(2"-methoxycarbony1-1"-propenyl)cyclopropanecarboxy late was synthesized from tert-butyl-trans-2,2-dimethyl-3-(2 -formyl-r -propenyl) cyclopropanecarboxylate with two steps, with low yield.

我们经过酯化,氧化,成双酯,热分解四步反应,成功地得到了第二菊酸,并改进了原第二菊酸的合成路线:通过改变二氧化硒的活性提高了烯丙甲基的氧化产率;将原路线中醛氧化成羧酸、羧酸酯化的两步反应改为醛和甲醇、二氧化锰等作用一步直接酯化的方法,减少了反应步骤,提高了总收率。

Catalysts in three synthesis routes,the hydroxylation of 4-tert-butyl-phenol,the alkylation of pyrocatechol by tert-butyl alcohol and the alkylation of pyrocatechol by isobutene,were discussed in detail in terms of reaction conditions,catalysts,temperature,reaction time etc.

论述了对叔丁基苯酚羟基化法、邻苯二酚与叔丁醇烷基化法和邻苯二酚与异丁烯烷基化法生产对叔丁基邻苯二酚的合成路线的催化剂。

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