烯化

Photoreactions of 8 with 15-19, on the other hand, furnished the corresponding [2+2] cyclobutane products and the annulation products together.

二氯马来酰亚胺（8）与15—19的光化反应中则分别得到相应[2+2]的环丁烷产物和增环产物，在与19的反应中，还得到由环丁烷产物脱氯化氢后得到的环丁烯开环的二烯产物。

The relation of the chromatographic retention indices of alkene to topological index,double bond atomic hybridization state index,polarizability effect index of branched chain to double bond atomic,immobile liquid polarity values and column temperatureat different temperatures on different stationary phases was studied.

通过对部分烯烃在不同固定相不同柱温下的1031个样本集的气相色谱保留指数值与其部分参数关系的研究，发现RI与拓扑指数、双键原子杂化状态指数、支链对双键的极化效应指数、固定液极性值及柱温的关系可表示为：^RI=-58.138+57.7460Q-8.2591Q+0.120T+0.807CP+36.460PBD+7.919DHSI(R=0.9989)继以留一法(Leave-one-out，LOO)进行交互检验，相关系数RCV=0.9977，说明所建模型具有良好的稳定性和预测能力，较好地揭示了烯烃类化合物气相色谱保留指数RI随固定相极性、柱温的改变而变化的规律

Camphene is widely applied to synthesize spice and medicament asimportant chemical material.At present,the main source of camphene is theisomerization of turpentine which is abundant in Guangxi Province.

莰烯是重要的化工原料，广泛应用于香料合成、药物合成等领域；目前莰烯的主要来源是松节油的异构化，而广西盛产松节油。

Seventhly, the effect of reuse of HY zeolite on isomerization reaction wasstudied.The results were as follows:when the HY zeolite was used many timescontinuously, the conversion rate of pinene dropped down markedly, but theselectivity of camphene fell no more.

7HY型沸石分子筛的重复使用对异构化反应的影响的结果指出，HY型沸石分子筛连续多次重复使用，蒎烯转化率显著降低，但莰烯选择性没有明显降低，其经烧炭再生能重复利用。

In my opinion, Cu complexes with unsaturated alcohol to form a complex compound; the nitrogenous compound introduced serves as the complex compound's stabilizing agent and reduces activation energy of reaction; TMPO serves as oxygen carrier and displays it's selective oxidation function. This new method and mechanism also demonstrates significance to other similar organic reactions.3 In the chlorohydrin reaction, NaCIO is replaced by Ca2see Chapter4.4.3.4(2 .A, this method hasn't been reported in previous literature,which exerts more buffer action to the react system, the yield increased from 52% to 88.6%; at the same time it solve the problem of poor stability and low percentage composition of NaCIO.

认为：CuD与烯醇形成络合物：含氮有机物的引入起到稳定络合物，降低活化能的作用：而TMPO则充当携氧子起传递氧的作用，并具有选择氧化功能：这种新的方法和理论对类似的反应(不饱和醇类在络合体系下选择性催化氧化为对应的醛也具有重要的指导作用。3在异戊二烯的氯醇化反应中，用次氯酸钙代替次氯酸钠见第4章4.3.4(2.A，本方法未见文献报道，使反应系统更加温和，收率由52%提高到88.6%：并解决了次氯酸钠稳定性差、有效氯含量低的实际问题，具有重要的实用意义。

Linear solvation energy relation was firstly introduced in the paper, and the method and step of gaining the special parameters of solvent and solute were introduced in detail, and these special parameters were used to selection and optimization of extractive agent in extractive distillation. The model of predicting activity coefficient at infinite dilution was established by linear solvation energy relation. By the above theory, several candidate solvents were selected to separate C5 fraction, and by experiment of vapor-liquid phase equilibrium at atmosphere pressure, the mixture of N-methyl-pyrrolidone including 4% water was used extractive agent of separating C5 fraction. Then binary vapor-liquid phase equilibrium of the some compound in C5 fraction and N-methyl-pyrolidone were determined at atmosphere pressure and correlated by NRTL equation. Isoprene being objective compound, experiments were operated in the laboratory-scale column; the processes were simulated by RadFrac model in ASPEN PLUS. And by the combination of experiment and simulation, the new process of separation of C5 was established.

本文首先对线性溶剂化能关系进行了分析介绍，也介绍了采用溶剂化能关系得到溶质溶剂特性参数的方法步骤，并将这些参数用于萃取精馏萃取剂的选择与优化；也通过线性溶剂化能关系式建立无限稀释活度系数预测模型，取得了一定的预测精度；将通过上述方法初选的溶剂进行了常压汽液平衡的测定研究，通过实验研究选定含水4%的N-甲基吡咯烷酮溶液做为C5分离的萃取剂，测定了大量N-甲基吡咯烷酮与C5组分的二元平衡数据，并进行关联计算；以异戊二烯为目标产物在实验室规模的精馏塔内进行了C5分离的实验研究，取得大量塔内数据；通过选用合适的热力学模型，采用ASPEN中RadFrac模块对分离过程进行模拟研究，通过实验与模拟相结合，建立了C5分离的新工艺，为将来的工业化打下了坚实的基础。

A catalyst for preparing propylene by dismutation reaction of the gas mixture containing ethylene and butylene is composed of the active components (5-30%) including tungsten oxide, molybdenum oxide and rhenium oxide and the carrier (more than 50 wt.%) which may be molecular sieve of Silicate-2,H, beta, SAPO, ZSM, or MCM type.

一种以含乙烯和丁烯的混合气歧化制丙烯催化剂，组成为ABC/D，活性组份总的重量担载量为5－30％；其中A为钨的氧化物，B为钼的氧化物；C为铼的氧化物；D为混合物载体并且主要为分子筛(重量含量大于等于50％)，包括Silicate－2，Y，Hβ，SAPO系列，ZSM系列，和MCM系列分子筛。

Zeolite shows high catalytic activity for hydration etherification of propene, but its stability needs to be improved.

采用该方法改性的催化剂，对丙烯水合醚化反应连续运转 72 0h ，丙烯转化率由 5 6 6 %仅降为 5 2 %，表明催化剂稳定性得到明显改

From 3-chloropropene bycondensation with sodium ethylate in ethanol to form 3-ethoxypropene followed by anti-Markovnikov addition with HBr inthe presence of benzoyl peroxide.

3-氯丙烯与乙醇钠在乙醇中回流制得3-乙氧基丙烯，继而在过氧苯甲酰存在下，与溴化氢经反马氏加成制得1-溴-3-乙氧基丙烷，总收率89。

PH of filtrate is kept below 0.65 in order to avoid the reaction between sodium formate and iodine bromide. Then iodine bromide halogenation method is used to determine quantitatively the content of the third monomer, i.

控制滤液pH在0.65以下，以防止甲酸钠和溴化碘起反应，然后用溴化碘卤化法定量测定滤液中的第三单体甲基丙烯磺酸钠的含量。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新