烯丙醇

While the adsorptions of 1-propanol and 1-Br-propane at 100℃ give rise to 1-propoxy species, which mainly converted to propanal at higher temperature. IR spectrum arising from the interaction of propene with the catalyst at 100 ℃ shows the IR bands of allyl alcoholate and isopropoxy species. As the temperature was increased to 150℃, the bands ascribable to the adsorbed acetone and acrolein were observed. Based on these results, it is suggested that isopropoxy species is one of the intermediates for SOP to acrolein over MoPO/SiO〓 catalyst.

2原位IR光谱实验结果表明：200℃时丙烷/O〓混合气在催化剂表面吸附后的IR谱与同温度下异丙醇吸附的IR谱相似，均检测到吸附态丙酮物种和丙烯醛物种的IR谱峰；溴代异丙烷和异丙醇在催化剂表面吸附后均转化为异丙氧基，异丙氧基主要转化为丙烯和丙酮，丙烯进一步转化为丙烯醛；溴代正丙烷和正丙醇在催化剂表面吸附后均转化为正丙氧基，正丙氧基主要转化为丙醛；丙烯在催化剂表面吸附后转化为σ-氧烯丙基和异丙氧基，升温后σ-氧烯丙基转化为丙烯醛而异丙氧基转化为丙酮。

While the adsorptions of l-propanol and 1-Br-propane at 100 癈 give rise to 1-propoxy species, which mainly converted to propanal at higher temperature. IR spectrum arising from the interaction of propene with the catalyst at 100 癈 shows the IR bands of allyl alcoholate and isopropoxy species. As the temperature was increased to 150 癈, the bands ascribable to the adsorbed acetone and acrolein were observed. Based on these results, it is suggested that isopropoxy species is one of the intermediates for SOP to acrolein over MoPO/SiO2 catalyst.

原位IR光谱实验结果表明：200℃时丙烷／O_2混合气在催化剂表面吸附后的IR谱与同温度下异丙醇吸附的IR谱相似，均检测到吸附态丙酮物种和丙烯醛物种的IR谱峰；溴代异丙烷和异丙醇在催化剂表面吸附后均转化为异丙氧基，异丙氧基主要转化为丙烯和丙酮，丙烯进一步转化为丙烯醛；溴代正丙烷和正丙醇在催化剂表面吸附后均转化为正丙氧基，正丙氧基主要转化为丙醛；丙烯在催化剂表面吸附后转化为σ-氧烯丙基和异丙氧基，升温后σ-氧烯丙基转化为丙烯醛而异丙氧基转化为丙酮。

Firstly, one of the two key intermediates, tetrahydrofuran fragment with aterminal alkyne 27, was prepared from D-glucose utilizing a multiple-step sequencedeveloped by us earlier.

在本组过去的工作基础上，我们从葡萄糖出发，获得了含有四氢呋喃环的炔化合物27。同时，从木糖及炔丙醇出发，获得了一端为γ内酯环的烯基碘化合物14，即C1-C13片断。

Mainly engaged in: Hydrogen-imide hydrochloride, o-chlorophenyl cyclopentanone, 3.4 dimethoxy ethyl benzene, butyn single potassium acid, potassium ethyl malonyl, Ding amide, amide isobutyraldehyde , allyl chloroacetate, isopropyl chloroacetate Benzyl aluminum, cyclopentene, cyanide-o-chlorophenyl, o-methyl chloride, sulfuric acid chloride, p-chlorophenol, imidazole, Pinacolone, one chlorine Pinacolone.

主要经营：盐酸氢亚胺、邻氯苯基环戊酮、3.4二甲氧基苯乙酯、丁炔二酸单钾盐、丙二酸单乙酯钾盐、丁酰胺、异丁酰胺、氯乙酸烯丙酯、氯乙酸苄酯异丙醇铝、环戊烯、邻氯苯氰、邻氯苯甲酯氯、硫酸氯、对氯苯酚、咪唑、频呐酮、一氯频呐酮。

Amino-2-methylpropanol was used as the chemical modifying reagent of fatty acids to modify the carboxyl group into nitrogen-containing heterocycle which would effectively prevent the migration of carbon double bonds of the alkenyl in the electron impact source.

以2-氨基－2-甲基－丙醇为脂肪酸的化学修饰试剂，气相色谱－电子轰击质谱分析葵子油脂肪酸。2-氨基－2-甲基－丙醇将脂肪酸羧基修改为含氮杂环，使在EI源中避免了链烯基中碳碳双键的移动。

In the second section, with ketone and hydroxylamine hydrochloride as the starting materials, 3-aminopropanol is prepared via three steps including reaction of ketone and hydroxylamine hydrochloride , condensation of ketoxime and acrylonitrile, and hydrogenation cracking of condensation product.

第二是3-氨基丙醇的制备，由酮肟丙烯睛缩合物催化氢化裂解制得：即先以酮、盐酸羟胺为起始原料在碱性条件下合成酮肟，再与丙烯腈反应生成酮肟丙烯腈缩合物后经催化氢化裂解制得3-氨基丙醇。

The electron impact mass spectra of the chemical products modified by 2-amino-2-methylpropanol of the fatty acids in sunflower oil were analyzed; the allocation rule for the carbon double bonds in olefinic acids was discussed and the location of the carbon double bonds of the fatty acids in sunflower oil was confirmed.

解析了葵子油脂肪酸2-氨基－2-甲基－丙醇化学修饰产物的EI质谱图，讨论了烯酸中碳碳双键的定位规则，确定了葵子油脂肪酸中碳碳双键的位置鉴定出葵子油6种脂肪酸，不饱和脂肪酸相对含量为89.41%，其中人体必需脂肪酸9，12-十八碳二烯酸含量占65.30%。

The reactions of benzaldehydes bearing an ortho substituent group on the phenyl ring with propargyl bromide may yield a mixture of regioisomers (homopropargyl and homoallenyl alcohols) or a single homoallenic alcohol due to the steric effect.

邻位上的取代基由于位阻原因往往使反应得到含有高丙二烯醇和高炔丙醇的混合物或者单一的高丙二烯醇。

Comparison was synthesized from undecylenic acid and iso-propyl alcohol over HPWA-SBA-15. Comparison was made among different catalysts, and influence of composition and repeated use of the catalyst were investigated.

将该催化剂用於催化以十一碳烯与异丙醇为原料合成十一碳烯酸异丙酯，进行了不同催化剂化剂的对比实验以及催化剂组成和重复使用的考察。

Urea adduction, in which i-propanol and water was used as mixed solvent, was introduced to separate α-olefins from coker kerosine distillate 220-320℃.

研究结果表明，采用异丙醇尿素水溶液脱蜡工艺，可从焦化柴油中成功分离得到直链α烯烃和直链烷烃，焦化柴油可作为C〓-C〓直链α烯烃与直链烷烃的一个重要来源。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新