烯丙醇

The latter was esterified with allyl alcohol in the presence of the catalyst toluene-p-sulfonic acid to get the title compound in the yield of 87.1%.

后者在对甲苯磺酸催化下与烯丙醇经酯化反应制得标题化合物，收率为87.1%。

Ce2(SO4)3 was used as an inexpensive and effective catalyst for the Friedel-Crafts alkylation of aromatic compounds with benzyl alcohol s, allyl alcohols and benzyl chlorides.

硫酸亚铈作为一种便宜的和有效的催化剂催化芳香化合物与苄基醇、烯丙醇类化合物和苄基氯的傅-克烷基化反应。

Ce2(SO4)3 was used as an inexpensive and effective catalyst for the Friedel-Crafts alkylation of aromatic compounds with benzyl alcohols, allyl alcohol s and benzyl chlorides.

硫酸亚铈作为一种便宜的和有效的催化剂催化芳香化合物与苄基醇、烯丙醇类化合物和苄基氯的傅-克烷基化反应。

A mild and highly efficient ZnCl2-catalyzed direct alkylation of active methylene compounds with benzylic and allylic alcohols has been reported.

报道了ZnCl2催化的活泼亚甲基化合物和苄醇或烯丙醇的直接烷基化反应。

Synthesis of mesitylene by catalytic alkylation of mixed C9 arenes and isobutene

可由三甲基氯硅烷与无水烯丙醇反应来制取。

To an asymmetric synthesis of (1), we applied a type of Roush addition in the first step to introduce the C4 stereocenter, and then the chair substance -122 are readily transformed into the title compound -aphanorphine using the same route as to the racemic target molecular.

aphanorphine分子的不对称合成是在第一步通过对甲氧基苯乙醛（119）发生Roush反应引入手性，得到手性高烯丙醇-122，然后利用与合成外消旋目标分子相同的方法，光学纯化合物-122经一系列转化可得到光学纯中间体化合物139；化合物139发生分子内傅—克反应的过程中，由C4位手性立体特异地控制C1位手性的生成，从而解决-aphanorphine分子中的手性问题。

Various alcohols are tolerable under the present conditions including benzylic alcohols,allylic alcohols as well as simple aliphatic alcohols.

醇的范围非常广，二苯甲醇、1-苯乙醇、烯丙醇衍生物等含苄醇结构的地物能够以最高接近定量的产率得到产物。普通烷基醇如环己醇，甚至最简单的甲醇和乙醇也能顺利反应，产率中等。

Moreover,the selective oxidation of primary and secondary alcohols to corresponding carbonyl compounds with the multinuclear copper complexes Cul-Cu4 as catalysts have been conducted using TBHP and O_2/TEMPO,respectively.Among them,the copper complex Cu3 showed the best performance.On the performances of the two classes of oxidants,benzylic and heterocyclic alcohols could be effectively oxidized to carbonyl compounds.Specifically,the secondary alcohols could be effectively oxidized to ketones with excellent selectivity up to 100%in the presence of TBHP and the allylic alcohols could be effectively oxidized to aldehydes in the presence of O_2/TEMPO system.

实验结果还表明，在TBHP或O_2/TEMPO存在下，各配合物催化剂均能使各种取代芳香伯/仲醇以及杂环醇等以不同程度的转化率和选择性转化成相应的醛或酮，其中，配合物Cu3在O_2/TEMPO存在下可使苯甲醇和烯丙醇等以较高转化率和近100%的选择性转化成相应的醛，而对其它芳香醇和脂肪伯/仲醇等的催化性能则较差；在TBHP存在下，配合物Cu3则可使1-苯乙醇和其它仲醇以较高转化率和近100%的选择性转化为相应的酮，但对各类其它伯醇选择氧化的性能相对较差。

The effect of emulsifying agent and reaction temperature on the stability of the polymeric system was investigated.

本文研究了乳化剂和反应温度对聚合体系稳定性的影响；(NH4 ) 2 S2 O8—DMAEMA—NaHSO3引发剂和烯丙醇对产品性能的影响。

The key steps were the stereospecific conversion of both allylie carbamates 10 and 13 into 11 by Li_2Cu_3(CH_2)_5 and the stereoselective hydroxylation of unsaturated side chain by OsO_4-NMO.

合成的关键步骤是用Li_2Cu_3(CH_3)_5立体专一地转化烯丙醇苯胺基甲酸酯10和13成为11和用OsO_4-NMO在化合物16的不饱和侧链上立体选择性羟基化。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新