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烯丙醇

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Industry production method of allyl alcohol , development of downstream products and its applications were introduced, and development suggestions were put forward.

介绍了烯丙醇的工业生产方法、下游产品的开发及应用情况,并提出发展建议。

The catalytic effect of basic lithium phosphate on the preparation of allyl alcohol by isomerization of propylene oxide was studied in this dissertation.

本论文主要研究了碱性磷酸锂在环氧丙烷异构化制烯丙醇反应中的催化作用。

The isomerization reaction of propylene oxide to produce allyl alcohol catalyzed by basic lithium phosphate was studied.

研究了环氧丙烷在碱性磷酸锂催化作用下异构化生成烯丙醇反应过程,考察催化剂的制备条件,异构化温度对催化性能的影响,以及催化反应机理和动力学特性。

Low concentration of allyl alcohol helped to increase the reaction rate and high concentration of H2O2 could decrease the selectivity to glycidol using water as a solvent.

当催化剂用量一定时,以水为溶剂,较低的烯丙醇浓度更有利于反应的进行,而较高的双氧水浓度则会降低产物的选择性。

The catalytic properties of Ti-MWW and the reaction conditions in epoxidation of allyl alcohol to glycidol have been studied. It was found that Ti-MWW-PI synthesized under dynamic crystallization conditions has more effective catalytic performance.

对Ti-MWW 催化烯丙醇的环氧化性能和反应条件进行了研究,发现动态法合成的Ti-MWW-PI 有更好的催化性能。

The resin was used as a selective oxidant for oxidation of allyl alcohol to allyl aldehyde.

合成了铬酸氢根季铵盐树脂,以它作为一种选择性氧化剂应用于烯丙醇的氧化反应,考察了温度、时间、溶剂、树脂与醇的物料比对氧化反应的影响。

A resin derived from allyl alcohol that hardens when cured; used as an adhesive.

烯丙醇制成的树脂,加工后变硬,用作粘合剂。

Lightfoot et al have developed one of these iridium-based systems for the stereocontrolled synthesis of lilial by asymmetric reduction of an allyl alcohol and subsequent oxidation of the alcohol.

Lightfoot等发展了一种基于铱的系统,通过烯丙醇和第二阶段酒精氧化的不对称还原,用来进行铃兰醛的立体控制合成。

The yield of allyl glycidyl ether can reach up to 96% at 30 ℃ for 3 h at a molar ratio of 1 to 1.5 of sodium allylate to epichlorohydrin.

醚化反应中固体烯丙醇钠与环氧氯丙烷摩尔比为1:1.5,在无水条件下于30℃反应3 h,烯丙基缩水甘油醚的收率达96%以上。

Ti-MWW is more attractive by a comparison with those conventional titanosilicates (TS-1,Ti-MCM-41,et al ) in the epoxidation of linear functionalized alkenes, on which the epoxidation of allyl alcohol to glycidol is one of the most industrial promising processes for benign reaction conditions, high yields of the product and environment friendly.

Ti-MWW 对线性官能烯烃的环氧化具有优良的催化性能,特别是对烯丙醇环氧化制缩水甘油的过程,其反应条件温和,产率高,且对环境友好而最具有工业应用前景。

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