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In chapter three, the activating agents of ytterbium have been examined. Barbier-type reaction promoted by ytterbium metal was examined. The experimental results shown that the yield of Barbier reaction of imines with allylic bromide promoted by ytterbium is higher than that of aldehydes and ketones with allylic bromide under the same reaction conditions. In this chapter, the reductive cleavage of Se-Se and S-S bond induced by ytterbium metal was also studied.

首先研究了金属镱的活化剂以及活化方法,接着考察了金属镱促进的Barbier反应及其在合成高烯丙基胺和高烯丙基醇中的应用,以及影响该反应的主要因素;究了金属镱促进的二硫醚和二硒醚的S—S键和Se—Se键的还原断裂,继而与氯代烃,胺基甲酰氯反应生成相应的硫醚,硒醚,胺基甲酸硫代酯和硒代酯。

Mainly engaged in: Hydrogen-imide hydrochloride, o-chlorophenyl cyclopentanone, 3.4 dimethoxy ethyl benzene, butyn single potassium acid, potassium ethyl malonyl, Ding amide, amide isobutyraldehyde , allyl chloroacetate, isopropyl chloroacetate Benzyl aluminum, cyclopentene, cyanide-o-chlorophenyl, o-methyl chloride, sulfuric acid chloride, p-chlorophenol, imidazole, Pinacolone, one chlorine Pinacolone.

主要经营:盐酸氢亚胺、邻氯苯基环戊酮、3.4二甲氧基苯乙酯、丁炔二酸单钾盐、丙二酸单乙酯钾盐、丁酰胺、异丁酰胺、氯乙酸烯丙酯、氯乙酸苄酯异丙醇铝、环戊烯、邻氯苯氰、邻氯苯甲酯氯、硫酸氯、对氯苯酚、咪唑、频呐酮、一氯频呐酮。

Dimethyldiallylammonium chloride and copolymer comprising DMDAAC and acrylamide have been synthesized from dimethylamine ,allylchloride and AM.

以二甲胺、氯丙烯等为原料合成二甲基二烯丙基氯化铵,再与丙烯酰胺共聚生成共聚物。

Company Product and its annual output to 12,000 tons Furfuryl / year, Furan Resin 5,000 tons / year, 5,000 tons of acrylamide solution / year, 2,000 tons of acrylamide Crystal / year, polyacrylamide Dry powder 1,000 tons / year.

企业主要产品及其年产量为糠醇12000吨/年,呋喃树脂5000吨/年,丙烯酰胺溶液5000吨/年,丙烯酰胺晶体2000吨/年,聚丙烯酰胺干粉1000吨/年。

Taking acryl amide, dimethyldiallyl ammonium chloride, acrylic acid as the monomer, amphoteric polyacrylamide was prepared by solution copolymetization. The effect of reaction conditions on the molecular weight and flocculation performance of AMPAM was studied.

以丙烯酰胺、二甲基二烯丙基氯化铵、丙烯酸为单体,用溶液共聚法制备两性聚丙烯酰胺,研究了反应条件对两性聚丙烯酰胺分子量及絮凝性能的影响。

Firstly, Copolymerization of acrylamide and styrene was carried out in a microemulsion system, in which AM aqueous solution was the continue phase and St was the dispersed phase using ST-80 as surfactants respectively, then hydroxamic functions were prepared with hydroxylamine salt at temperatures of from 60℃ to 90℃.

首先以丙烯酰胺水溶液为连续相,以苯乙烯为分散相,ST-80为乳化剂制成微乳液,在15℃~35℃合成丙烯酰胺与苯乙烯的共聚物;然后采用程序控温方式,在60℃~90℃用硫酸羟胺将共聚物羟肟化合成了一种带有苯环结构的嵌段型氧肟酸类聚合物材料。

At 15-35℃, copolymerization of acrylamide and styene was carried out in a microemulsion system, in which AM aqueous solution was the continuous phase and St was the dispersed phase using ST-80 as surfactants, respectively. Hydroxamic functions were prepared with hydroxylamine salt at temperatures from 60℃ to 90℃.

以丙烯酰胺水溶液为连续相,苯乙烯为分散相,ST-80为乳化剂制成微乳液,在15~35℃下合成丙烯酰胺与苯乙烯的共聚物,采用程序控温方式,在60~90℃下使用硫酸羟胺将共聚物羟肟化得到产物。

The copolymer of N isopropylacrylamide and acrylamido azobenzene was synthesized for the study of the effect of the photoisomerization of a water soluble copolymer containing azobenzene groups on the photocontrolled release behavior of liposomes.

为了研究侧链含有偶氮苯基的水溶性共聚物的光异构化对脂质体内包容物的光控释放的影响,设计合成了N-异丙基丙烯酰胺和丙烯酰胺基偶氮苯的共聚物。

A new corrosion inhibitor and Universal antibacterial reagent, namely, the copolymer of N-isopro-pylacrylamide and N-allyl-1-benzoyl-3-phenyl-4,5-dihydro-4-formamido pyrazole was prepared.

合成了一种新的腐蚀抑制及广谱抑菌剂:N-异丙基丙烯酰胺与N-烯丙基-1-苯甲酰基-3-苯基-4,5-2H-4甲酰胺基吡唑的共聚物PNIPAM-Co-PBPCP。

Several physical and chemical properties, such as pH, refractive index,heavy metal content, infrared spectrum, heat stability and residual acrylamide, were determined for medical-use polyacrylamide hydrogel samples.

医用聚丙烯酰胺是以丙烯酰胺为原料合成的,具有广泛用途的水溶性高分子,PAM水凝胶主要用于人体软组织填充[1,2 ] ,也可用于医药软膏、药膜和药物载体。医用PAM水凝胶的主要理化性能包括外观、pH值、折射率、重金属含量、红外光谱、化学热稳定性和丙烯酰胺单体残留量。

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