烯丙胺

In this paper, chiral molybdenum or tungsten 2'-pyridinyl alcoholate complex catalyzed asymmetric epoxidation of cis-1-propenylphosphonic acid in H2O was reported.

目前磷霉素的生产是通过以Na2WO4为催化剂、在乙醇中以30%的H2O2将顺丙烯膦酸环氧化得到消旋产物，再利用α-苯乙胺进行拆分而得到[2，3]。

As a precursive work of polymerization directly from vesicles, a polymerizable surfactant, allyl dodecyl dimethylammonium bromide was synthesized, and spontaneous stable vesicles were formed from aqueous solutions of ADDB and sodium dodecyl sulfonate in equimolar composition.

作为可聚合囊泡制备的前期基础工作，研究了一种可聚合的囊泡体系：1-丙烯基－2，2，二甲基－十二烷基溴化胺和ADDB与十二烷基磺酸钠的等摩尔比混合体系。

In this thesis, monomer with unsaturated double bond was firstly synthesized byreacting acryloyl chloride with bifunctional monomer. Such synthesized monomer ormonomer with initial unsaturated double bond was used to prepare linear polymericmaterials by free radical polymerization. A series of new degradable space polymerswith acylamino bond were subsequently synthesized using diisocyanate as thecross-linker.

本文首先通过丙烯酰氯和双官能团单体反应引入不饱和双键，或者直接使用具有不饱和双键的单体，通过自由基聚合得到含有活泼羟基或氨基的线型高分子聚合物，再用二异氰酸酯作为交联剂交联，从而合成了一系列基于酰胺键的新型可降解高分子体型聚合物。

Similar to S-adenosylmethionine decarboxylase(B26),S-adenosylmethionine methyl-transferase(B70), allene oxide synthase(B38),ethylene receptor(B96),cytochrome P450(B58) and methionine synthase (B77) were found in ovaries of Pingyi Tiancha at 1d before the blossom day,which related to plant hormone and could participate in metabolic pathways of ethylene,polyamine,jasmonate acid and gibberellin,et al.,as well as had close relationship with maturity and senescence of plants.

在平邑甜茶开花前1d的子房中发现的S-腺苷甲硫氨酸脱羧酶(B26)、S-腺苷甲硫氨酸甲基转移酶(B70)、丙二烯氧化合酶(B38)、乙烯受体(B96)、细胞色素P450酶(B58)、甲硫氨酸合酶(B77)等相似基因片段与植物体内的生长素有关，将会参与乙烯、多胺、茉莉酸、赤霉素等的代谢途径，与植物的成熟和衰老具有密切的关系。

We also for the first time compared the the storage stability of the allylamine plasma samples in the different mediums , including the hydrophilicity and biocompatibility, and the results indicated the samples had good stability in the different mediums.

同时还首次比较了丙烯胺等离子体修饰样品在多种不同介质中的储存稳定性，包括亲水性和生物相容性，结果显示样品在不同介质中均有较好的稳定性。

Secondly, the pulse discharge plasma with allylamine was discussed, and the modification results with two kinds of discharge models were compared. The results showed that discharge models had influences on the plasma treatment results, especially under lower pressure and higher temperature with pulse discharge. The nitrogen element content in the layer under the pulse discharge was obviously lower than that under the continuous discharge, but there was higher proportion NH〓 groups remaining in the layer under the pulse discharge. The sample surfaces obtained by pulse discharge also had good biocompatibility.

其次讨论了脉冲放电模式下丙烯胺单体的等离子体修饰，比较了两种放电模式对修饰结果的影响，研究结果显示，放电模式对表面修饰层的结果有一定的影响，其中脉冲放电对低压及高温两等离子体条件下的影响尤为明显；脉冲放电下所得到的修饰层中的氮元素含量明显低于连续放电模式下，而脉冲放电下有较高比例NH〓基团保留在修饰层中；脉冲放电所得到的表面修饰层同样有较好的生物相容性。

The deposition thickness of allylamine was increased with the treating time. The surface textures were changed following different procedures except allylamine groups and it means that the 30 min deposition thickness of allylamine is too thin to change the surface contours.

SEM-EDS的结果显示在未经任何处理及经氩气电浆清洁后的钛金属表面，侦测到主要为钛元素，丙烯胺电浆处理后，即可测到氮元素；戊二醛作用后表面有氧元素的出现；白蛋白处理后即可测得碳及氧元素。

During the low temperature plasma polymerization, different factors (reaction power, pulse duty factor, reaction time, bias voltage and pressure) were investigated to get the best film. The results of X-ray photoelectron spectroscopy and Fourier transformed infrared spectoscopy implied that polymer nano-film containing carboxyl or amido were deposited successfully by using allylamine or acrylic acid as a reagent, respectively.

低温等离子聚合过程中，研究了反应的功率、脉冲占空比、反应时间、偏压、反应室压强这五个因素对薄膜性质的影响，确定了最佳的工艺参数。X光电子能谱和傅立叶转换红外光谱分析结果表明，以丙烯胺和丙烯酸为反应物可以在样品表面分别得到含有羧基或氨基的有机薄膜。

In the second section, with ketone and hydroxylamine hydrochloride as the starting materials, 3-aminopropanol is prepared via three steps including reaction of ketone and hydroxylamine hydrochloride , condensation of ketoxime and acrylonitrile, and hydrogenation cracking of condensation product.

第二是3-氨基丙醇的制备，由酮肟丙烯睛缩合物催化氢化裂解制得：即先以酮、盐酸羟胺为起始原料在碱性条件下合成酮肟，再与丙烯腈反应生成酮肟丙烯腈缩合物后经催化氢化裂解制得3-氨基丙醇。

We screened a set of Lewis base organocatalysts derived from chiral pipecolinic acid and tert-butanesulfinamide for the reduction of-N-Cbz-1- phenylpropenamine, including newly designed ones and some of those previously developed in our lab. However, only moderate stereoselectivities, albeit high yields were obtained.

在本课题组前期研究的基础上，我们筛选并设计了一系列以手性哌啶酸和叔丁基亚磺酰胺为母体的有机小分子路易斯碱催化剂，它们能催化三氯氢硅对-N-苄氧羰基-1-苯基丙烯胺的不对称还原，获得很高的收率和中等的对映选择性，并且具有很好的底物普适性。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。