烯丙胺

The reaction process in methanol solvent can be deduced from the computational results with CPCM solvent model and the supermolecular handling, namely the reaction involves four steps in the methanol solvent. The nucleophilic addition of trimethylamine to acraldehyde generates an enolate. Nucleophilic attack of the enolate on the aldehyde forms the carbon-carbon bond, followed by the proton-transfer process and the further elimination generating the product and liberating the trimethylamine catalyst.

对于CH3OH对反应体系的影响，可以综合考虑CPCM溶剂模型及超分子模型下的研究结果，即CH3OH溶剂中反应按四步进行，催化剂三甲胺首先与丙烯醛发生亲核加成，生成的两性离子中间体与甲醛发生类似于Aldol的醛醇缩合，形成碳-碳键，之后发生分子内质子转移，最后经E1cb消除得到产物，并释放催化剂三甲胺。

Then Doripenem came into the market in the July ,2005. We studied the synthesis of Doripemen.Firstly, we synthesized the chemical 2 from the starting material------o-hydroxylphenylacylamine through Reformastky reaction, alkylation, Diekmann reaction, enolization, esterification and etc. Secondly, we synthesized the chemical 3 from L — hydroxylproline through the protection of carboxyl, amidogen and hydroxyl group, reduction by NaBr, SN_2 substitution and Mitsumobu reaction.

我们以水杨酰胺为起始原料，经Reformatsky反应、烷基化、Diekmann环合、烯醇化、酯化等反应合成双环母核2；再从L-羟基脯氨酸出发，经酯化保护羧基、保护氨基、保护羟基、硼氢化还原酯得醇、Sn2取代和Mitsumobu反应等合成巯基侧链3；最后由化合物3经脱保护、水解得硫醇，和化合物2在二异丙基乙基胺的作用下缩合，最后Pd／C催化脱保护，历经16步反应最终得到产物多尼培南。

Using allylamine monomer,amine-containing functional films were prepared by pulsed dielectric barrier discharge at a high pressure.

采用高气压脉冲DBD等离子体，以丙烯胺为聚合单体，氩气为辅助气体，合成胺基薄膜。

Using allylamine monomer, amine-containing functional films were prepared by pulsed dielectric barrier discharge at a high pressure.

采用高气压脉冲DBD放电等离子体，以丙烯胺为聚合单体，氢气为辅助气体，合成含胺基薄膜。

In this study, collagen connected titanium plates were evaluated in vitro. The titanium plates were treated by glow discharge with allylamine.

钛金属表面先以丙烯胺电浆处理，使附著上胺基(-NH2)，再分别以不同浓度的交链剂BS3及戊二醛连接固定第一型胶原蛋白。

Otherwise, an intermediary allylamine deposition was covalently linked to the oxide layer by glow discharge, the covalent binding of bioactive protein to the free terminal NH2 groups using glutaraldehyde as a coupling agent was followed.

并利用丙烯胺的电浆处理在钛金属表面键结上胺基(-NH2)的官能基，之后再以交链剂戊二醛来固定生物活性胶原蛋白於低温电浆处理后的钛金属表面。

A series of new style crude oil pour point depressants were synthesized by aminate of acrylic alkyl ester and maleic anhydried bipolymer.

通过丙烯酸高碳酯与马来酸酐二元共聚进行胺解反应得到一系列新型高凝原油降凝剂，并进行筛选，从中选出丙烯酰高碳胺与共聚物结合后的降凝剂降凝效果最好，凝点降幅大于10℃；进一步回归出加剂和未加剂原油的全粘温方程，方程呈对数关系。

Then bis chloroformate was reacted with aromatic amines under the appropriate solvent and appropriate catalyst, after removed the solvent to obtain one kind of new amine-terminated polyether.

以聚氧化丙烯为基础原料，与光气在合适的溶剂下经过传统的低温、高温两段法光气化反应合成氯甲酸二酯，然后再与芳香多胺在合适的溶剂和催化剂下反应，脱除溶剂后得到一种新型的端胺基聚醚。

As a foundation raw material, propylene oxide was reacted with phosgene use the process tradition method that mean low temperature and high temperature two phosgenation sections to synthesis bis chloroformate .

以聚氧化丙烯为基础原料，与光气在合适的溶剂下经过传统的低温、高温两段法光气化反应合成氯甲酸二酯，然后再与芳香多胺在合适的溶剂和催化剂下反应，脱除溶剂后得到一种新型的端胺基聚醚。

Enlarge effection of the mixture of. PB and Beta-cypermethrin accord with equation y =-0.0156x2 + O.I623x + 1.2098(r = 0.8862). Other several proportion of insecticide with PB is 5:1, Tetramethrin's enlarge effection is 2.51 times The Permethrin is 1.40 times, D-trans allethrin is 0.50 times, D-prallethein is 1.67 times ,80% DDV milk is 1.38 times.

PB对高效氯氰菊酯的增效作用符合方程y=-0.0156x~2+0.1623x+1.2098(r=0.8862)，以PB和其它几种杀虫剂的比例为5：1时，对敏感家蝇种群成虫的毒力增效倍数为胺菊酯2.51倍、氯菊酯1.40倍、右旋反式丙烯菊酯0.50倍、右旋丙炔菊酯1.67倍、80％DDV乳油1.38倍，各杀虫剂与PB混配均表现为相加作用。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新