烯丙胺

B3LYP/6-311++G** calculations were carried out to study the trimethylamine catalyzed Baylis-Hillman reaction between acraldehyde and formaldehyde.

采用密度泛函DFT-B3LYP方法在6-311++G**基组下计算研究了三甲胺催化的丙烯醛和甲醛的Baylis-Hillman反应的微观过程，获得了两种反应通道(分别对应于顺式-丙烯醛和反式-丙烯醛)的势能面。

The optimized structures and energies of the reactants, intermediates, transition states and products of two reaction channels (corresponding to syn-acraldehyde and anti-acraldehyde) in gas or in methanol solvent were obtained. The potential energy profiles reveal the processes of the trimethylamine-catalyzed Baylis-Hillman reaction between acraldehyde and formaldehyde in gas or in methanol solvent at the microscope level.

通过研究，获得了三种情况下两种反应通道(分别对应于顺式-和反式-丙烯醛)中涉及的反应物、产物、中间体、过渡态的优化结构及其能量，并由此得到了反应的势能面图，在电子微观层次上揭示了三甲胺催化的丙烯醛和甲醛的Baylis-Hillman反应的微观过程。

University of Munich experts in the oil potato chips and crisps were found in the glycerol amine dose of 0.3 micrograms per kilogram to 1.5 micrograms, the same volume of French fries and potato chips in the acrylamide is 300 micrograms to 600 micrograms, and Acrylamide in human liver can be transformed into part of glycerol amines.

慕尼黑大学专家在油炸薯条和薯片中发现的甘油胺剂量在每公斤0.3微克至1.5微克，同样量薯条和薯片中的丙烯胺为300微克至600微克，而丙烯胺在人体肝脏中又可以部分转化为甘油胺。

Firstly, 3-ethylthiobutanal was prepared from crotonaldehyde reacting with ethanehiol in triethylamine with high yield. Secondly, methyl acetoacetate was converted to 6-ethylthiohept-3-en-2-one by three steps via hydrolysis, condensation with 3-ethyltio-butanal and dehydration, then 6-ethylthiohept-3-en-2-one was cycloco ndensed with dimethyl malonate by Michael addition and Claisen condensation, followed by saponification and decarboxylation to give the intermediate of 5-(2-ethylthiopropyl)-cyclohexane-1,3-dione.

首先，以巴豆醛与乙硫醇为原料，在三乙胺的催化作用下高收率制得3-乙硫基丁醛；然后从乙酰乙酸甲酯出发，通过碱水解、与3-乙硫基丁醛缩合、脱水三步反应合成6-乙硫基-3-烯-2-庚酮，接着6-乙硫基-3-烯-2-庚酮与丙二酸二甲酯通过Michael加成和Claisen缩合成环，再通过皂化和脱羧反应生成中间体5-[2-丙基]-1，3-环己二酮；再与丙酸酐反应丙酰化，最后与0-3-氯-2-丙烯基羟胺肟化，得到目标化合物烯草酮。

Trifluoromethyl-3-heptadfluoroisopropyl-2-perfluoropentene-4-(N',N'-dimethylamino propyl) imino was prepared by the reaction of hexafluoropropene timer with N,N-dimethyl propanediamine in the molar ratio 1:1.0 at room temperature for 8h, and the structures of VIII were identified by IR and NMR spectra.

以六氟丙烯三聚体与N，N-二甲基丙二胺为原料合成叔胺2-三氟甲基-3-七氟异丙基-2-全氟戊烯-4-(N'，N'-二甲胺丙基)亚胺，利用红外光谱和核磁共振确定其结构，并通过对合成条件的考察得其最佳合成条件：乙醚为溶剂，碳酸钠为缚酸剂，摩尔投料比为1：1.0，在室温下反应8小时。

In this regard, our goal is to develop a glow-discharge method to functionalize titanium surfaces by the covalent immobilization of bioactive organic molecules.

钛金属圆片先以氩气电浆去除表面污染物，来产生可重复取得的清洁表面，接著用丙烯胺电浆处理，使丙烯胺聚合在钛金属表面，再以交链剂戊二醛将白蛋白与丙烯胺的胺基(-NH2)键结。

Two new active esters of acrylic acids monomers, N-p-acryloxybenzoyloxy succini-mide and N-p-methacryloxybenzoyloxy succinimide have been synthesized and polymerized.ABOSu and MBOSu were prepared by coupling of p-acryloxybenzoic acid or p-methacryloxybenzoie acid with N-hydroxy succinimide in the presence of dicyclohexylcarbodimide.

新的丙烯酸活性酯，N-(对甲基丙烯酰氧苯甲酰氧基)丁二酰亚胺及N-丁二酰亚胺单体分别由对甲基丙烯酰氧基苯甲酸、对丙烯酰氧基苯甲酸与N-羟基丁二酰亚胺在环已基羰二亚胺存在下经偶联反应合成。

A series of modified polyurethane elastomer materials with different amino siloxane content were synthesized,which were based on polyoxypropylene glycol,aminoethyl aminopropyl poly,toluene diisocyanate and the curing agent dimethylsulfide toluylenediamine.

以聚氧化丙烯二醇或聚氧化丙烯三醇、氨乙基氨丙基聚二甲基硅氧烷、甲苯二异氰酸酯为原料在无溶剂条件下制备预聚体，利用二甲基硫甲苯二胺为固化剂合成一系列氨基硅油改性聚氨酯弹性体材料，并对材料的力学性能、耐热性、表面水接触角等性能进行了测试。

This paper discuss the method and application of polyacrylamide modified by starch, cellulose, chitin respectively.

本文综述了用淀粉、纤维素、壳聚糖这三种天然高分子改性丙烯酰胺的研究和应用情况。

The control group were injected peritoneal physiological saline injection.Three study groups were injected acrylamide solution 5 mg.kg-1.d-1,30 mg.kg-1.d-1,and 60 mg.kg-1.d-1,respectively.On the 5th day,brains of each group were taken out quickly,fixed by Zamboni fixation solution,made into conventional freezing moviemaking,stained by immunohistochemistry staining,and then observed by light microscope.

对照组小鼠腹腔注射生理盐水；实验组小鼠分别代以5 mg·kg-1·d-1、30 mg·kg-1·d-1、60 mg·kg-1·d-1丙烯酰胺水溶液腹腔注射。5 d时分别处死各组小鼠，取出大脑，Zamboni固定液固定，常规冰冻制片，免疫组织化学染色，光镜观察。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。