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Furthermore, the important fragment which is composed of pentenyl cinnamic acid and D-Tyrosine, and the ester which is composed of L-N-methylated phenyl amino acid and diketopiprazine was synthesized with considerable yield The conjugation of the new DOPA analogue into the peptide in the total synthesis of Pepticinnamin E was investigatited

另外,本文作者还进一步合成了高收率的戊烯基肉桂酸衍生物与D-酪氨酸的缩合片段及L-N-甲基苯丙氨酸与哌嗪二酮的酯两个重要的结构组成部分;对新多巴衍生物片段嵌入肽链中的工作亦进行了有益的尝试。

A catalyst composition for the polymerization of propylene comprising one or more Ziegler-Natta procatalyst compositions comprising one or more transition metal compounds and one or more esters of aromatic dicarboxylic acid internal electron donors; one or more aluminum containing cocatalysts; a selectivity control agent comprising at least one silicon containing compound containing at least one C1-10 alkoxy group bonded to a silicon atom, and one or more activity limiting agent compounds comprising one or more aliphatic or cycloaliphatic carboxylic acids; alkyl-, cycloalkyl- or alkyl-ester derivatives thereof; or inertly substituted derivatives of the foregoing.

一种用于丙烯聚合的催化剂组合物,所述催化剂组合物包括:一种或多种齐格勒-纳塔主催化剂组合物,该主催化剂组合物包括一种或多种过渡金属化合物和一种或多种芳族二羧酸酯内部电子给体;一种或多种包含铝的助催化剂;选择性控制剂,该选择性控制剂包括至少一种包含硅的化合物,该化合物包括至少一种与硅原子连接的C 1-10 烷氧基;和一种或多种活性限制剂化合物,该活性限制剂包括一种或多种脂族或脂环族的单或聚羧酸类、其烷基-、环烷基-或烷基-衍生物、或上述惰性取代的衍生物。

A catalyst composition for the polymerization of propylene comprising one or more Ziegler-Natta procatalyst compositions comprising one or more transition metal compounds and one or more esters of aromatic dicarboxylic acid internal electron donors; one or more aluminum containing cocatalysts; and a mixture of two or more different selectivity control agents, said SCA mixture comprising from 1 to 99 percent of one or more esters of one or more aromatic monocarboxylic acids or substituted derivatives thereof, and from 99 to 1 percent of one or more alkoxysilane compounds.

一种用于丙烯聚合的催化剂组合物,包括:一种或多种齐格勒-纳塔主催化剂组合物,该齐格勒-纳塔主催化剂组合物包括一种或多种过渡金属化合物和一种或多种芳族二羧酸酯内部电子给体;一种或多种包含铝的辅催化剂;和两种或更多种不同的选择性控制剂的混合物,所述SCA混合物包括1到99%的一种或多种芳族单羧酸的一种或多种酯或其取代衍生物、和99到1%的一种或多种烷氧基硅烷化合物。

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