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The preparation of potassium malonyloxyborohydride in situ and its seletive hydroborating alkene are described.

介绍了丙二酰氧基硼氢化钾的制备及其原位与烯烃的选择性硼氢化。

The annulation of stilbene compounds were studied. Phenanthrene derivates-interme diates of tylophorine were synthesized by annulation from-2,3-bis(3,4-dimethoxyphen yl)acrylic acid and-2,3-bis(3,4-dimethoxyphenyl) acrylonitrile with phenyliodine diace tate as a friendly and high efficient catalyzer.The route was first reported, whose application foreground would be promising.The catalyzer will be used to study of synthesi- zing a series of new phenanthrenes.

本文还探索了简单类化合物关环反应,并研究出用廉价高效对环境友好的催化剂-二乙酸碘苯成功地将类化合物-3,4-二甲氧基-α-(3,4-二甲氧苯基)-肉桂酸和-2-(3,4-二甲氧苯基)-3-(3,4-二甲氧苯基)-丙烯关环形成相应的菲环衍生物-娃儿藤碱重要中间体,此方法在国内尚属首次,具有重要的应用价值,此外可用此催化剂研究一系列类化合物的关环反应。

Monomeric acrylamide is a water-soluble, vinyl monomer that is used primarily to produce polyacrylamides which widely used as binding agent, thickening agent or bibulous in different industry such as wastewater treatment, petroleum extract, paper making, mining, medicine.

丙烯酰胺(Acrylamide,ACR)是一种水溶性的、乙烯基单体,主要用于生产聚丙烯酰胺,后者可作为良好的凝结、增稠、吸水剂,广泛用于废水处理、采油、造纸、纺织、皮革、采矿、医药等行业。

A random copolymer of poly(vinyl acetate-co-isopropenyl acetate) with number-average molecular weight of 9600 and relatively narrow molecular weight distribution (MWD, M w/ M n=2.03)was prepared by free radical copolymerization of vinyl acetate with isopropenyl acetate using AIBN as initiator.

通过自由基共聚合方法,以AIBN为引发剂引发醋酸乙烯酯和醋酸异丙烯酯共聚,得到两者的无规共聚物聚。

The effects of spatial hindrance , solvent, free volume were investigated. The result showed that the structure of graft copolymers exhibit a marked influence on photoisomerization.

另外,邻位被丙烯酰氧基取代的偶氮聚合物还表现出光致变色性禁阻,这说明空间位阻起了一个非常重要的作用。

New compounds of the type of unsymmetrically substituted ureas are synthesized by a series of reactions of preparing organic isocyanates by Curtius rearrangement with aromatic amine.

以3 苯基 2 丙烯酸为原料,用Curtius重排的方法合成异氰酸酯,直接与芳香胺作用,合成了5 种N 取代苯基 N′苯丙烯基脲类化合物。

The chemical components of volatile oil from Foemiculum Vulgare Mill were determined by GC-MS.

用GC-MS方法测定了小茴香挥发油的全组分,其中对-丙烯基茴香醚的含量为82.65%。

Although many researchers have studied the synthesis of allyl phenyl ether by phase-transfer catalysis, no studies have used it in membrane reactor up to now. The purpose of this paper is to combine the studies of membrane reactor and phase-transfer catalysis. The membrane was used to stabilize the aqueous/organic interface at a fixed position, also the quaternary ammonium ion in the membrane was used as the catalyst to partake in the reaction system directly, and so it can also separate the product and reactants at the same time. A theoretical model is also presented.

中文摘要对於利用相间转移触媒催化技术来合成丙烯基苯基醚的反应,已有不少专家学者研究过,而至今还无在薄膜反应器中进行此反应之研究,本研究则是要结合薄膜反应器与相间转移触媒两者之特性,固定水油两相之界面,并且利用薄膜上的四级铵离子为触媒,直接在反应系统中参与反应,并同时分离产物及反应物,进而推导出相关之理论模型。

The fluorescence of the polymer, P could be quenched by electron-deficient quenchers such as methacrylonitrile, acrylonitrile, fumaronitrile; methyl acrylate and methyl methacrylate.

本文合成了新的功能性单体N一甲基丙烯酞一N,一呛吮基呱嗦,并观察了单体及其聚合物溶液的荧光光谱。

It is important to use the best available water blended with not more than 60 percent ethylene glycol base antifreeze or 50 percent propylene glycol base antifreeze.

最重要的是要利用现有的水混合不超过60%或50%乙烯丙烯乙二醇防冻剂乙二醇基制药基地。

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