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Covalent modification of four isolated alkannin derivatives (alkannin, acetylalkannin,β,β dimethylacrylalkannin and β acetoxyisovalerylalkannin, respectively) on rabbit muscle latate dehydrogenase and yeast Alcohol Dehydrogenase has been studied.

为研究紫草萘醌类化合物的细胞毒性作用机制,从新疆软紫草根中分离出四种紫草萘醌类化合物β,β二甲基丙烯酰阿卡宁(1),乙酰阿卡宁(2 ),β乙酰氧基异戊酰阿卡宁(3)和阿卡宁(4)。

Compared with TEA,TiBA activated system produced more blocky copolymer,but the blockiness of its block fraction is lower.

与三乙基铝相比,三异丁基铝为助催化剂得到的不溶级份含量及丙烯含量都较高,但其嵌段性却较低。

New composite sorbents for separating estrone were synthesized with the monomers of acrylamide and p-vinylbenzoic acid using estrone as the template.

以雌酚酮为模板剂,以丙烯酰胺和对乙烯基苯甲酸为单体合成出用于分离雌酚酮的新型复合吸附剂。

A commercial and practical synthesis rout with-2-(3-acetoxy-l-me-thyl-l~propenyl)-5,5-dimethyl-l,3-dioxane as starting material by couple,oxidation, Ramberg-Backlund and deprotection is chosen and studied in this paper.

本文选择了以2-(3-氯-1-甲基-1-丙烯)-5,5-二甲基-1,3-二噁烷为原料,经偶连、氧化、Ramberg-Bcklund反应及脱保护基四步反应的合成路线,对该中间体进行合成研究。

Based on the experimental results,di-butyl-peroxide,di-cyclopentadiene and propyl nitrate are found to be sensitive to the change of heating temperature and heating time,and their thermal decomposed products can be detected easily.

实验表明,在343~473 K温度范围内,过氧化二叔丁基、双环戊二烯和硝酸丙酯对受热温度和受热时间的变化较为敏感,热分解现象明显,热分解产物易于检测。

Three methods are used to prepare molecular imprinted polymers,which include conventional bulk technique or polymerization with ultraviolet initiated in low temperature and polymerization with silica-gel as sacrificial materials. In the polymerization procedure , Sulfamethazine(SM2)and Sulfisoxazole were used as target template molecules, methacrylic acid and 4-vinylpyridine(4-VP) and acrylamide were selected as functional monomers, ethylene glycol dimethacrylate as crosslinker, azobisisobutyronitrile was used as initator.

主要工作如下:首先,以磺胺异噁唑和磺胺二甲嘧啶为模板,分别以4-乙烯基吡啶,甲基丙烯酸,丙烯酰胺为功能单体,以二甲基丙烯酸乙二醇酯为交联剂,偶氮二异丁腈为引发剂,采用了传统方法(60℃恒温水浴)、牺牲硅胶法及低温紫外光聚合法等三种方法合成了一系列的磺胺类药物印迹聚合物。

In this study, collagen connected titanium plates were evaluated in vitro. The titanium plates were treated by glow discharge with allylamine.

钛金属表面先以丙烯胺电浆处理,使附著上胺基(-NH2),再分别以不同浓度的交链剂BS3及戊二醛连接固定第一型胶原蛋白。

Otherwise, an intermediary allylamine deposition was covalently linked to the oxide layer by glow discharge, the covalent binding of bioactive protein to the free terminal NH2 groups using glutaraldehyde as a coupling agent was followed.

并利用丙烯胺的电浆处理在钛金属表面键结上胺基(-NH2)的官能基,之后再以交链剂戊二醛来固定生物活性胶原蛋白於低温电浆处理后的钛金属表面。

We screened a set of Lewis base organocatalysts derived from chiral pipecolinic acid and tert-butanesulfinamide for the reduction of-N-Cbz-1- phenylpropenamine, including newly designed ones and some of those previously developed in our lab. However, only moderate stereoselectivities, albeit high yields were obtained.

在本课题组前期研究的基础上,我们筛选并设计了一系列以手性哌啶酸和叔丁基亚磺酰胺为母体的有机小分子路易斯碱催化剂,它们能催化三氯氢硅对-N-苄氧羰基-1-苯基丙烯胺的不对称还原,获得很高的收率和中等的对映选择性,并且具有很好的底物普适性。

A novel polymerizable amphiphilic compound with self-assembly ability, 4-2-(acryloyloxy ethoxy benzyl tri-ethyl ammonium bromide, was designed and synthesized. It exhibits good water solubility, strong self-association ability and response to extra-stimulation.

设计并合成了一种新型具有自组装功能的可聚合两亲化合物4-2-(丙烯酰氧基乙氧基苯亚甲基三乙基溴化铵,它易溶于水,具有很强的自缔合能力和对外界刺激的响应性。

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