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Anethole accounted for 82.65% of the whole oil. Selective isolation of anethole form the volatile oil was carried out using an inclusion crystalline method with 1,1,6,6- tetraphenylhexa- 2,4-diyne-1,6-diol inclusion complex with anethole . The crystal structure of the inclusion complex was determined by IR, 1^H NMR and single crystal XRD techniques.

采用包结结晶方法对小茴香挥发油中的对-丙烯基茴醚进行了选择性分离,以1,1,6,6-四苯基-2,4-已二炔-1,6-二醇作为主体分子,小茴香挥发油中的对-丙烯基茴香醚作为客体分子,D.D选择性地与之形成超分子包结物晶体。

The main products are: HH-01 fungicides HH-02 organic dispersant HH-03 cationic starch Wood HH-04 cationic starch Department HH-05 modified starch warp sizing agents also sell German Baker Chemical Co., Ltd. Main Products Defoamer series product: E640, T50 Surface Sizing Agent: A281, A288, K532, pesticides / medicine / veterinary medicine a variety of intermediate products (p-Bromo-p-Bromotoluene bromoform 1 - bromo-heptane triethyl citrate 1,2, 3 - Three Bromopropane 3 - chloro -4 - fluoro bromobenzene Bromotoluene ethylbenzene 4 - bromo -2 - bromo-ethyl-Chloroaniline 2 - bromo--5 - chloro-toluene 3 - bromo-methyl 1,6 C - Dibromo Hexane 1 - bromo -4 - nitrobenzene o-methoxy benzaldehyde acid propyl bromide p-fluorotoluene bromo dodecane toluene four of iodine bromide bromoethane three citric acid tert-butane n-butyl 2 - bromo-p-bromo-butane Hydroxybenzaldehyde between 2 - bromo-propionic acid bromide veratryl aldehyde inter-bromo-trifluoro-n-hexane of toluene on Bromoxynil Bromotoluene toluene ethylbenzene o-bromophenol bromide bromide Cyclohexane Cyclopentane bran acid dibutyl maleate Ethyl Lactate Propylene between bromine bromine bromine between aniline o-anisidine o-fluorophenol difluorobenzonitrile to aminobenzaldehyde Bromotoluene aniline on Bromobenzaldehyde Bromotoluene acid) and other relevant units have been in substantial promotion, and client set up a good relationship of cooperation has been the user's praise.

现主要产品:HH—01杀菌剂 HH—02有机分散剂HH—03阳离子淀粉 HH—04木署阳离子淀粉 HH—05 经纱上浆变性淀粉同时还代理销售德国贝克化学公司系列产品主要产品消泡剂:E640 、T50 表面施胶剂:A281、A288 、K532,农药/医药/兽药中间体多种产品(对溴苯酚对溴甲苯溴仿 1-溴庚烷柠檬酸三乙酯 1,2,3-三溴丙烷 3-氯-4-氟溴苯对溴乙苯 4-溴-2-氯苯胺溴乙酸乙酯 2-溴-5-氯甲苯 3-溴丙酸甲酯 1,6-二溴己烷 1-溴-4-硝基苯邻甲氧基苯甲醛溴乙酸丙酯对氟甲苯溴代十二烷对碘甲苯四溴乙烷溴代叔丁烷柠檬酸三丁酯 2-溴氯苯间羟基苯甲醛溴丁烷 2-溴丙酸黎芦醛溴已烷间溴三氟甲苯对溴苯腈对溴乙苯邻溴甲苯溴代环已烷溴代环戊烷糠溴酸马来酸二丁酯溴丙烯乳酸乙酯间溴苯胺间溴苯甲醚邻氟苯酚邻氟苯腈对氨基苯甲醛对溴苯胺对溴苯甲醛对溴苯甲酸)等在相关单位得到了大量推广,与客户建立了良好的合作关系,得到了用户的赞誉。

The hydrophobically associating interactions of the copolymer PASA with acrylamide, styrene derivative and sodium-2-acrylarnido-2-methylpropane sulphonate in aqueous solution were studied by flourescent probe.

通过荧光探针研究了丙烯酰胺-苯乙烯衍生物-2-甲基-2-丙烯酰胺基丙磺酸钠共聚物在溶液中的疏水缔合作用。

Pyrene has been used as a fluorescence probe to investigate the associative behaviors of hydrophobically modified water-soluble terpolymers Poly(acrylamide/sodium acrylate/octylacrylamide) \[P(AM/NaAA/C_8AM)\].

采用胶束共聚共水解方法合成疏水改性水溶性聚合物聚(丙烯酰胺/丙烯酸钠/N 辛基丙烯酰胺)[P(AM/NaAA/C8AM)],并以芘为荧光探针,应用稳态荧光光谱法研究了它的疏水缔合行为。

It showed that the blend system had much slower Rp than that of hybrid monomer, either of acrylate double bond or propenyl ether double bond, and propenyl ether double bond conversion of hybrid monomer was much higher than that of the blend system at the end.

杂化单体与相同类型的混合体系相比,每种基团的反应动力学性质都得到了促进,丙烯酸酯和丙烯基醚双键的聚合速率都有了很大提高,丙烯基醚双键的转化率较混合体系有很大增加。

The title anti-fogging coating was prepared from film-forming substance such as UV curing of n-butyl methacrylate,β-hydroxy ethyl acrylate,acrylamide and sodium propenyl alkyl ether hydroxyl sulfonate,and proper solvents, crosslinker s,photoinitiators and additives.

以光敏丙烯酸酯低聚物、甲基丙烯酸丁酯、丙烯酸-β-羟乙酯、丙烯酰胺及丙烯基烷醚羟磺酸钠为主要成膜物质,再配以适量的溶剂、交联剂、光敏剂及各种助剂制成UV固化防雾涂料。

The copolymers with high molecular weight synthesized from 2-acrylamio-2-methyl propane sulfonic acid and acrylic acid or acrylamide or other water soluble monomers can be used to purification of wastewater and as the dehydrant of organic slurry.

2-丙烯酰胺基-2-甲基丙磺酸和丙烯酸或丙烯酰胺等水溶性单体的高分子量共聚物,可用于废水的净化,还可作为有机污泥的脱水剂。

In searching for novel and high active fungicides with pyridyl moiety, with Dimethomorph as a model compound and isonicotinic acid as the main starting material, twenty-seven title compounds were designed and synthesized through chlorination, Friedel-Crafts acylation, Wittig-Horner reaction and other steps. All the target structures were confirmed via 1H NMR and elementary analysis.

为了寻找具有高活性的含吡啶杂环杀菌剂,以烯酸吗啉为模板化合物,以异烟酸为起始原料,通过卤代反应、Friedel-Crafts酰基化反应、Wittig-Homer反应等,将吡啶-4-基或2-氯吡啶-4-基引入到模板结构中,设计合成了27个4-[3-(吡啶-4-基)-3-取代苯基丙烯酰]吗啉类化合物,其结构通过1H NMR和元素分析确证。

A series of 3 - aryl - 3 -( 5,5 - dimethyl - 3 - hydroxy - 2 - cyclohexene - 1 - one - 2 - yl) propanoic ester s were synthesized by reaction between aromatic aldehydes ,5,5- dimethyl -1,3-cyclohexanedione and isopropylidene malonate catalyzed by KF - Al2O3 in alcohols.

在KF-Al_2O_3催化下,将芳香醛3,5-二甲基-1,3-环己二酮及丙二酸亚异丙酯在醇中反应,一锅式合成了一系列的3-芳基-3-(5,5-二甲基-3-羟基-2-环己烯-1-酮-2-基)丙酸酯。

The results of its fluorescence probe showed that when the guanidine hydrochloride concentration in denaturation solution was about 1.0 mol/L,there existed some stable hydrophobic regions,which could interact with a hydrophobic reagent 8-anilino-1-naphthalene sulfonic acid,in the partially folded intermediate of Bacillus amyloliquefaciensα-amylase;with the denaturation concentration increasing,the stable hydrophobic regions disappered.the results of fluorescence quenching using acrylamide and potassium iodide as quenchers showed that using acrylamide as quenchers,with the protein denaturation extent increasing,the number of Trp that can be quenched increased untill all the Trp residues were quenched;Using potassium iodide as quenchers,with the maximum number(8) of tryptophan residues in a partially folded intermediate Bacillus amyloliquefaciensα-amylase molecule could be quenched by potassium iodide;with the denaturation concentration increasing,the number of Trp that can be quenched decreased to 5.the results of their protein electrophoreses and SEC showed that no aggregate or aggregate precipitation of Bacillus amyloliquefaciensα-amylase formed during the whole unfolding/refolding procedure of Bacillus amyloliquefaciensα-amylase induced by guanidine hydrochloride or urea.

ANS外源荧光探针结果表明:盐酸胍诱导的芽孢杆菌α-淀粉酶分子去折叠过程中存在着能够与探针分子1-苯胺基-8-萘磺酸结合的稳定的疏水区域;而随着芽孢杆菌α-淀粉酶分子在盐酸胍溶液中变性程度的加深,这一疏水区域逐步被瓦解。丙烯酰胺和碘化钾猝灭结果表明:在盐酸胍溶液中,随着芽孢杆菌α-淀粉酶分子变性程度的进一步加深,其分子内能够被丙烯酰胺接近的色氨酸残基逐渐增多,直至全部被猝灭。但位于芽孢杆菌α-淀粉酶分子表面的能够被碘化钾猝灭的色氨酸残基,在中间态芽孢杆菌α-淀粉酶分子中数目达到最大的8个,而随着其分子变性程度的进一步加深,反而减少至5个。

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