烯丙基的

Two classes of specific binding sites in the polymer matrix were investigated by Scatchard analysis, which indicated that two kinds of complexes between functional monomers and templates were formed before the polymerization process. Comparing with the structure of TNT and acrylamide, one kind of complex between TNT and acrylamide was strongly charge-transfer complexing interaction by p-πcomplex between electron-rich amino group of acrylamide and electron-deficiecy-benzene ring of TNT, the other was hydrogen bonding interaction between amino group (-NH_2) of acrylamide molecule nitro group (-NO_2) of TNT.

Scatchard分析结果表明，在TNT印记聚合物微球中存在两类结合位点，这表明在聚合反应之前，TNT与功能单体丙烯酰胺分子之间存在两种不同类型的作用力而自组装成两类的模板分子-功能单体复合物，一类可能是由于富电子的丙烯酰胺和缺电子的TNT的苯环通过p-π配键而形成的电荷转移复合物，另一类可能是由于丙烯酰胺的胺基与TNT的硝基之间的氢键作用而形成的复合物。

To develop an eco-friendly epoxy impregnating resin system for groundwall insulation of large generators, the curing reaction mechanism has been fully studied, the formulation and the curing techniques have been optimized, and the influence of different constitution on the curing reaction, microstructure, and final performances have been studied and characterized.In this paper, influences of different reactive organo-siloxanes on the curing reaction and performances of epoxy V.P.I.

本文研究比较了含有环氧基、氨基或乙烯基的反应性硅氧烷，包括：γ-缩水甘油醚氧丙基甲基二乙氧基硅烷、β-(3，4环氧环已基)乙基三乙氧基硅烷、γ-缩水甘油醚氧丙基三甲氧基硅、β-(3，4环氧环已基)乙基三甲氧基硅烷、γ-甲基丙烯酰氧基丙基三甲氧基硅烷、乙烯基三乙氧基硅烷和苯胺甲基三乙氧基硅烷对环氧V.P.I。

A process for the carbonylation of allylic butenyl ether (for example, methyl crotyl ether, 3-methoxybutene-1 and mixtures thereof) or mixture of butadiene and alcohol and production of beta-gamma unsaturated carboxylic acid esters (for example, methyl-3-pentenoate) utilizing a rhodium-containing catalyst for example, dicarbonylacetylacetonate rhodium(I or the like promoted with an iodide-containing compound (for example, HI, AlI3, SnI4, TiI4, CrI3, and CoI2 or the like).

一种将烯丙型丁烯基醚(如甲基巴豆基醚、3－甲氧基丁烯－1及其混合物)或者丁二烯与醇的混合物羰基化的方法，以及由含碘化物化合物(如HI、AlI3、SnI4、TiI4、CrI3和CoI2或等效物)促进，用含铑催化剂如二羰基乙酰丙酮酸铑(I或其等效物制备β－γ不饱和羧酸酯(如甲基－3－戊烯酸酯)的方法。

In this paper,firstly a series of acryloxyl derivatives were synthesized from the dehydrogenated abietic acid,a main composition of disproportionated rosin, through acyl chloridation and esterification.The derivatives included the (β-acryloxyl ethyl) esters of dehydrogenated abietie acid,(β-methacryloxyl ethyl) esters of dehydrogenated abietic acid and (β-methacryloxyl propyl)esters of dehydrogenated abietic acid.

论文首先以歧化松香中的主要成分脱氢枞酸为模型化合物，采用酰氯化、酯化手段合成了它的一系列丙烯酰氧基衍生物，包括脱氢枞酸酯、脱氢枞酸(β-甲基丙烯酰氧基乙基)酯和脱氢枞酸(β-甲基丙烯酰氧基丙基)酯。

Firstly, 3-ethylthiobutanal was prepared from crotonaldehyde reacting with ethanehiol in triethylamine with high yield. Secondly, methyl acetoacetate was converted to 6-ethylthiohept-3-en-2-one by three steps via hydrolysis, condensation with 3-ethyltio-butanal and dehydration, then 6-ethylthiohept-3-en-2-one was cycloco ndensed with dimethyl malonate by Michael addition and Claisen condensation, followed by saponification and decarboxylation to give the intermediate of 5-(2-ethylthiopropyl)-cyclohexane-1,3-dione.

首先，以巴豆醛与乙硫醇为原料，在三乙胺的催化作用下高收率制得3-乙硫基丁醛；然后从乙酰乙酸甲酯出发，通过碱水解、与3-乙硫基丁醛缩合、脱水三步反应合成6-乙硫基-3-烯-2-庚酮，接着6-乙硫基-3-烯-2-庚酮与丙二酸二甲酯通过Michael加成和Claisen缩合成环，再通过皂化和脱羧反应生成中间体5-[2-丙基]-1，3-环己二酮；再与丙酸酐反应丙酰化，最后与0-3-氯-2-丙烯基羟胺肟化，得到目标化合物烯草酮。

Trifluoromethyl-3-heptadfluoroisopropyl-2-perfluoropentene-4-(N',N'-dimethylamino propyl) imino was prepared by the reaction of hexafluoropropene timer with N,N-dimethyl propanediamine in the molar ratio 1:1.0 at room temperature for 8h, and the structures of VIII were identified by IR and NMR spectra.

以六氟丙烯三聚体与N，N-二甲基丙二胺为原料合成叔胺2-三氟甲基-3-七氟异丙基-2-全氟戊烯-4-(N'，N'-二甲胺丙基)亚胺，利用红外光谱和核磁共振确定其结构，并通过对合成条件的考察得其最佳合成条件：乙醚为溶剂，碳酸钠为缚酸剂，摩尔投料比为1：1.0，在室温下反应8小时。

As a useful fluorinated product,hexafluoropropene trimers can be prepared from hexafluoropropene oligomerization by gas phase-and liquid phase-methods,and many fluorocarbon surfactants such as full-fluoride nonene oxygen benzene sodium can be derived from perfluorinated nonene.

六氟丙烯可通过气相和液相法进行聚合制得六氟丙烯三聚物，即全氟壬烯，全氟壬烯可以进一步衍生出如全氟壬烯氧基苯磺酸钠等多种氟碳表面活性剂，是一种比较有用的含氟产品。

The copolymer of N isopropylacrylamide and acrylamido azobenzene was synthesized for the study of the effect of the photoisomerization of a water soluble copolymer containing azobenzene groups on the photocontrolled release behavior of liposomes.

为了研究侧链含有偶氮苯基的水溶性共聚物的光异构化对脂质体内包容物的光控释放的影响，设计合成了N－异丙基丙烯酰胺和丙烯酰胺基偶氮苯的共聚物。

A novel polymeric organic thermal stabilizer for PVC was designed and synthesized by acryloylthiourea grafting on polystyrene which was nitrified by HNO3 and then reducted by Sn powder to amine.

以经部分硝化和还原的低分子量聚苯乙烯为母链，利用其胺基和丙烯酰基异硫氰酸酯加成，合成了一种新型有机高分子型PVC 热稳定剂——丙烯酰基硫脲接枝聚苯乙烯，其结构经IR和元素分析表征。

In the course of our study the chemistry of arenes contaning allylic acetates moiety under the catalysis of palladium, we found an efficient synthesis of benzocycles via intramolecular Friedel-Crafts reaction of halogen free 6-acetoxy-4alkenyl arens.

我们在设计钯催化的碳—氢键活化时，发现了含有烯丙基醋酸酯侧链的芳烃的三氟醋酸促进的分子内的Friedel-Crafts反应，从而为有效合成苯并六元环结构提供了一个方便的方法。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。