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Liquid-phase epoxidation of allyl chloride with hydrogen peroxide was carried out over Ti-MWW, a novel titanosilicate with the MWW structure, to synthesize epichiorohydrin selectively and effectively. Ti-MWW proved to be superior to the conventional TS-1 catalyst in both catalytic activity and product selectivity. Ti-MWW prefers aprotic solvents of acetone and acetonitrile, both of which can restrain the solvolysis of epichiorohydrin, whereas TS-1 favors a protic solvent of methanol.

研究了具有MWW结构的新一代钛硅分子筛Ti-MWW催化剂对烯丙基氯液相环氧化高效合成环氧氯丙烷的催化性能结果表明,Ti-MWW的催化活性以及产物选择性均优于传统的钛硅分子筛TS-1,对于Ti-MWW,合适的溶剂为非质子性溶剂丙酮和乙腈,在该溶剂中环氧化物不易发生溶剂化开环反应;而对于TS-1,合适的溶剂是质子性溶剂甲醇,但甲醇可导致醇醚副产物的生成。

Consideration of display resin requirements led us to select for study the diallyl phthalate polymer thermosetting system, which had most of the performance properties desired, but was excessively brittle.

Consideration的要求使我们选择的研究烯丙基酯聚合物热系统,它最的性能理想,但过于脆弱。

Objective: To investigate the arrest effect of diallyl disulfide in the cell cycle of human nasopharyngeal carcinoma CNE2 cell line and its molecular mechanism.

目的:在前期工作的检测上,进一步探讨二烯丙基二硫(diallyl disulfide, DADS)对人鼻咽癌CNE2细胞周期的阻滞作用,并研究组蛋白乙酰化状态及其调控p21WAF1蛋白表达改变的情况。

We ever reported cellulose is in propyl of Xi of ionic liquid 1-- chloric salt of Zun of 3- methylic Mi (the homogeneous phase acetyl in Am ImC L) converts reaction, falling without activator condition, one pace gets the CA of different DS, get acetone but the CDA[12] of dissolve.

我们曾报道了纤维素在离子液体1-烯丙基-3-甲基咪唑氯盐中的均相乙酰化反应,在无催化剂条件下,一步得到不同DS的CA,并得到丙酮可溶的CDA[12]。

In this dissertation, polyethylene glycol monomethyl ether of 2000 molecular weight as soluble support, an array of soluble polymer-supported tartrate esters were designed, synthesized, and applied in asymmetric epoxidation of allylic alcohols.

本论文以平均分子量为2000的聚乙二醇单甲醚为可溶性支载体设计和合成了一系列可溶性聚合物支载的酒石酸酯配体,并将它们用于烯丙基醇的不对称环氧化反应。

Sodium allyl hydroxyalkyl sulphonate was used as reactive surfactant to modify the polymerization ofelastic acrylic emulsion. Influence of SAHS on minimum content of surfactants and particle size of emulsion was studied andmechanism of change of particle size discussed.

使用烯丙基羟烷基磺酸钠作为可聚合乳化剂,改性合成了弹性丙烯酸酯乳液,研究了它对乳化剂的最低用量和乳胶粒粒径的影响,探讨了乳胶粒粒径变化的机理。

It is shown that the optimal conditions for the reaction of CADB with SESA are pH 12.0 and m:m=6:1.The product p-aminobenzart sulfanily ethyl CADBwas diazotized and linked with lipase.The optimal pH for lipase linked to diao-compound is 7.5.The link time is at last 12h.

试验结果表明:CADB与SESA反应的最适条件是pH=12.0,SESA与CADB质量比为6:1,反应生成的对氨基苯磺酰乙基交联烯丙基葡聚糖凝胶经重氮化后与脂肪酶偶联的最适条件是pH7.5,偶联时间≥12h。

Organic our country high polymer flocculant already has commercialized at present having several breeds such as PAM , polypropylene acidamides and carboxyl methyl cellulose only , studies innocuous high-effect organic synthesis high polymer flocculant (the ammonium equality gathers the sum copolymer kind if alkyl alkene propyl group halogenates waiting), optimizes it's the cost reduction composing handicraft.

目前我国有机高分子絮凝剂已商品化的仅有PAM、聚丙烯酰胺和羧甲基纤维素等几个品种,研究高效无毒的有机合成高分子絮凝剂(如烷基烯丙基卤化铵的均聚和共聚物类等),优化其合成工艺降低成本。

The ultrathin multilayer film of poly (diallyldimethylammonium chloride) and polyvinylidene fluoride has been prepared by the layer-by-layer static self-assembly method. The PVDF/PDDA multilayer film with the thickness ranging from about 30nm to 150 nm the thickness of each layer is about 9nm.

聚二烯丙基二甲基氯化铵和极化处理后的聚偏氟乙烯复合超薄膜是通过层与层的静电自组装方法制备的,厚度约30~150 nm,每层膜厚度约为9 nm。

As the concentration of substrate increased, the e.e.

随着底物浓度的增加,经烯丙基醇预处理的酵母细胞,其S型产物的e.e。

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推荐网络例句

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候,里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色,卵在发育96h后卵基本全部孵化。

There was a conflict between plebs and patricians in ancient Rome in 494BC.

在公元前494年,罗马发生了一次平民反对贵族的斗争。