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The described tackifier is applicable to perchloride raw rubber based on fragment form and non-halide or low-halide raw rubber, and can make most of allyl group implement bromation reaction in priority.

所述增粘剂基于碎片形式的高氯化生橡胶和非卤化或低卤化的生橡胶,并优选使大部分的烯丙基进行溴化反应。

While the basicity of the N-atom is stronger, more active second generation catalyst is indispensable and the temperature needs to be reached 150℃, and mixture of pyrrolidine and pyrrole was gained.

研究结果表明微波辐射条件下氮原子的碱性强弱对于二烯丙基胺发生关环复分解反应具有很大的影响:当底物的碱性比较强时,必须使用活性更高的第二代Grubbs催化剂,且温度需升至150℃反应才能顺利发生,得到光学纯吡咯啉和吡咯的混合物。

Last, we studied the allylation of benzoylhydrazones with allyltrichlorosilane.

在研究过程中,发现了一个C=N双键烯丙基化的新方法,和苯甲酰肼的新的合成方法。

This article summarizes the latest research progress of the allylation reaction mediated by metals in aqueous media, and the new reaction mechanism is explained briefly.

本文综述了水相中金属参与烯丙基化反应的最新研究进展,并对新的反应机理作了简要的阐述。关键词:谢斌,冯建申邹立科,张秀兰

It was found that the binaphthyl backbone of S configuration was matched to the S, S pyrrolidino group. In this case, the asymmetric allylation product could be obtained in 85. 6% ee.

轴手性是S构型时,和中心手性S,S构型相匹配,它和钯形成的络合物在催化烯丙基取代反应时,取得了比不含中心手性因素的吡咯烷基氮膦配体高得多的对映选择性,可以得到85.6%ee值的产物。

The quality and inhibition efficiency of thiourea, allylthiourea and phenylthiourea self-assembled films were studied by electrochemical impedance spectroscopy and polarization curves, respectively.

利用电化学阻抗谱和极化曲线研究了硫脲、烯丙基硫脲、苯基硫脲在金属铜表面上的自组装膜的质量和缓蚀效率,并通过量子化学计算进一步研究了各种分子和金属铜的相互作用。

The asymmetric hydrogenation of prochiral ketones is one of the most efficient methods of producing enantiomerically enriched secondary alcohols. The ruthenium complex RuCl_2[P(C_6H_5)_3]_2--DPEN(DPEN=1, 2-diphenylethylene-diamine) was applied to the asymmetric hydrogenation of benzalacetone.

具有光学活性的烯丙基醇是合成许多生理活性药物的重要中间体,前手性酮不对称加氢反应是制备具有光学活性仲醇的一种重要方法。

We also studied the enantioselective conjugate addition of chalcone in the presents of chiral Ni2 aminoalcohol complexes.

我们还研究了手性氨基醇配体/镍盐催化的a,β-不饱和酮的不对称迈克尔加成反应,以及酰腙的不对称烯丙基化反应。

Too high allyl contents are unfavorable in that a high BMI proportion will be required to copolymerize with the allylated Novolak resin.

为了协调好工艺性、耐热性与T〓三者之间的矛盾,获得综合性能优良的改性酚醛树脂体系,应通过控制投料比将Novolak树脂的烯丙基化程度控制在25%左右。

Butadiene was polymerized to some extent in the presence of binary catalyst system NdCl33iPrOHAlEt3 in toluene and the allylchloride was then added to the solution in order to cyclize the formed polybutadiene and cyclopolymerize the unreacted butadiene monomers.

采用NdCl3·3i-PrOH-AlEt3稀土催化剂进行丁二烯的顺式聚合,在聚合过程中引入烯丙基氯,进行分子内环化反应以及单体的环聚反应。考察了稀土催化剂用量、n/n(AlEt3)、环化时间、反应温度、单体浓度等对环化反应的影响,并对产物进行了红外光谱、核磁共振光谱的表

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