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We studied effects of additives in the allylic amination reaction. We found that4NF could improve the reactivity and enantioselectivity.

对于烯丙基胺化反应,我们研究了外加添加剂对对映选择性的影响,我们发现四丁基氟化铵的加入可以大大提高反应速度及对映选择性。

When the proportion of the aryl halides was changed,the aromatic products with different number substitutes could be obtained.

通过研究我们发现,活泼酰基与烯丙基在偶联反应中活性相当,可得到不同成环方式的产物,且当改变卤代物比例时,将得到不同数量取代芳烃的产物。

A new chiral quaternary ammonium salt 1a was synthesized by the reaction of cinchonine and(2,4,6-)trimethyl benzyl chloride.Etherification between 1a and benzyl bromide,allyl chloride,or methyl give corresponding etherified quaternary ammonium salts 1b,1c,and 1d.

由辛可宁和2,4,6-三甲基苄氯,合成了一种新的手性季铵盐(1a),并进一步用苄基溴、碘甲烷和烯丙基氯对分子中的羟基进行醚化,得到相转移催化剂1b、1c和1d。

The effect of crosslinking agent dicumyl peroxide and co- crosslinking agent triallyl isocyanurate on the cure and tensile properties of liquid ethylene propylene diene monomer was investigated.

研究了由过氧化二异丙苯和助交联剂三烯丙基异氰脲酸酯组成的过氧化物体系对液体三元乙丙橡胶的交联及产物拉伸性能的影响。

The mechanism was supposed as follows: polyfluoroalkyl iodides were initiated by sodium dithionite to give R〓 which was added to one double bond of diallylacetic acid, after the sequential radical cyclization and nucleophilic substitution to form bicyclo-lactones.

这是因为:多氟烷基碘化物在连二亚硫酸钠的引发下,得到自由基R〓,后者加成到二烯丙基乙酸中的一个—C=C—双键上,然后在碱性介质中进行分子内亲核反应得到双环内酯类产物。

In order to prepare bismaleimide/montmorillonite nanocomposites with high performance, Na-montmorillonite was modified with allyl-tri-phenyl phosphonium bromide via ion-exchange method.

通过离子交换法将烯丙基三苯基溴化交换到钠基蒙脱土的层间制备改性蒙脱土。

The electron transfer mediated asymmetric radical allylation reactions were investigated in details.

中文摘要本论文对电子转移引发的不对称自由基烯丙基化反应进行了研究。

2-Substituted-3,4-dihydro-1(2H)-isoquinolinones were synthesized from methyl 3-hydroxy-ben- zoates via allyl etherification, Claisen rearrangement, oxidation, reductive amination and aminolysis for the first time.

以3-羟基-4-甲氧基苯甲酸甲酯等为原料,通过烯丙基醚化、Claisen重排、氧化、与伯胺反应、还原、分子内酯的胺解六步反应合成了一系列2-取代-3,4-二氢-1-异喹啉酮类化合物。

Ee were achieved in the Pd (0)-catalyzed asymmetric reaction of racemic 1, 3-dipheylprop-2-en-1-yl acetate with dimethyl malonate under the optimized reaction conditions.

在钯催化的乙酸1,3-二苯基烯丙基酯与丙二酸二甲酯的不对称反应中,取得了接近定量的收率和较好的对映选择性(71.2%ee)。

Comb-shaped polycarboxylic -type superplasticizers were synthesized with acrylic acid,mathacrylic acid,sodium allylsulphonateand methoxypolymethacrylatethrough aqueous copolymerization initiated by ammonium persulfate.

将甲氧基聚氧乙烯醚单甲基丙烯酸酯、丙烯酸、甲基丙烯酸和烯丙基磺酸钠进行水溶液共聚,合成了具有梳型结构的聚羧酸系高效减水剂。

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