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The originalprocedure has subsequently been replaced by milder and more environmentallyfriendly conditions. We tried to alkylate 3,4,5-trimethoxytoluene by2-allylphenylbenzyl ether in the presence of N-bromosuccinimide.

本实验是在溴代琥珀酰亚胺的作用下使2-烯丙基苯基苄基醚产生苄正离子,苄正离子亲电进攻3,4,5-三甲氧基甲苯从而进行傅氏烷基化反应的。

Moreover, the polymeric arsine palladium(0) complex is an efficient catalyst for the carbonyl allylation of aldehydes and the coupling reaction of aryl halides with terminal alkynes or Grignard reagent.

该聚合物负载的胂钯(0)配合物还是醛的羰基烯丙基化及芳基卤化物与端炔、Grignard试剂的交叉偶联反应的有效催化剂。

Three kinds of novel N-heterocyclic carbene allyl palladium complexes (Catalyst 1, 2 and 3) were synthesized. Norbornene polymerizations were carried out using three catalysts activated with methylaluminoxane in toluene.

研究了以3种N-杂环卡宾螯合烯丙基钯配合物1、2和3为催化剂,甲苯为溶剂,甲基铝氧烷为助催化剂催化降冰片烯的聚合。

A hydrophilic positively charged nanofiltration membrane was prepared by UV irradiation graft polymerization of diallydimethyl ammonium chloride onto the surface of ultrafiltration membranes made of polyetherketone cardo.

通过在酚酞基聚芳醚酮超滤膜表面紫外辐照接枝亲水性单体二烯丙基二甲基氯化铵制备了一种表面荷正电的纳滤膜。

It provides a route tothe compounds which contains three functional groups, two carbon-nitrogentriple bonds and one carbon-carbon double bond. In water, metallic indiumpromotes carbon-sulfur bond coupling reaction of aromatic sulfonyl chloride withsuitable organic halides to afford sulfones. In the last chapter, metallic tin mediated allylation of aldimines with allylbromide was revealed.

第三章,我们研究了在水相介质中金属铟促进的烯丙基溴对1,1-二氰基-2-芳基乙烯的Michael加成反应,生成一个含碳碳双键和二个碳氮叁键的三官能团化合物,另外,金属铟在水介质中还可以促进芳基磺酰氯与卤代烃发生碳硫键的偶联,生成砜。

Herein, we describe a novel catalysis of palladium complex, which mediates tandem allylation of o-phenylenediamines with 2-ene-1,4-diols using water as solvent.

在本实验中,我们探讨邻-苯二胺类和2—烯—1,4—二醇类在水中进行连续两次烯丙基化的一个新的钯催化系统。

Thestercoselectivity of the reaction of propargylide was different completely from that of the reactionof telluronium 3-trimethylsilylalltide with α,β-unsaturaled ketones and trans-trimethysilylacetylenyl-l-benzoyleyelopropane derivatives were obtained.

发现这一反应的立体化学与同样条件下含硅烯丙基碲叶立德和α,β-不饱和酮反应的立体化学完全不同,得到的是又式-2-三甲基硅基乙炔基-1-酮基环丙烷衍生物。

As superplasticizer , a series of comb-shaped copolymers of polycarboxylic acid were synthesized by polyoxyethylene allyl methyl diether, maleic anhydride, and styrene with different initiators,and esterified with PEO-n.

以聚氧乙烯甲基烯丙基二醚、顺丁烯二酸酐、苯乙烯等为共聚单体,采用不同引发剂,合成了一系列聚羧酸型梳状共聚物超分散剂,并以PEO n单酯化得酯化产物,研究了共聚物的结构、组成、添加量等对水泥粒子分散性能的影响。

UV-curable hyperbranched poly was synthesized via organosilicon polymer bearing silicon hydride end groups and vinyltriallylsilane at the presence of Pt/C catalyst.

通过含硅氢键的超支化聚合物和乙烯基三烯丙基硅烷在铂催化剂作用下反应制备了可紫外光固化的超支化聚硅氧基硅烷。

A series of β-vinyl alcohols were synthesized using methyl alkyl ketones or methyl aryl ketones and allyl chloride as starting materials by Grignard reagent method.

以烯丙基氯和甲基酮为原料,通过格氏试剂法合成了-β烯醇化合物,并探讨了各种因素对收率的影响,获得了控制反应过程的最佳参数。

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