烯丙基化

The originalprocedure has subsequently been replaced by milder and more environmentallyfriendly conditions. We tried to alkylate 3,4,5-trimethoxytoluene by2-allylphenylbenzyl ether in the presence of N-bromosuccinimide.

本实验是在溴代琥珀酰亚胺的作用下使2-烯丙基苯基苄基醚产生苄正离子，苄正离子亲电进攻3，4，5-三甲氧基甲苯从而进行傅氏烷基化反应的。

The carbonylation of allyl bromide and hydrogenation of 1-octene were carried out under atmospheric pressure and at 40℃.

研究了它们在烯丙基溴的常压羰基化反应和1-辛烯的常压加氢反应中的催化性能。

The yield of allyl glycidyl ether can reach up to 96% at 30 ℃ for 3 h at a molar ratio of 1 to 1.5 of sodium allylate to epichlorohydrin.

醚化反应中固体烯丙醇钠与环氧氯丙烷摩尔比为1：1.5，在无水条件下于30℃反应3 h，烯丙基缩水甘油醚的收率达96%以上。

We studied effects of additives in the allylic amination reaction. We found that4NF could improve the reactivity and enantioselectivity.

对于烯丙基胺化反应，我们研究了外加添加剂对对映选择性的影响，我们发现四丁基氟化铵的加入可以大大提高反应速度及对映选择性。

The epoxidation of of various olefins was carried out using LDH-F with Mg/Al=5 as the catalyst and H2O2 and benzonitrile as the oxidants. This catalytic system has excellent catalytic activity. The conversion and selectivity are both above 95% when using styrene, indene, allyl alcohol, and allyl chloride as the substrates.

以Mg/Al=5的LDH-F为催化剂，H2O2和苯甲腈为氧化剂对不同官能团化烯烃进行环氧化反应，结果表明，此催化体系具有良好的催化性能，在苯乙烯、茚、丙烯醇和烯丙基氯环氧化反应中转化率和选择性均在95%以上。

In the presence of alkalinity and tetraethyl ammonium bromide, 2,4-dihydroxy benzophenone reacts with allyl glycidyl ether to form an ethylenic derivative of benzophenone, 2-hydroxy-4-(β-hydroxy-γ-allyloxy) propyloxy benzophenone, which can further undergo hydrosilylation with polyhydromethylsiloxane.

在相转移催化剂四乙基溴化按作用下，利用2，4-二羟基二苯甲酮与烯丙基缩水甘油醚在碱性水溶液中的开环加成反应，合成了中间体4-丙氧基－2-羟基二苯甲酮，将其进一步与聚甲基氢硅氧烷进行硅氢化加成反应。

Fourthly, The preparation of 1 -triazolyl-2-isoxazolinyl substituted-ethenes was developed through an one-pot 1, 3-dipolar cycloaddition of NaN_3 and RI,α-alkylation reaction of substituted allyl bromides and 1, 3-dipolar cycloaddition of nitrile oxidesbased on polystyrene-supported propargyl selenide.

四、从聚苯乙烯负载的炔丙基硒醚出发，通过与叠氮化钠和碘化物的一锅法1，3-偶极环加成反应、取代烯丙基溴的α-烷基化反应和腈氧化物的1，3-偶极环加成反应固相合成了1—三唑—2—异噁唑啉取代的-乙烯。

As superplasticizer , a series of comb-shaped copolymers of polycarboxylic acid were synthesized by polyoxyethylene allyl methyl diether, maleic anhydride, and styrene with different initiators,and esterified with PEO-n.

以聚氧乙烯甲基烯丙基二醚、顺丁烯二酸酐、苯乙烯等为共聚单体，采用不同引发剂，合成了一系列聚羧酸型梳状共聚物超分散剂，并以PEO n单酯化得酯化产物，研究了共聚物的结构、组成、添加量等对水泥粒子分散性能的影响。

This novel reagent was treated with LDA to produce polystyrene-supported a-seleno carbanions, which reacted with alkyl halides and epoxides, followed by stereospecific selenoxide syn-elimination to give olefins and allylic alcohols respectively.

它与LDA反应形成α—硒基稳定的碳负离子，再与卤代烃或环氧化合物发生α—烷基化反应，烷基化后的树脂可以在30%的双氧水中进行氧化-消除，以良好产率和较高纯度合成了取代烯烃或烯丙基醇。

UV-curable hyperbranched poly was synthesized via organosilicon polymer bearing silicon hydride end groups and vinyltriallylsilane at the presence of Pt/C catalyst.

通过含硅氢键的超支化聚合物和乙烯基三烯丙基硅烷在铂催化剂作用下反应制备了可紫外光固化的超支化聚硅氧基硅烷。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。