烯丙基化

Bromopropane is produced from hydrogen bromide and propene in the presence of catalyst by free radical addition process.

丙烯与溴化氢在催化剂作用下，进行自由基加成反应生产1-溴丙烷。

A steel bar is washed and dried, and then put into a glass pipe which is sealed to obtain stirring magneton; a mixed solvent of Gamma-methacrylate oxide propyl trimethoxy silane and methanol is prepared and added with an organic base to obtain a pre-bonding solvent; the stirring magneton is immerged into the pre-bounding solvent, and the outer surface of the glass pipe of the stirring magneton is bonded with a layer of silane substance with alkenyl; a reactive monomer mixture and a pore-forming agent mixed solvent are evenly mixed and then added into a container, the stirring magneton after the pre-bounding is put into the container which is sealed and then put into a water bath; after reaction, the container is removed, the stirring magneton coated with a polymer is taken out and put into a extractor and extracted by using a solvent; or the stir bar is immersed into the solvent till no impurity can be checked in the solvent, thereby obtaining the product.

将铁条清洗干燥，放入玻璃管内，密封得搅拌磁子；配制γ-甲基丙烯酸氧丙基三甲氧基硅烷与甲醇的混合溶液，加入有机碱得预键合溶液，将搅拌磁子浸入预键合溶液，在搅拌磁子的玻璃管外壁键合一层带烯基的硅烷化物质；将反应单体混合剂和致孔剂混合溶液混匀后倒入容器中，将预键合后的搅拌磁子放入容器，密封后置于水浴中，反应后除去容器，取出涂有聚合物的搅拌磁子，置于提取器中，以溶剂提取，或将搅拌棒置于溶剂中浸泡至溶剂中无杂质检出，得产物。

Via comprehensive computations, the possibilities of vinylidene and allene intermediates were excluded, and the reaction mechanism was found to contain the following three steps:(1) gold-catalyzed cyclization to give the cyclic intermediate,(2) the cyclic intermediate undergoing a 1,3-H migration to give a more stable intermediate, with the assistance of water-cluster,(3) finially, the 1,2-H or 1,2-silyl migration occuring for generation of the observed product.

通过对各种可能的反应路径的进行计算和比较，排除了亚甲基卡宾和连二烯中间体的可能性，并确定该异构化反应机理包含以下三个步骤：（1）炔丙基吡啶反应在金催化条件下发生分子内的成环得到环状中间体；（2）环状中间体在水分子簇的协助下优先发生1，3-氢迁移反应，异构化得到更为稳定的中间体；（3）最后再进行1，2-氢迁移或是1，2-硅烷基团迁移即得到实验中所观察到的环异构化产物。

Various synthetic method of 1,3-propanediol were introduced and compared, including hydration and hydrogenation of acrylaldehyde, carbonylation of epoxy ethane , microbiological fementation, the process starting from methyl aldehyde, etc.

介绍了1，3-丙二醇的几种制备方法，即丙烯醛水合-氢化法、环氧乙烷羰基化法、微生物发酵法和以甲醛等为原料的方法。

4R,5S,6R-5,6-Bis-allyl-6-aldehyde-γ-hexanelactone I-145 was prepared from D-arabinose by six steps. Compound I-145 underwent Mukaiyama-type intramolecular aldolization to produce bicyclooctane I-147 stereospecifically.

我们以D-阿拉伯糖为起始原料，经六步反应，得到(4R，5S，6R)-5， 6-二烯丙氧基-6-醛基-γ-己酸内酯I-145，然后I-145发生分子内的Mukaiyama式aldol缩合反应，完全立体专一性地得到环化中间体I-147。

Titanium silicalite 1(TS 1)with different crystal size s were synthesized in the system of TPABr n butylamine by adjusting the formation of gel and the method of crystallization.

在四丙基溴化铵正丁胺体系中合成不同晶粒大小的TS 1沸石，采用IR、XRD UV Vis、SEM、2 7AlMASNMR对其进行表征，并以丙烯环氧化反应为探针考察其催化性能。

The formation of charge transfer complex was studied in the first part. The second part includes the synthesis and characterization of the acrylated unsaturated polyester and the kinetic studies on the Ar-UPE/ triethylene divinyl ether (DVE-3) photocuring system, the rheology and properties of film after photocuring. The third part includes the synthesis and characterization of the urethane modified unsaturated polyester and the kinetic studies on the PU-UPE/DVE-3 photocuring system, the rheology and properties of film after photocuring. The fourth part includes the synthesis and characterization of the vinyl ether end capped polyurethane and the kinetic studies on the VE-PU/DVE3 photocuring system, the rheology and properties of film after photocuring.

整个研究工作分为四个部分：一是电荷转移复合物的研究；二是丙烯酰氧基化不饱和聚酯的合成，表征，Ar-UPE/二缩乙二醇二乙烯基醚（DVE-3）体系光固化动力学研究以及Ar-UPE/DVE-3体系流变性能和光固化后涂膜综合性能的研究；三是氨酯改性的不饱和聚酯的合成，表征，PU-UPE/DVE-3体系光固化动力学研究以及该体系光固化后涂膜综合性能的研究；四是乙烯基醚封端的聚氨酯的合成，表征，VE-PU/马来酸二甲酯体系光固化动力学研究以及VE-PU/DMA体系流变性能和光固化后涂膜综合性能的研究。

Poly silica hybrids were prepared through polymerization, condensation and sol gel processes of the mixture of methyl methacrylate, poly and a small amount of coupling agent methacryloxylpropyl trimethoxy siliane in tetrahydrofuran.

采用溶胶-凝胶技术，以硅酸钠为原料制备聚硅酸/四氢呋喃溶胶，再与甲基丙烯酸甲酯及少许偶联剂甲基丙烯酰氧丙基三甲氧基硅烷(MPTMS 混合，经聚合、缩合和溶胶-凝胶过程制备了有机/无机两相间有— C—Si—O—键的杂化材料——聚甲基丙烯酸甲酯/二氧化硅(PMMA/Si O2 )。

Compared with the present process for the synthesis of acrylate by esterification of acrylic acid, which comes by oxygenation of propylene, the process by the carbonylation of acetylene to acrylic acid and its esters pays less cost, and so, is worth to be studied.

相对于目前主张的丙烯氧化法生产丙烯酸，再酯化生产丙烯酸酯的主流工艺，乙炔羰基化法合成丙烯酸及酯的工艺具有很好的经济性应用价值。

Moreover, MeJA induced defense genes, such as pathogenesis-related proteins (PR2a), phenylalanine ammonia-lyase, BX9, and TPS. MeJA also increased DIMBOA and Vannillic acid content of leaves and roots significantly but leaf p－Hydroxybenzoic acid concentration was decreased significantly and Protocatechuric acid was produced in roots only.

1MeJA叶片处理能诱导叶片和根系中丙二烯氧化物环化酶基因、糖基转移酶（BX9）基因、苯丙氨酸转氨酶基因的表达，使叶片和根系中丁布含量升高，同时，6μL/L MeJA处理使第二叶中原儿茶酸含量显著降低，诱导根中产生原儿茶酸，使第二叶中香草酸含量和根中未知物质峰面积显著增大。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新