烯丙基

In this study, we carried out the allylation of anilines with allylic acetates in PEG-H2O system in the presence of palladium as catalyst. N-allylation of anilines was achieved.

在本研究中，我们完成利用钯催化剂，在水及聚乙二醇系统中，使苯胺类和乙酸烯丙酯类进行烯丙基化反应，并探讨各苯胺类反应物之结果。

Template copolymerization of acrylamide with acylic acid was carried out in the presence of polyallylammonium chloride as matrix in aqueous solutions.The various influences on the rate of polymerization were studied by dilatometer and electrical conductivity measurements.

丙烯酰胺和丙烯酸模板共聚合是以聚烯丙基氯化铵模板存在下，在水溶液中进行，在这体系中，模板PAAC和单体AA有很强的相互作用，而单体AM与模板则没有作用。

According to the properties of acrylic acid series polymer of scale inhibition. A kind of amphiprotic tercopolymer of acrylic acid, acrylamide and dimethyldiallylammonium chloride is synthesised, with water as solvent, persulfate and hypophosphate as initiator. Through the tests, the copolymer can show the good scale inhibiting effect and bactericidal action, and become a multifunctional scale inhibition.

本研究根据丙烯酸聚合物阻垢剂的特点，使用过硫酸铵(NH_4_2S_2O_8、次亚磷酸钠(Na_2PO_3)构成的氧化——还原型引发剂，水为溶剂，合成了新型可用于处理工业循环冷却水的丙烯酸—丙烯酰胺—二甲基二烯丙基氯化铵两性型三元共聚物。

By the experimental study we can get the ways of this polymerization craft which is that we can construct water-solution foam polymeric system with the help of the foaming agent, using AM and DMDAAC as monomers, and that we choice the oxide-reductive agent and ultraviolet light as compound initiation system, and that we proceed vacuate pretreating for Pharmaceuticals, and superinduce additive to prevent cross link in drying process which also can improve product water-solubility.

实验研究得出这种聚合工艺的具体方法为：以丙烯酰胺、二甲基二烯丙基氯化铵为单体，在起泡剂的帮助下，构建出水溶液泡沫聚合体系，引发体系则选用氧化—还原剂和紫外灯组成的复合引发体系引发反应，药品进行抽真空预处理，同时添加一定量的助剂防止产品在干燥过程中发生交联，改善产品水溶性。

Taking acryl amide, dimethyldiallyl ammonium chloride, acrylic acid as the monomer, amphoteric polyacrylamide was prepared by solution copolymetization. The effect of reaction conditions on the molecular weight and flocculation performance of AMPAM was studied.

以丙烯酰胺、二甲基二烯丙基氯化铵、丙烯酸为单体，用溶液共聚法制备两性聚丙烯酰胺，研究了反应条件对两性聚丙烯酰胺分子量及絮凝性能的影响。

Was applied to the AD reaction of eight olefins in PEG/NMO system according to the protocol of ligand 8. The yields and ees of the diols were 70～90% and 77～96%(except for trans-5-decene and ally naphthyl ether) respectively.

在与8相同的催化反应条件下，手性配体9催化八种烯烃的AD反应得到的化学产率和ee值分别为70～90％和77-96％（反式-5-癸烯和萘基烯丙基醚除外）。

The yields were 67～89% and 61～90% respectively, and the ees were 66～99. 9% and 68～99. 9% respectively (except for trans-5-decene and ally naphthyl ether). With trans-stilbene as the substrate, chiral ligands and OsO〓 could be recovered and reused five times in the AD reaction with high catalytic activity and stereoselectivity.

4在PF〓/NMO体系中，将配体8和10分别用于八种烯烃的AD反应，配体、OsO〓和底物的摩尔比为0.02/0.015/1时，化学产率分别为67～91％和61～90％，ee值分别为66～99.9％和68～99.9％（反式-5-癸烯和萘基烯丙基醚除外）。

A one-step method for the synthesis of aromatic indolizine derivatives byintramolecular 1,5-dipolar cyclization reaction of 2-(2-arylethenyl)pyridinium N-ylidesin the presence of an oxidant has been studied for the first time. In the presence ofelectron-deficient olefins, however, 2-(2-phenylethenyl)pyridinium N-ylides underwent1,3-dipolar cycloadditions and then aromatized in situ by TPCD to produce indolizinederivatives, indicating 1,3-dipolar cycloaddition proceed more readily than 1 ,5-dipolarcyclization in these conditions. Pyridinium disubstituted N-ylides, readily obtainedfrom corresponding pridinium and β-chlorovinyl ketone, underwent thermalintramolecular 1,5-dipolar cyclization to give indolizine derivatives easily.Indolizinecarbaldehyde derivatives were synthesized starting from 2-pyridinecarbaldehyde in four-steps involving 1,3-dipolar cycloaddition reaction.

本文首次研究了2-(2-芳基乙烯基)吡啶N-叶立德在氧化剂存在下的分子内1，5-偶极环化反应，采用一锅法合成了中氮茚衍生物；研究了这些N-叶立德的1，5-偶极环化和1，3-偶极环加成反应的选择性，发现当有缺电子烯烃存在时，优先进行1，3-偶极环加成反应，而不再发生分子内1，5-偶极环化反应；由β-氯乙烯酮方便地得到了烯丙基N-叶立德，他们在加热时进行分子内1，5-偶极环化反应而得到中氮茚衍生物；由2-吡啶甲醛为起始原料，通过1，3-偶极环加成反应等四步反应，得到了重要的中氮茚甲醛衍生物，这些反应都具有条件温和和操作简便的特点，是合成中氮茚衍生物的新方法。

The polymerization of preparing PDA could be impacted by allyl chloride, allyl alcohol and allyl aldehyde. The content of allyl chloride, allyl alcohol and allyl aldehyde in the DMDAAC monomer solution varied from 0mg/kg to 1000mg/kg, their intrinsic viscosity of PDA descended from 10.3dL/g to 8.0dL/g, 6.8dL/g and 8.8dL/g respectively. The polymerization of preparing PDA could be carried out well in the case the content of NaCl, active carbon, yellow residua and low molecular polymer of DMDAAC were less than 10000mg/kg, 1000mg/kg, 1000mg/kg and 50000mg/kg respectively.

单一杂质含量变化对聚合产物PDA特征粘度影响的研究结果表明：在DMDAAC单体溶液聚合反应过程中，当Fe~(3+)、Fe~(2+)和Cu~(2+)含量分别达到7mg／kg、9mg／kg和5mg／kg时无法得到聚合产物PDA胶体；当烯丙基氯、烯丙醇、烯丙醛含量分别从0mg／kg增加到1000mg／kg时，聚合产物PDA的特征粘度从10.3dL／g分别下降到8.0dL／g，6.8dL／g和8.8dL／g；活性炭和黄色物质含量在1000mg／kg以下，低聚物含量在50000mg／kg以下以及氯化钠含量在10000mg／kg以下时产物PDA的特征粘度降低变化量不超过0.2dL／g。

The results indicated the ally1 carbon of cyclohexene was catalytically oxidized by molecular oxygen at atmospheric pressure in the presence of the polymer complex and a trace of HOAc at 70℃, which afforded corresponding alcohol, ketone and hydroperoxide acting as intermediate.

结果表明，70℃时，以微量醋酸为添加剂，在催化剂的催化作用下，以常压氧气氧化环己烯，得到烯丙基位的氧化产物环己烯醇、环己烯酮和中间产物环己烯过氧化氢。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新