烯丙基

A novel liquid crystalline compound named p-phenylenediamine di 4-[2- benzamide] was synthesized from allyl 2-hydroxyethylether, ethyl 4-hydroxybenzoate and p-phenylenediamine.

以乙二醇单烯丙基醚、对羟基苯甲酸乙酯、对苯二胺为原料合成了末端为不饱和双键的芳香聚酰胺溶致型液晶化合物——二对烯丙氧基乙氧基苯甲酰对苯二胺，最佳合成的摩尔比为∶羧酸∶对苯二胺∶吡啶=2。

A salt or ester of carbamic acid, especially one used as an insecticide.

丙烯酰胺、甲代烯丙基磺酸钠等为原料，采用溶液聚合法合成出兼含膦酰基和磺酸基的四元聚合阻垢剂PMAAS，。。。

More than 75%of dodecene,decene,allylplenylether,phenylpropene(1.9×10－3mol) were completely hydrosilylated with 23.2 mg complex containing 4.9×10－6 mol platinum within 0.75 hour.

使用23.2 mg络合物(含4.9×10－6 mol Pt)为催化剂、分别使用1.9×10－3 mol 1－十二烯、癸烯、烯丙基苯基醚、苯丙烯进行硅氢加成反应，在0.75 h内产率超过75%。

The third part of this thesis is reactive simulating calculation In this section, some well-known auxiliaries are selected to compute in density functional theory B3LYP on Gaussian 03, from which the relationship between reaction active energies of transition states and enantiomeric excess of chiral products homoallylic alcohols isobtained based on relative reactive ratio theory. Using this relationship, calculations on the reaction of more than eight auxiliaries with four other aldehydes are carried out in AMI and MNDO, proving that N,N\'-dibenzyl tartamide has higher enantioselectivity than others in this reaction.

第三部分为计算化学部分，运用密度泛函理论B3LYP方法在Gaussian03软件上对已经报道的几种手性配体参与的醛不对称烯丙基化反应过程进行模拟计算，基于相对反应速率理论找出两种构型过渡态间活化能的差异与产物光学收率之间的关系；并以此为基础，用AM1和MNDO方法对上述合成的几种配体控制的反应过程进行量化计算，从而在理论上证实了N-苄基酒石酸二酰胺配体在醛的不对称烯丙基化反应中具有较高的立体选择性。

In a similar way, using N,N\'-dibenzyl tartamide as auxiliary,-(2-methyl)allyl-2-chloro-phenyl-methyl azide, a vital intermediate of Repaglinide, can be prepared via asymmetric allylation of o-chlorobenzaldehyde in

产物经氧化和碘加成内酯化反应得到阿伐他汀中间体(3R，5S)-3-羟基-5-碘甲基戊内酯(10)；将N-苄基酒石酸二酰胺用于邻氯苯甲醛的不对称烯丙基化反应以较高光学收率得-甲基烯丙基-2-氯苯基-甲基醇

Reaction of 5'-O-p-methoxytrityl-thymidine with 1, 1'-carbonyl-diimidazole gave the 3'-O-carbonylimidazolide, which was condensed in high yield with 3'-O-protected thymidine to give a dithymidine carbonate. In the same way, we obtained the protected trithymidine dicarbonate. After deprotection, we obtained quantatively the trithymidine dicarbonate.By the same stratagy, we completed the synthesis of dithymidine sulfite.It was shown that allyl can be used as a good protection group for hydroxyl of ribose in the synthesis of oligonucleotides consisting in some unstable nucleotide analogues.

我们在第一部分工作的基础上，以烯丙基作为3'-OH的保护基合成了保护的三胸苷碳酸酯以及二胸苷亚硫酸酯，用我们所得的脱保护条件进行了脱保护研究，得到了三胸苷碳酸酯以及二胸苷亚硫酸酯，并研究了它们合成中的一些化学问题，结果表明：烯丙基能很好地运用于这两类寡核苷酸类似物的合成中，其脱保护条件为中性，不会影响碳酸酯键及亚硫酸酯键。

To obtain a flocculant which could effectively remove dyes from dyeing wastewater , the amphoteric polymer was prepared by copolymerization of acrylamide, acrylic acid, cationic monomer and dmethyldiallylammonium chloride or acryloyl oxyethyl trimethyl ammonium chloride.

为制备一种对染色废水有显著脱色效果的絮凝剂，采用溶液聚合法，将两种阳离子单体二甲基二烯丙基氯化铵和丙烯酰氧乙基三甲基氯化铵分别与丙烯酰胺，丙烯酸共聚，合成了两性聚合物。

It is found that the stereochemistry of the reactions of telluronium allylide,crotonylide and trimethylsilyallylide with α,β-unsaturated esters and amides can be tuned by thechoice of reaction conditions.

利用反应条件的变化首次实现了烯丙基、巴豆基、含硅烯丙基碲叶立德与α，β-不饱和酯、酰胺进行环丙烷反应的立体化学调控，能高立体选择性地、高效率地合成两种不同几何异构体中的一个。

The algicidal performances of monomer dimethyldiallylammonium chloride and a commercial algicide dodecyldimethylbenzylammonium chloride（ 1227 ） were contrasted with that of PDM.

对两种营养化的模拟水体，通过灭藻实验，研究了聚二甲基二烯丙基氯化铵系列样品的静态灭藻性能，考察了加药量、作用时间、特征黏度等因素对灭藻性能的影响规律，并与聚合物单体二甲基二烯丙基氯化铵及市售灭藻剂十二烷基二甲基苄基氯化铵（1227）的灭藻性能进行了对比。

Tetraallylsilane was synthesized by one-step approach through the reaction of silicon tetrachloride with the partially solvated Grignard reagents formed in situ from allyl bromide and magnesium in the mixed solvents of toluene and ether.

采用一步合成方式，将3-溴丙烯与金属镁在以甲苯和供电子溶剂构成的混合溶剂中进行反应，继而与四氯化硅反应，成功合成了四烯丙基硅烷，其产率在乙醚与3-溴丙烯的摩尔比为4(V甲苯/V乙醚=1·1)时达到极值，超过了91%。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新