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The molybdenum-based multiphasic oxide catalysts were prepared and tested in the selective oxidation of isobutylene to methacrolein reaction.

研究了添加不同助剂对钼基复合氧化物催化剂对异丁烯选择性氧化制备甲基丙烯醛反应的影响。

The reaction of the compound - 3 - triaiylstannyl -1,1 - diphenyl - 2 - propenyl - 1 -ol with ICl,Br2,I2 formed organotin halides ,which reacted with KOH to form organotin oxide or hydroxide.

首次以非碳环醇-3-三芳基锡基-1,1-二苯基-2-丙烯基-1-醇[Ph_2 CCH=CHSnAr_3]和卤素或拟卤素发生取代反应得到卤化物,并以此合成了氢氧化物、氧化物和配合物。

Various synthetic method of 1,3-propanediol were introduced and compared, including hydration and hydrogenation of acrylaldehyde, carbonylation of epoxy ethane , microbiological fementation, the process starting from methyl aldehyde, etc.

介绍了1,3-丙二醇的几种制备方法,即丙烯醛水合-氢化法、环氧乙烷羰基化法、微生物发酵法和以甲醛等为原料的方法。

Water,butylene glycol,cyclomethicone,VP/VA copolymer,glyceryl stearate,glycerin,ppg-15 stearyl ether,titanium dioxide,propylene glycol,cetyl alcohol,citrus aurantium dulcisfruit extract,saccharide isomerate,biosaccharide gum-1,ethoxydiglycol,peg-40 stearate,glycyrrhiza glabraroot extract,morus bombycis root extract,potassium cetyl phosphate,phenoxyethanol,c12-20 acid peg-8 ester,triethanolamine,prunus amygdalus dulcis oil,carbomer,caprylyl glycol,caffeine,disodium edta,methylparaben,chondrus crispus,butylparaben,iris germanica root extract,pentadecalactone,sodium polyacrylate,ethylparaben,sodium hyaluronate,peg-8,propylparaben,citric acid,chlorhexidine digluconate,tocopherol,ascorbyl palmitate,ascorbic acid

水,丁烯二醇,环甲硅脂,VP/VA共聚物,甘油基硬脂酸,甘油,ppg-15 stearyl ether,二氧化钛,丙二醇,十六烷基醇,橙子萃取物,天然异构寡糖, biosaccharde gum-1,乙基氧基乙二醇,聚乙二醇- 40硬脂酸,甘草根提取物,桑白皮根萃取,钾十六烷基磷酸盐,苯氧乙醇,c12-20 acid peg-8 ester,三乙醇胺,甜杏仁油,高分子胶,辛乙二醇,咖啡因,乙二胺四乙酸二钠,对羟基苯甲酸甲酯,卡拉胶,对羟基苯甲酸丁酯,鸢尾花根萃取, pentadecalactone ,聚丙烯酸钠,羟苯乙酯,透明质酸钠,聚乙二醇- 8,羟苯丙酯,柠檬酸,洗必泰葡萄糖酸盐,维生素E,维生素C棕榈酸酯,抗坏血酸

The formation of charge transfer complex was studied in the first part. The second part includes the synthesis and characterization of the acrylated unsaturated polyester and the kinetic studies on the Ar-UPE/ triethylene divinyl ether (DVE-3) photocuring system, the rheology and properties of film after photocuring. The third part includes the synthesis and characterization of the urethane modified unsaturated polyester and the kinetic studies on the PU-UPE/DVE-3 photocuring system, the rheology and properties of film after photocuring. The fourth part includes the synthesis and characterization of the vinyl ether end capped polyurethane and the kinetic studies on the VE-PU/DVE3 photocuring system, the rheology and properties of film after photocuring.

整个研究工作分为四个部分:一是电荷转移复合物的研究;二是丙烯酰氧基化不饱和聚酯的合成,表征,Ar-UPE/二缩乙二醇二乙烯基醚(DVE-3)体系光固化动力学研究以及Ar-UPE/DVE-3体系流变性能和光固化后涂膜综合性能的研究;三是氨酯改性的不饱和聚酯的合成,表征,PU-UPE/DVE-3体系光固化动力学研究以及该体系光固化后涂膜综合性能的研究;四是乙烯基醚封端的聚氨酯的合成,表征,VE-PU/马来酸二甲酯体系光固化动力学研究以及VE-PU/DMA体系流变性能和光固化后涂膜综合性能的研究。

The stable or unstable state of the montmorillonite-water dispersion is mainly effected by the properties of montmorillonite, water, and stabilizers as well as their interactions, while the type, the structure, the properties and the concentration of the stabilizer play dominate roles. Based on the molecular designing clues, this research selected three sulfonated copolymers as the stabilizers, i.e. the sodium 2-acrylamido-2-methyl-1propane sulfonate /acrylamide /disodium itaconate terpolymer, the AMPS/AM/N-vinyl pyrrolidone terpolymer and the sodium styrenesulfonate /IA copolymer. The preparation and characterization of the sulfonated copolymers were discussed, the high-temperature stability of the montmorillonitewater dispersion was characterized with the rheology, the filtration, the particle size distribution, the electrostatic properties, and the adorption of the sulfonated copolymers onto montmorillonite particles. At the same time, a systematic mechanism of the hightemperature stabilization of the dispersion was presented.

本文构筑了分子设计的思路,选取AMPS(2-丙烯酰胺基-2-甲基丙磺酸钠)/AM/IA三元共聚物、AMPS/AM/NVP三元共聚物和SSA/IA二元共聚物等三种磺化共聚物作为蒙脱土-水分散体系的高温稳定剂,进行了磺化共聚物稳定剂的制备与表征;从流变学、滤失性能、粒度分布、电性质以及磺化共聚物在蒙脱土上的吸附作用等方面,对蒙脱土-水分散体系的高温稳定性进行了研究,考察了蒙脱土-水分散体系的高温稳定性能,同时提出了高温稳定机理。

The main products are : 2 - Acrylamido--2 - methylpropane sulfonic acidsewage treat agent etc.

主要产品为:2-丙烯酰胺基-2-甲基丙磺酸水处理剂等产品。

Main products are Perfluorosulfonated acid resin, PFSA aqueous dispersion, and on the basic of them, HFPO,TFE sultone,PSVE,PPVE,MTPME etc fluorinated fine chemicals,and FEP,FKM,PVDF etc fluorpolymers.

公司主导产品有全氟磺酸离子交换树脂、全氟磺酸离子交换树脂溶液,同时以此为依托,配套生产六氟环氧丙烷、四氟磺内酯、PSVE、PPVE、甲氧基四氟丙酸甲酯等含氟精细化学品,聚全氟乙丙烯树脂(FEP,F46)及分散液、氟橡胶、聚偏氟乙烯等含氟高分子材料。

In chapter four, molecular imprinting polymers against amino acid derivatives utilizing 2-VP+AM as combined functional monomer and trimethylolpropane trimethacrylate as tribasic cross-linker were prepared and result was compared with those with the same amino acid derivative as the imprinted molecules utilizing ethyleneglycol dimethacrylate as dibasic cross-linker. It was found that cross-link intensity of the molecular imprinting polymer is higher when TRIM was utilized and baseline separation for the imprinted molecule could be achieved. When TRIM was utilized as cross-linker more molecule is imprinted during the polymerization.

第四章采用2-乙烯基吡啶+丙烯酰胺复合功能单体,考察了三元交联剂三甲氧基丙烷三甲基丙烯酸酯烙印氨基酸衍生物的情况,并与二元交联剂乙二醇二甲基丙烯酸酯烙印相同氨基酸衍生物的情况进行了对比,发现三甲氧基丙烷三甲基丙烯酸酯交联剂在较小的用量下就可使分子烙印聚合物达到足够的交联度,实现烙印分子的基线分离。

The result of potassium malonyloxyborohydride as a new hydroboration reagent reacts with terminal alkenes and alkynes is described.

介绍新的硼氢化试剂丙二酰氧基硼氢化钾与链端烯炔烃的作用,烯烃的硼氢化物在PTC条件下,插入∶CCl2 ,可得饱和羧酸;炔烃则难以与之硼氢化。

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