烯丙基

This thesis focused mainly on studying the role of planar chirality in asymmetric catalysis, synthesizing novel ferrocene ligands and applying them to palladium-catalyzed allylic substitution reactions.

本论文主要是研究二茂铁平面手性在不对称催化反应中的作用，设计合成新型二茂铁配体及其在钯催化烯丙基取代反应中的应用。

It revealed that the gaseous oxygen was related to the deep oxidation of hydrocarbon, since the breakage of C-C bond in allylic intermediate didn＇t exist during the process of reaction. This is due to the weak ability of lattice oxygen to attack hydrocarbon molecular.

实验结果指出，烃类的深度氧化反应与气相氧的存在有关，晶格氧对烃分子中碳碳键的攻击较弱，反应中烯丙基中间体几乎不发生碳碳键的断裂。

But, there is no an example of the application of allylsamarium bromide as a single electron transfer reagent.

我们用不同的方法合成了一系列的卤代酮，考察了这些卤代酮与烯丙基溴化钐试剂的反应。

Products has led caprate cobalt, cobalt naphthenate, TY series of high-performance polyimide resin, FLQ type latent epoxy curing promoting agent, diallyl bisphenol A Product dozens of top-five.

主导产品有癸酸钴、环烷酸钴、TY系列高性能聚酰亚胺树脂、FLQ型潜伏性环氧固化促进剂、二烯丙基双酚A五大类数十种产品。

It seems that the planar chirality is decisive in controlling the absolute configuration of product in the model reaction.

对烯丙基钯络合物的研究表明反应的对映选择性是由动力学和热力学共同控制的。

In this thesis, it was intended to investigate the role of planar chirality, and to design and synthesize novel ligands.

在前项工作基础上合成一类有效的手性二茂铁配体，拓宽烯丙基化反应的底物或反应类型，为解决这些问题做出我们的一些贡献。

ZnO nanorings were prepared on a large scale by a facile solution-based method at 70 ℃ for 5 h via hexamethylenetetramine(C6H12N4) and Zn(NO3)2·2H2O as the raw materials in the presence of surfactant PAM-CTAC.

以六次甲基四胺(Hexamethylenetetramine， C6H12N4)和水合硝酸锌[Zn(NO3)2·2H2O]为原料，表面活性剂聚丙烯酰胺-氯化二烯丙基二甲基铵为形貌控制剂，采用液相沉淀法合成了ZnO纳米环。

The tetraoxazoline ligands only afforded the-configuration whether monometallic and/or bimetallic palladium complexes were formed upon the complexing process. Using the chelation-induced axially chiral palladium complex as a catalyst, excellent catalytic activities and enantioselectivities in the Wacker- type cyclization of allylphenols with up to 99% ee were gained.

当它与钯离子配位后只得到了轴构型为S的单金属或双金属配合物，并将该配体应用于钯催化的邻烯丙基苯酚的Wacker-type环化反应中，获得了很好催化活性和高达99% ee。

Aqueous allylation reaction mediated by metals is one of the most widely researched organometallic reactions in aqueous media.

在已发现的水相金属有机反应中，水相烯丙基化反应是研究得较多和较深入的反应之一。

The described tackifier is applicable to perchloride raw rubber based on fragment form and non-halide or low-halide raw rubber, and can make most of allyl group implement bromation reaction in priority.

所述增粘剂基于碎片形式的高氯化生橡胶和非卤化或低卤化的生橡胶，并优选使大部分的烯丙基进行溴化反应。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。