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The results showed that the reaction time was 5 h,reaction temperature was 60℃,the molar ration of allyl chloride to hydroxyl was 1.5,the molar rat...

实验结果表明,最佳工艺条件为反应时间5 h、反应温度60℃、烯丙基氯用量为1.5、季铵盐催化剂用量为聚乙二醇物质的量比的5%,聚乙二醇封端率达到85%以上。

We see the symmetry we have attributed to allylic particles on the basis of the resonance theory; the two ends of each of these molecules are equivalent

我们看到了曾经根据共振论而归因于烯丙基型粒子的对称性,所有这些分子中每个分子的两端都是等性的。

That is encouraging for palladium-catalyzed allylic substitution reactions which is difficult to use in industry due to the current low reactivity of catalysts.

而且,值得注意的是这类配体的反应活性都非常高,对于由于催化剂活性低难以在工业上应用的钯催化烯丙基取代反应来说,这无疑是一大喜讯。

Application of 1, 1'-Planar chiral P, N -ligands into palladium-catalyzed allylic substitution

1, 1'-平面手性二茂铁膦氮配体在钯催化烯丙基取代反应中的应用

It afforded a practical method to synthesize chiral allylic amines.

该方法是合成手性烯丙基胺类化合物的一个非常适用方法。

This paper reviews the recent advances in synthesis of chiral allylic amines, mainly discussing the effects of ligands on chemo-and regio-selectivities.

综述了近年来手性烯丙基胺的合成进展,重点介绍了催化剂配体对化学选择性和对映选择性的影响,并阐述了各种类型的反应机理

There were few successful examples of regioselectivity in reactions of unsymmetrically allylic derivatives, and enantioselectivities obtained with prochiral nucleophiles.

因而我们选用反应机理相对比较清楚的钯催化烯丙基取代反应来研究平面手性的作用。

Synthesis and application of 1, 1'-ferrocene P, N -ligands in enatio- and regio-selective palladium-catalyzed allylic substitution reactions

1, 1'-二茂铁膦氮配体的合成及其在不对称区域选择性钯催化烯丙基取代反应中的应用

Allylic side chain was modified to give six bayin analogs in which compound I has a free 7-hydroxy group.

修饰8-位烯丙基侧链,得到了六个黑豆素类似物,共中8的7-位为游离羟基。

Flexibilizing co-monomers were evaluated including both vinyl and allylic types.

Flexibilizing共同单体进行了评价,包括乙烯和烯丙基类型。

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