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We studied effects of additives in the allylic amination reaction. We found that4NF could improve the reactivity and enantioselectivity.

对于烯丙基胺化反应,我们研究了外加添加剂对对映选择性的影响,我们发现四丁基氟化铵的加入可以大大提高反应速度及对映选择性。

When the proportion of the aryl halides was changed,the aromatic products with different number substitutes could be obtained.

通过研究我们发现,活泼酰基与烯丙基在偶联反应中活性相当,可得到不同成环方式的产物,且当改变卤代物比例时,将得到不同数量取代芳烃的产物。

A hydrophilic positively charged nanofiltration membrane was prepared by UV irradiation graft polymerization of diallydimethyl ammonium chloride onto the surface of ultrafiltration membranes made of polyetherketone cardo.

通过在酚酞基聚芳醚酮超滤膜表面紫外辐照接枝亲水性单体二烯丙基二甲基氯化铵制备了一种表面荷正电的纳滤膜。

A new chiral quaternary ammonium salt 1a was synthesized by the reaction of cinchonine and(2,4,6-)trimethyl benzyl chloride.Etherification between 1a and benzyl bromide,allyl chloride,or methyl give corresponding etherified quaternary ammonium salts 1b,1c,and 1d.

由辛可宁和2,4,6-三甲基苄氯,合成了一种新的手性季铵盐(1a),并进一步用苄基溴、碘甲烷和烯丙基氯对分子中的羟基进行醚化,得到相转移催化剂1b、1c和1d。

The mechanism was supposed as follows: polyfluoroalkyl iodides were initiated by sodium dithionite to give R〓 which was added to one double bond of diallylacetic acid, after the sequential radical cyclization and nucleophilic substitution to form bicyclo-lactones.

这是因为:多氟烷基碘化物在连二亚硫酸钠的引发下,得到自由基R〓,后者加成到二烯丙基乙酸中的一个—C=C—双键上,然后在碱性介质中进行分子内亲核反应得到双环内酯类产物。

The solubility and the dissolution rate of cellulose in two ionic liquids with different structure AMIMCl and BMIMCl were investigated.

测定了纤维素在不同结构的离子液体——1-烯丙基-3-甲基咪唑氯化物和1-丁基-3-甲基咪唑氯化物中的溶解度和溶解速率。

The calculated adiabatic ionization potential is 8.18 eV, which is in excellent agreement with the experimental value. The result is helpful for identifying the allyl radical formed from other flames and for understanding the mechanism of soot formation.

计算的电离能与实验得到的电离能符合得很好,这一结果有助于今后鉴别和分析其它火焰中的烯丙基自由基,且对研究火焰燃烧机理有十分重要的价值。

In order to prepare bismaleimide/montmorillonite nanocomposites with high performance, Na-montmorillonite was modified with allyl-tri-phenyl phosphonium bromide via ion-exchange method.

通过离子交换法将烯丙基三苯基溴化交换到钠基蒙脱土的层间制备改性蒙脱土。

Thus, the corresponding chiral sulfonium ylide was designed and its precursor was found to be readily available from the coresponing sulfide that was easily prepared from D-camphor in two steps.

从价廉易得的手性源 D-樟脑出发,合成了硫原子 b -位含有羟基的手性硅基烯丙基硫盐。

Ee were achieved in the Pd (0)-catalyzed asymmetric reaction of racemic 1, 3-dipheylprop-2-en-1-yl acetate with dimethyl malonate under the optimized reaction conditions.

在钯催化的乙酸1,3-二苯基烯丙基酯与丙二酸二甲酯的不对称反应中,取得了接近定量的收率和较好的对映选择性(71.2%ee)。

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推荐网络例句

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称;三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起,称之为挽歌体诗人或者史诗诗人,他们被称为诗人,似乎只是因为遵守格律写作,而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。

This is not paper type of business,it's people business,with such huge money involved.

这不是纸上谈兵式的交易,这是人与人的业务,而且涉及金额巨大。